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Table 2
Adopted radial parameters for the 4d8, 4d75s and 4d75p configurations.
| Configuration | Parameter | Ab initio | Fitted | Ratio |
| (cm-1) | (cm-1) | |||
|
|
||||
| 4d8 | Eav | 10 882 | 10421 ± 21 | |
| F2(4d,4d) | 65 044 | 51938 ± 222 | 0.80 | |
| F4(4d,4d) | 42 149 | 35804 ± 554 | 0.85 | |
| α | 0 | 21 ± 5 | ||
| ζ4d | 1163 | 1180 ± 20 | 1.01 | |
| 4d75s | Eav | 36 719 | 37656 ± 26 | |
| F2(4d,4d) | 68 421 | 54908 ± 332 | 0.80 | |
| F4(4d,4d) | 44 587 | 39300 ± 466 | 0.88 | |
| α | 0 | 32 ± 2 | ||
| β | 0 | −462 ± 142 | ||
| ζ4d | 1256 | 1260 ± 10 | 1.00 | |
| G2(4d,5s) | 13 647 | 11376 ± 42 | 0.83 | |
| 4d75p | Eav | 74 500 | 77980 ± 16 | |
| F2(4d,4d) | 69 029 | 55106 ± 135 | 0.80 | |
| F4(4d,4d) | 45 033 | 38083 ± 194 | 0.85 | |
| α | 0 | 24 ± 2 | ||
| ζ4d | 1269 | 1269 ± 15 | 1.00 | |
| ζ5p | 1135 | 1406 ± 33 | 1.24 | |
| F2(4d,5p) | 17 482 | 14722 ± 134 | 0.84 | |
| G1(4d,5p) | 7027 | 5339 ± 57 | 0.76 | |
| G3(4d,5p) | 5685 | 3798 ± 144 | 0.67 | |
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