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Table 1

Ionization potentials of the 2s22p5  2P3/2, 2s22p5  2P1/2, and 2s2p6  2S1/2 states (in cm-1) in the considered F-like ions.

States DHF CCSD(T) Method NIST δ
Method DC DCB DCBV DCBVS in (%)
Ti XIV
2s22p5  2P3/2 6 369 056.70 6 351 716.78 6 349 138.38 6 349 080.30 6 353 771.99 6 353 000(300) 0.02
2s22p5  2P1/2 6 416 796.01 6 400 283.25 6 396 275.76 6 396 217.45 6 401 015.63 6 400 219 0.02
2s2p6  2S1/2 7 202 770.06 7 172 838.82 7 170 443.09 7 170 520.17 7 175 709.00 7 172 772 0.04
V XV
2s22p5  2P3/2 7 244 125.24 7 225 844.64 7 222 732.82 7 222 662.80 7 228 662.73 7 227 000(3000) 0.03
2s22p5  2P1/2 7 302 886.28 7 285 571.67 7 280 781.04 7 280 710.72 7 286 875.34 7 285 093 0.03
2s2p6  2S1/2 8 136 150.98 8 105 203.30 8 102 337.72 8 102 431.88 8 109 027.13 8 104 732 0.05
Cr XVI
2s22p5  2P3/2 8 174 508.35 8 155 080.76 8 151 368.12 8 151 284.42 8 158 857.81 8 159 300(4000) 0.02
2s22p5  2P1/2 8 246 120.22 8 227 800.77 8 222 131.04 8 222 046.98 8 229 864.75 8 230 192 0.02
2s2p6  2S1/2 9 126 939.75 9 094 738.32 9 091 345.36 9 091 459.33 9 099 745.29 9 097 090 0.03
Mn XVII
2s22p5  2P3/2 9 160 254.00 9 139 439.23 9 135 054.35 9 134 955.09 9 144 404.09 9 144 100(5000) 0.02
2s22p5  2P1/2 9 246 744.55 9 227 179.30 9 220 528.71 9 220 429.03 9 230 229.32 9 229 600 0.02
2s2p6  2S1/2 10 375 395.14 10 341 671.95 10 337 690.69 10 337 827.51 10 348 129.25 10 344 100 0.04
Fe XVIII
2s22p5  2P3/2 10 301 417.91 10 378 939.41 10 373 806.91 10 373 690.04 10 386 175.07 10 384 000(5000) 0.02
2s22p5  2P1/2 10 305 025.68 10 383 932.25 10 376 193.15 10 376 075.78 10 389 052.54 10 386 579 0.02
2s2p6  2S1/2 11 381 797.98 11 346 249.19 11 341 615.25 11 341 778.28 11 355 019.25 11 348 702 0.06
Co XIX
2s22p5  2P3/2 11 398 063.84 11 373 605.77 11 367 646.25 11 367 509.56 11 381 780.07 11 369 000(4000) 0.10
2s22p5  2P1/2 11 321 250.52 11 398 301.05 11 389 359.83 11 389 222.56 11 304 168.53 11 390 960 0.10
2s2p6  2S1/2 12 346 447.88 12 308 728.46 12 303 374.00 12 303 566.93 12 319 058.12 12 300 860 0.14
Ni XX
2s22p5  2P3/2 12 350 263.35 12 323 467.75 12 316 597.83 12 316 438.92 12 333 745.78 12 329 400(6000) 0.04
2s22p5  2P1/2 12 395 726.57 12 370 543.48 12 360 280.51 12 360 120.94 12 378 338.18 12 373 359 0.04
2s2p6  2S1/2 13 369 662.79 13 329 381.20 13 323 234.87 13 323 461.75 13 342 228.46 13 331 600 0.08
Cu XXI
2s22p5  2P3/2 13 358 095.13 13 328 558.60 13 320 690.89 13 320 507.18 13 342 154.51 13 335 000(7000) 0.05
2s22p5  2P1/2 13 328 781.69 13 300 932.85 13 389 222.40 13 389 037.94 13 311 901.06 13 303 830 0.06
2s2p6  2S1/2 14 351 782.41 14 308 494.96 14 301 481.85 14 301 747.12 14 324 844.54 14 310 750 0.10
Zn XXII
2s22p5  2P3/2 14 321 644.44 14 388 914.71 14 379 957.85 14 379 746.57 14 304 630.40 14 395 800(8000) 0.06
2s22p5  2P1/2 15 320 764.09 15 389 757.57 15 376 467.76 15 376 255.64 15 302 721.60 15 392 668 0.07
2s2p6  2S1/2 16 393 169.87 16 346 374.93 16 338 416.51 16 338 725.04 16 365 693.02 16 348 230 0.10
Mo XXXIV
2s22p5  2P3/2 34 370 867.54 34 340 971.33 34 310 383.81 34 309 545.12 34 350 756.58 34 351 000(19000) 0.30
2s22p5  2P1/2 35 378 543.89 35 340 238.01 35 395 353.62 35 394 516.78 35 356 142.00 35 337 305 0.33
2s2p6  2S1/2 37 373 405.67 37 315 588.74 36 388 789.48 36 390 191.78 37 346 807.71 37 306 300 0.40

Notes. The results are compared with the NIST values (Kramida et al. 2013). Differences between the results from the DCBVS Hamiltonian and NIST are given as δ(%).

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