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Table B.1

Greek symbols.

Parameter Unity Description

Surface fraction of the porous network covered by water molecules that form the clathrate structure
Surface fraction of the porous network covered by the pure ice species x
β Power law of the size distribution of dust grains
Δri m Thickness of each layer i
Δt s Time step
δ Obliquity
ϵ Infrared surface emissivity of the nucleus
ϕ x mol m-2 s-1 Free sublimation rate of the specie x
Φx mol m-2 s-1 Molar flow of gas x
φ Argument of the sub-solar meridian at perihelion
Molar fraction of the molecule x trapped during formation of MG clathrate (l = f)
     or released during dissociation of MG clathrate (l = d)
γ The true anomaly of the comet
λ m Mean free path of molecules in the porous network
mol m-2 Pa-1 s-1 Kinetic parameter of formation (k = f) or dissociation (k = d) of clathrate
mol m-2 Pa-1 s-1 Nominal kinetic parameter of formation (k = f) or dissociation (k = d) of clathrate
θ Latitude on the comet surface
θ s Cometocentric latitude of the sub-solar point
kg m-3 Mass density of amorphous water ice
kg m-3 Mass density of the solid or gas component l (l = d for dust, cl for clathrate,
     i for pure ices of elements x, or g for gas)
kg m-3 Mass density of the volatile molecule x trapped in amorphous ice
kg m-3 Bulk density of the solid component l (l = d for dust, cl for clathrate or i for pure ices of elements x
kg m-3 Mass density of gas x
σ J s-1 m-2 K-4 Stefan-Boltzmann constant
τ cr s Time of crystallization of the amorphous water ice
τ Tortuosity that is defined as the ratio of the length of a pore to the distance between its ends
ω s-1 Spin rotation period of the comet nucleus
ξ Solar zenith distance
Ψ, Ψi Porosity and initial porosity of the matrix

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