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Table 1

Assigned features of the infrared spectrum of the EXP1 ice mixture H2O:CH3OH:NH3: = 10:1:1 after 56 h of VUV photolysis at 25 K.

EXP1 25 K
Wavenumber (cm-1) Assignments Species References

1723 ν(CO) H2CO Schutte et al. (1993)
1710 ν(CO) HCOOH/NH2CHO Schutte et al. (1999)/Brucato et al. (2006)
1638 δ(OH) H2O Palumbo (2005)*
1585 νas(COO) HCOO Schutte et al. (1999)
1502 δ(CH2) H2CO Schutte et al. (1993)
1460 δ(OH) / δ(NH) CH3OH / ? Schutte et al. (1999)
1378 δs (CH) HCOO Schutte et al. (1999)
1353 δas (CH) HCOO Schutte et al. (1999)
1246 ρ(CH2) H2CO Schutte et al. (1993)
1122 ω(NH) NH3 Kerkhof et al. (1999)
1024 ν(C-O) CH3OH Kerkhof et al. (1999)
840 b libration H2O Palumbo (2005)*

Notes.Vibration mode: stretching (ν), bending (δ), rocking (ρ), inversion (ω). as: asymmetric mode, s: symmetric mode. * Tentatively assigned to water bands in a complex environment changing the position bands from pure water ice.

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