Fig. C.3

Translucent gas conditions in all models (see Table 3). Upper left: pure gas phase chemistry.
Upper right: gas and surface chemistry and inactive non-thermal
desorption efficiency aRRK = 0. Lower
left: gas and surface chemistry and active non-thermal desorption with
the typical efficiency aRRK = 0.01. Lower
right: gas and surface chemistry and high active non-thermal desorption
(aRRK =
0.1). The observed abundances and upper limits are indicated
with solid and dashed horizontal lines, respectively, following the respective
species colour code. The dot-dashed and dotted lines for
NH
represent the estimated X(NH
for the TK
= 30 K and 50 K models. If the reactive desorption mechanism is
active with the typical aRRK = 0.01, each NH,
NH2 and
NH3
species that is formed on the grain through a hydrogenation reaction has a
probability of 9.3 ×
10-3, 7.6
× 10-3, and 5.2 × 10-3, respectively,
to desorb into the gas phase. There it will become available for detection and for
follow-up reactions. Experiments by Dulieu et al.
(2013) indicate that this type of non-thermal desorption could be much
more efficient on bare grains than aRRK = 0.01. As shown, our
models are not very sensitive to the exact value of the desorption probability,
since the model with aRRK = 0.1 gives very similar
results to the model using aRRK = 0.01.
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