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Table 7
Same as Table 5 for HCl and CO. In contrast to other molecules, the Λ = 1 state of HCl corresponds to its C1Π (and not A1Π) electronic configuration.
| aHCl | bCO | |||||||||||||
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|
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| Λ | Te (cm-1) | ωe (cm-1) | Be (cm-1) | Te (cm-1) | ωe (cm-1) | Be (cm-1) | ||||||||
| 0 | 2.990 (+03) | 1.059 (+01) | 2.170 (+03) | 1.931 (+00) | ||||||||||
| 1 | 7.758 (+04) | 2.684 (+03) | 9.330 (+00) | 6.508 (+04) | 1.518 (+03) | 1.612 (+00) | ||||||||
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| MΛ′υ′Λ′′υ′′ (ea0) | MΛ′υ′Λ′′υ′′ (ea0) | |||||||||||||
| υ′′\υ′ | 0 | 1 | 2 | 3 | 4 | 0 | 1 | 2 | 3 | 4 | ||||
| Λ′ → Λ′′ 1 → 0 |
0 | 8.6 (−1) | 2.9 (−1) | 4.0 (−1) | 4.2 (−1) | 3.8 (−1) | 3.0 (−1) | |||||||
| 1 | 5.8 (−1) | 4.2 (−1) | 3.3 (−1) | 9.1 (−2) | 1.2 (−1) | 2.3 (−1) | ||||||||
| 2 | 4.2 (−1) | 4.2 (−1) | 4.2 (−2) | 2.5 (−1) | 2.9 (−1) | 1.7 (−1) | ||||||||
| 3 | 1.9 (−1) | 3.3 (−1) | 2.2 (−1) | 2.7 (−1) | 2.5 (−2) | 1.8 (−1) | ||||||||
| 4 | 1.3 (−1) | 2.2 (−1) | 3.3 (−1) | 4.9 (−2) | 2.4 (−1) | 2.2 (−1) | ||||||||
| MΛ′υ′Λ′′υ′′ (ea0) | MΛ′υ′Λ′′υ′′ (ea0) | |||||||||||||
| υ′′\υ′ | 0 | 1 | 2 | 3 | 4 | 0 | 1 | 2 | 3 | 4 | ||||
| Λ′ → Λ′′ 0 → 0 |
0 | 4.3 (−1) | 2.8 (−2) | 3.1 (−3) | 2.2 (−4) | 1.2 (−5) | 4.3 (−2) | 4.1 (−2) | 2.6 (−3) | 1.6 (−4) | 8.1 (−6) | |||
| 1 | 4.9 (−1) | 2.0 (−2) | 2.0 (−3) | 2.0 (−4) | 3.3 (−2) | 5.7 (−2) | 4.4 (−3) | 3.4 (−4) | ||||||
| 2 | 6.0 (−3) | 2.0 (−2) | 2.0 (−3) | 2.4 (−2) | 4.0 (−2) | 3.6 (−3) | ||||||||
| 3 | 6.1 (−1) | 2.0 (−2) | 1.4 (−2) | 4.5 (−2) | ||||||||||
| 4 | 3.4 (−1) | 3.8 (−3) | ||||||||||||
|
|
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 (cm3
s-1) |
(cm3
s-1) |
|||||||||||||
| J′′\J′ | 0 | 1 | 2 | 3 | 4 | 5 | 0 | 1 | 2 | 3 | 4 | 5 | ||
| 0 | 7.9 (–12) | 3.0 (–12) | 2.3 (–12) | 1.3 (–12) | 4.5 (–13) | 2.1 (–11) | 2.8 (–11) | 7.8 (–12) | 3.8 (–12) | 2.3 (–12) | ||||
| 1 | 1.7 (–11) | 2.0 (–11) | 7.0 (–12) | 2.4 (–12) | 1.3 (–12) | 6.1 (–11) | 4.1 (–11) | 4.0 (–11) | 1.5 (–11) | 6.4 (–12) | ||||
| 2 | 6.1 (–12) | 1.8 (–11) | 2.3 (–11) | 7.2 (–12) | 1.5 (–12) | 1.2 (–10) | 6.1 (–11) | 4.6 (–11) | 4.3 (–11) | 1.7 (–11) | ||||
| 3 | 2.6 (–12) | 3.5 (–12) | 1.3 (–11) | 2.6 (–11) | 6.9 (–12) | 3.9 (–11) | 7.2 (–11) | 5.5 (–11) | 4.7 (–11) | 4.5 (–11) | ||||
| 4 | 5.4 (–13) | 4.6 (–13) | 1.5 (–12) | 9.8 (–12) | 2.6 (–11) | 2.0 (–11) | 2.7 (–11) | 5.3 (–11) | 4.9 (–11) | 4.8 (–11) | ||||
| 5 | 5.1 (–14) | 6.9 (–14) | 8.3 (–14) | 7.0 (–13) | 6.8 (–12) | 1.1 (–11) | 1.1 (–11) | 2.0 (–11) | 4.3 (–11) | 4.5 (–11) | ||||
|
|
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| ∑ [D] kD (cm3 s-1) |  (s-1) |
∑ [D] kD (cm3 s-1) | (s-1) |
|||||||||||
| 2.29 (−13) | 9.80 (−10) | 2.28 (−17) | 2.60 (−10) | |||||||||||
|
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| nJ/n(HCl) | nJ/n(CO) | |||||||||||||
| J | 0 | 1 | 2 | 3 | 4 | 5 | 0 | 1 | 2 | 3 | 4 | 5 | ||
| ❶ | 1.0 (+00) | 4.9 (–04) | 8.5 (–06) | 8.1 (–07) | 6.1 (–08) | 2.7 (–09) | 7.3 (–02) | 2.5 (–01) | 3.3 (–01) | 2.2 (–01) | 8.9 (–02) | 2.9 (–02) | ||
| ❷ | 1.0 (+00) | 4.9 (–04) | 8.6 (–06) | 8.2 (–07) | 6.3 (–08) | 2.9 (–09) | 7.3 (–02) | 2.5 (–01) | 3.3 (–01) | 2.2 (–01) | 8.9 (–02) | 2.9 (–02) | ||
| χnir | 103 | ❸ | 1.0 (+00) | 4.9 (–04) | 8.7 (–06) | 8.2 (–07) | 6.3 (–08) | 2.9 (–09) | 7.3 (–02) | 2.5 (–01) | 3.3 (–01) | 2.2 (–01) | 8.9 (–02) | 2.9 (–02) |
| 105 | ❸ | 1.0 (+00) | 7.5 (–04) | 2.3 (–05) | 8.9 (–07) | 6.3 (–08) | 2.9 (–09) | 7.1 (–02) | 2.4 (–01) | 3.3 (–01) | 2.2 (–01) | 9.4 (–02) | 3.1 (–02) | |
| 107 | ❸ | 9.7 (–01) | 2.6 (–02) | 1.4 (–03) | 1.3 (–05) | 2.2 (–07) | 4.3 (–09) | 3.3 (–02) | 9.8 (–02) | 1.6 (–01) | 2.0 (–01) | 2.0 (–01) | 1.5 (–01) | |
| χopt/UV | 102 | ❸ | 1.0 (+00) | 5.0 (–04) | 9.0 (–06) | 8.5 (–07) | 6.4 (–08) | 3.0 (–09) | 7.3 (–02) | 2.5 (–01) | 3.3 (–01) | 2.2 (–01) | 9.0 (–02) | 3.0 (–02) |
| 103 | ❸ | 1.0 (+00) | 6.1 (–04) | 1.3 (–05) | 1.0 (–06) | 7.7 (–08) | 3.4 (–09) | 7.0 (–02) | 2.3 (–01) | 3.3 (–01) | 2.3 (–01) | 9.8 (–02) | 3.3 (–02) | |
| 104 | ❸ | 1.0 (+00) | 1.7 (–03) | 4.8 (–05) | 3.1 (–06) | 2.1 (–07) | 8.4 (–09) | 5.3 (–02) | 1.7 (–01) | 2.6 (–01) | 2.6 (–01) | 1.6 (–01) | 7.0 (–02) | |
| χopt/UV | 102 | ❹ | 1.0 (+00) | 6.5 (–04) | 1.4 (–05) | 1.5 (–06) | 1.5 (–07) | 1.4 (–08) | 7.2 (–02) | 2.4 (–01) | 3.3 (–01) | 2.2 (–01) | 9.2 (–02) | 3.1 (–02) |
| 103 | ❹ | 1.0 (+00) | 2.1 (–03) | 6.3 (–05) | 7.4 (–06) | 9.4 (–07) | 1.1 (–07) | 6.3 (–02) | 2.1 (–01) | 3.1 (–01) | 2.3 (–01) | 1.1 (–01) | 4.2 (–02) | |
| 104 | ❹ | 9.8 (–01) | 1.6 (–02) | 5.6 (–04) | 6.7 (–05) | 8.9 (–06) | 1.1 (–06) | 3.7 (–02) | 1.2 (–01) | 2.0 (–01) | 2.4 (–01) | 1.9 (–01) | 1.2 (–01) | |
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