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Table 6
Vibrational energy differences ( cm-1) between ℓ-sublevels of doubly and triply excited bending states of 12C2HD, as resulting from the rotational analysis and the global rovibrational analysis.
| Vibrational state | sublevels | ΔG | ΔG |
| rotational analysis | global analysis | ||
|
|
|||
| v4 = 2 | Δ − Σ+ | 8.782 | 8.772 |
| v4 = 3 | Φ − Π | 17.916 | 17.544 |
| v5 = 2 | Δ − Σ+ | 20.868 | 20.799 |
| v5 = 3 | Φ − Π | 42.280 | 41.598 |
| v4 = v5 = 1 | Δ − Σ+ | 1.397 | 1.401 |
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