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Table 3

Relativistic sensitivity coefficients q (in cm-1) of the first three low-lying transitions in the considered F-like ions.

Transition DHF CCSD(T) Method

Method DC DCB DCBV DCBVS

Ti XIV
2s22p5  2P3/2 → 2s2p6  2S1/2 64 658.77 62 281.60 62 428.80 62 630.00 64 100.20
2s22p5  2P1/2 → 2s2p6  2S1/2 16 057.46 13 031.00 14 665.00 14 866.80 16 006.00
2s22p5  2P3/2 → 2s22p5  2P1/2 48 601.30 49 250.60 47 763.80 47 763.20 48 094.20
V XV
2s22p5  2P3/2 → 2s2p6  2S1/2 78 713.40 75 890.80 76 092.00 76 337.00 78 107.40
2s22p5  2P1/2 → 2s2p6  2S1/2 18 765.94 15 237.20 17 192.00 17 437.60 18 723.20
2s22p5  2P3/2 → 2s22p5  2P1/2 59 947.45 60 653.60 58 900.00 58 899.40 59 384.20
Cr XVI
2s22p5  2P3/2 → 2s2p6  2S1/2 94 982.75 91 645.80 91 908.00 92 203.60 94 328.40
2s22p5  2P1/2 → 2s2p6  2S1/2 21 762.93 17 688.00 20 003.00 20 299.40 21 732.40
2s22p5  2P3/2 → 2s22p5  2P1/2 73 219.81 73 957.80 71 905.00 71 904.20 72 596.00
Mn XVII
2s22p5  2P3/2 → 2s2p6  2S1/2 113 401.19 109 469.80 110 401.80 110 456.00 112 497.80
2s22p5  2P1/2 → 2s2p6  2S1/2 25 061.52 20 397.60 23 116.00 23 471.20 25 047.20
2s22p5  2P3/2 → 2s22p5  2P1/2 88 639.67 89 372.20 86 985.80 86 984.80 87 950.60
Fe XVIII
2s22p5  2P3/2 → 2s2p6  2S1/2 135 419.03 130 401.80 130 412.00 131 432.60 134 465.80
2s22p5  2P1/2 → 2s2p6  2S1/2 28 674.75 23 381.00 26 549.60 26 971.20 28 680.60
2s22p5  2P3/2 → 2s22p5  2P1/2 106 444.28 107 420.80 104 462.40 104 461.40 105 485.20
Co XIX
2s22p5  2P3/2 → 2s2p6  2S1/2 159 402.33 154 494.80 154 490.80 155 487.40 158 499.60
2s22p5  2P1/2 → 2s2p6  2S1/2 32 614.50 26 655.40 30 321.20 30 819.20 32 645.00
2s22p5  2P3/2 → 2s22p5  2P1/2 126 487.82 127 439.40 124 469.60 124 468.20 126 454.60
Ni XX
2s22p5  2P3/2 → 2s2p6  2S1/2 187 433.43 180 414.20 181 405.00 181 488.40 186 480.60
2s22p5  2P1/2 → 2s2p6  2S1/2 36 891.19 30 234.80 34 450.00 35 034.60 36 951.60
2s22p5  2P3/2 → 2s22p5  2P1/2 150 442.24 150 479.40 146 455.00 146 453.80 149 429.00
Cu XXI
2s22p5  2P3/2 → 2s2p6  2S1/2 218 412.89 210 444.00 211 437.60 212 418.60 217 410.00
2s22p5  2P1/2 → 2s2p6  2S1/2 41 514.47 34 136.20 38 955.40 39 638.00 41 609.80
2s22p5  2P3/2 → 2s22p5  2P1/2 176 498.41 176 407.80 172 482.20 172 480.60 175 400.20
Zn XXII
2s22p5  2P3/2 → 2s2p6  2S1/2 253 461.14 244 482.80 245 487.80 246 478.20 252 408.00
2s22p5  2P1/2 → 2s2p6  2S1/2 46 493.87 38 377.20 43 858.20 44 650.40 46 629.20
2s22p5  2P3/2 → 2s22p5  2P1/2 206 467.27 206 405.60 201 429.60 201 427.80 205 478.80
Mo XXXIV
2s22p5  2P3/2 → 2s2p6  2S1/2 1 122 326.66 1 074 110.20 1 076 680.20 1 080 272.60 1 120 727.00
2s22p5  2P1/2 → 2s2p6  2S1/2 133 456.00 122 472.40 141 431.20 145 411.00 134 439.00
2s22p5  2P3/2 → 2s22p5  2P1/2 988 470.66 951 437.80 934 449.00 934 461.60 985 488.00

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