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Table C.1
Adopted C-H and C-C band modes for eRCN and DG bulk materials: band centre (ν0), width (δ) and integrated cross-section (σ).
| ν 0 | δ | σ | Band | eRCN | |
| No. | [cm-1 (μm)] | [cm-1] | [× 10-18 cm2] | assignment | designation |
|
|
|||||
| C-H stretching modes | |||||
| 1 | 3078 (3.25) | 22.5 | 1.40 | sp2 CH2 olefinic, asy. | X |
| 2 | 3050 (3.28) | 53.1 | 1.50 | sp2 CH aromatic | X |
| 3 | 3010 (3.32) | 47.1 | 2.50 | sp2 CH olefinic | X |
| 4 | 2985 (3.35) | 17.7 | 1.15 | sp2 CH2 olefinic, sym. | X |
| 5 | 2960 (3.38) | 29.3 | 4.00 | sp3 CH3 aliphatic, asy. | φ X |
| 6 | 2925 (3.42) | 28.9 | 3.30 | sp3 CH2 aliphatic, asy. | X |
| 7 | 2900 (3.45) | 30.0 | 0.50 | sp3 CH2 aliphatic | X |
| 8 | 2882 (3.47) | 30.2 | 1.00 | sp3 CH tertiary aliphatic | X |
| 9 | 2871 (3.48) | 27.8 | 1.45 | sp3 CH3 aliphatic, sym. | φ X |
| 10 | 2850 (3.51) | 41.8 | 2.20 | sp3 CH2 aliphatic, sym. | X |
| C-H bending modes | |||||
| 11 | 1470 (6.80) | 30.0 | 0.30 | sp3 CH3 aliphatic, asy. | φ X |
| 12 | 1450 (6.90) | 3.0 | 1.20 | sp3 CH2 aliphatic | X |
| 13 | 1430 (6.99) | 120.0 | 0.20 | sp2 CH aromatic | X |
| 14 | 1410 (7.09) | 30.0 | 1.00 | sp2 CH2 olefinic | X |
| 15 | 1400 (7.14) | 30.0 | 0.10 | sp3 (CH3)3 aliphatic, sym. | X |
| 16 | 1370 (7.30) | 30.0 | 0.30 | sp3 CH3 aliphatic, sym. | φ X |
| C-C modes | |||||
| 17 | 1600 (6.25) | 160.0 | 0.29 | sp2 C≃C aromatic | XC≃C |
| 18 | 1500 (6.67) | 4.0 | 0.15 | sp2 C≃C aromatic | XC≃C |
| 19 | 1640 (6.10) | 40.0 | 0.10 | sp2 C=C olefinic | XC=C |
| additionally-assumed and estimated C-H modes | |||||
| 20 | 3020 (3.31) | 50.0 | 0.50 | sp2 CH olefinic | X |
| 21 | 890 (11.24) | 8.0 | 0.50 | sp2 CH aromatic | X |
| 22 | 880 (11.36) | 40.0 | 0.50 | sp2 CH aromatic | X |
| 23 | 790 (12.66) | 50.0 | 0.50 | sp2 CH aromatic | X |
| additionally-assumed and estimated C-C modes | |||||
| 24 | 1328 (7.53) | 600.0 | 0.10 | sp2C-C aromatic |
X
|
| 25 | 1300 (7.69) | 720.0 | 0.05 | sp2 C-C aromatic |
X
|
| 26 | 1274 (7.85) | 600.0 | 0.05 | sp2 C-C aromatic |
X
|
| 27 | 1163 (8.60) | 270.0 | 0.05 | sp2 C-C aromatic |
X
|
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