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Table 4
Constants (in cm-1) for the X2Π state of 12CH.
Constant | v = 0 | v = 1 | v = 2 | v = 3 | v = 4 | v = 5 |
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T v | 0.0 | 2732.97900(130) | 5339.9051(20) | 7822.2222(28) | 10 181.0060(41) | 12 416.755(24) |
0.0 | 2732.97813(94) | 5339.9036(15) | 7822.2184(18) | 10 180.9996(22) | 12 416.786(10) | |
B v | 14.192249(57) | 13.6617020(560) | 13.135783(58) | 12.613439(67) | 12.092930(100) | 11.57387(52) |
14.192393(61) | 13.6617896(53) | 13.135809(50) | 12.613441(50) | 12.092993(54) | 11.57300(23) | |
A v | 28.14675a | 28.33833a | 28.5312(78) | 28.652(14) | 28.909(30) | 28.64(49) |
28.14675a | 28.33833a | 28.6160(510) | 28.765(48) | 28.968(45) | 29.17b | |
γv × 102 | –2.624(33) | –2.424(32) | –2.267(37) | –2.136(46) | –1.954(62) | –1.86(16) |
–2.853(86) | –2.654(85) | –2.462(83) | –2.323(81) | –2.138(80) | –1.933(70) | |
pv × 102 | 3.358(29) | 3.174(24) | 3.085(34) | 2.987(48) | 2.779(95) | 2.580(150) |
3.464(36) | 3.260(34) | 3.119(36) | 2.967(42) | 2.836(52) | 2.673(62) | |
qv × 102 | 3.8684(20) | 3.7290(17) | 3.5902(23) | 3.4487(35) | 3.3104(69) | 3.1724(75) |
3.8660(31) | 3.7285(29) | 3.5919(32) | 3.4541(36) | 3.3179(43) | 3.1776(32) | |
Dv × 103 | 1.46079(32) | 1.43776(32) | 1.41641(32) | 1.39722(35) | 1.37980(56) | 1.3740(25) |
1.46112(37) | 1.43742(31) | 1.41553(31) | 1.39612(32) | 1.37911(35) | 1.3692(11) | |
Hv × 107 | 1.1381(71) | 1.1061(68) | 1.0717(64) | 1.0295(64) | 0.953(10) | 0.90 b |
1.1064(75) | 1.0625(85) | 1.0212(97) | 0.9790(100) | 0.917(10) | 0.88b | |
Lv × 1012 | –12.00(54) | –12.12(47) | –12.65(41) | –13.52(37) | –13.48(68) | –13.5b |
–3.40(177) | –4.34(162) | –5.69(147) | –7.55(129) | –9.27(111) | –11.6b | |
pDv × 105 | –0.853(79) | –0.728(68) | –0.685(71) | –0.532(91) | –0.52(17) | –0.6b |
–1.010(370) | –0.840(340) | –0.730(320) | –0.630(290) | –0.60(27) | –0.55b | |
qDv × 105 | –1.524(10) | –1.4865(94) | –1.4453(94) | –1.394(12) | –1.344(26) | –1.35b |
–1.590(20) | –1.5500(220) | –1.5090(240) | –1.461(24 ) | –1.4090(25) | –1.35b | |
qHv × 109 | 3.08(13) | 2.94(11) | 2.790(10) | 2.60(11) | 2.30(24) | 2.0b |
4.06(57) | 3.79(53) | 3.560(480) | 3.30(42) | 2.90(37) | 2.52b | |
γDv × 105 | 0.99(15) | 0.90(14) | 0.88(13) | 0.91(13) | 0.81(14) | 0.8b |
1.78(24) | 1.64(22) | 1.53(21) | 1.50(19) | 1.33(18) | 1.29b |
Notes. Uncertainties in parentheses are one standard deviation in units of the last quoted digit. The second line contains the values of Colin & Bernath (2010).
(a)
Fixed to Jackson et al. (2008).
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