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Table 3
Rotational spectrum of CH3CH=C=CH-CN in the ground vibrational state.
| Watson S-reduction | ||||||||||||
| Total number of transitions: 654 | ||||||||||||
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| Transition | Obs. frequency | Obs. - calc. | Weight | t | Distortion corrections | Upper energy | ||||||
| total | higher | |||||||||||
|
|
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| 5 | 0 | 5 | 6 | 0 | 6 | 18 371.950 | 0.057 | 0.15 | 0.2 | −0.497 | 1.1E-04 | 6.432897E+04 |
| 5 | 1 | 5 | 6 | 1 | 6 | 18 124.680 | −0.042 | 0.15 | −0.2 | −0.139 | 6.6E-05 | 7.464370E+04 |
| 6 | 1 | 5 | 6 | 2 | 4 | 32 724.730 | 0.450 | 0.20 | 1.4 | −1.852 | −8.7E-04 | 1.091964E+05 |
| 6 | 0 | 6 | 7 | 1 | 7 | 31 458.240 | 0.049 | 0.15 | 0.2 | 0.474 | 6.2E-05 | 9.578716E+04 |
| 6 | 0 | 6 | 7 | 0 | 7 | 21 426.330 | 0.326 | 0.20 | 1.0 | −0.783 | 2.4E-04 | 8.575497E+04 |
| 6 | 1 | 5 | 7 | 1 | 6 | 21 752.800 | 0.212 | 0.10 | 1.3 | −0.623 | 1.7E-04 | 9.822469E+04 |
| 7 | 0 | 7 | 8 | 0 | 8 | 24 476.900 | 0.379 | 0.20 | 1.2 | −1.158 | 4.6E-04 | 1.102315E+05 |
| 7 | 1 | 7 | 8 | 1 | 8 | 24 161.250 | −0.043 | 0.10 | −0.3 | −0.610 | 3.7E-04 | 1.199485E+05 |
| 7 | 1 | 6 | 8 | 1 | 7 | 24 857.380 | 0.247 | 0.15 | 1.0 | −1.040 | 3.7E-04 | 1.230818E+05 |
| 7 | 2 | 5 | 8 | 2 | 6 | 24 556.600 | −0.129 | 0.10 | −0.8 | 0.221 | −1.1E-04 | 1.552332E+05 |
| 8 | 1 | 7 | 8 | 2 | 6 | 32 151.420 | 0.069 | 0.15 | 0.3 | 0.487 | −1.7E-03 | 1.552332E+05 |
| 8 | 0 | 8 | 9 | 0 | 9 | 27 523.020 | 0.046 | 0.10 | 0.3 | −1.630 | 8.3E-04 | 1.377545E+05 |
| 8 | 1 | 8 | 9 | 1 | 9 | 27 178.010 | −0.082 | 0.10 | −0.5 | −0.974 | 7.1E-04 | 1.471265E+05 |
| 8 | 1 | 7 | 9 | 1 | 8 | 27 960.810 | 0.356 | 0.15 | 1.5 | −1.585 | 7.1E-04 | 1.510423E+05 |
| ... | ||||||||||||
Notes. The full version of Table 3 is online at CDS.
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