Fig. 2

Infrared spectra between 900 and 2000 cm-1 of the EXP1 ice mixture (H2O:CH3OH:NH3=10:1:1). The spectrum before irradiation was measured after 10 min of ice deposition at 25 K without photolysis. Afterwards, we started the simultaneous ice deposition and photolysis for 56h at 25 K. The two spectra are compared with pure ice of H2CO, NHHCOO−, pure HCOOH, and pure NH2CHO. ω is assigned to the broad band at 1710 cm-1 that could be a combination of the HCOOH and NH2CHO bands, whereas α is tentatively assigned to the bending (OH) of water.
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