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Table 10
Constants (in cm-1) for the A2Δ state of 13CH.
Constant | v = 0 | v = 1 | v = 2 | v = 3 |
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T v | 23 173.84500(200) | 25 906.4648(33) | 28 447.0001(50) | 30 775.3828(78) |
23 173.84460(69)a | 25 906.4596(15)a | 28 446.9953(30)a | 30 775.3748(59)a | |
B v | 14.492570(100) | 13.830140(110) | 13.11333(140) | 12.31697(34) |
14.492358(41)a | 13.830193(54)a | 13.113259(88)a | 12.31700(24)a | |
A v | –1.09930(270) | –1.0741(33) | –1.0312(38) | –1.0000(68) |
–1.09926(90)a | –1.0735(12)a | –1.0339(35)a | –0.9981(38)a | |
γv × 102 | 4.211(66) | 4.056(77) | 3.717(78) | 3.530(160) |
4.184(24)a | 3.999(28)a | 3.783(48)a | 3.470(53)a | |
Dv × 103 | 1.54753(74) | 1.58069(82) | 1.64999(87) | 1.7963(34) |
1.54745(28)a | 1.58442(54)a | 1.65055(48)a | 1.7972(22)a | |
Hv × 108 | 9.610(180) | 5.05(18) | 0.0 | 0.0 |
9.664(65)a | 6.92(20)a | 0.0a | 0.0a | |
Lv × 1011 | –2.61(14) | 0.0 | 0.0 | 0.0 |
2.667(50)a | 2.54(24)a | 0.0a | 0.0a | |
γDv × 105 | –1.140(220) | –1.610(270) | 0.0 | 0.0 |
–0.907(75)a | –0.714(89)a | 0.0a | 0.0a | |
pv × 107 | 0.0 | 0.0 | 0.0 | 0.0 |
5.7(18)a | 10.4(74)a | 20.5a,b | 27.5a,b | |
qv × 108 | 0.0 | 0.0 | 0.0 | 0.0 |
–2.84(41)a | –16.3(23)a | –32.4a,b | –47.3a,b |
Notes. Uncertainties in parentheses are one standard deviation in units of the last quoted digit.
(a)
Constants derived by Zachwieja (1997).
(b)
kept fixed in Zachwieja (1997).
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