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Table 1

Spectral properties (attribution, position, width, integrated cross section, and oscillator strength) of the PAH bands considered for comparison with astrophysical data in this article.

Molecule Electronic transition λ air a FWHM σdλ f N max b
(Å) (Å) (10-16 cm2 Å) (cm-2)

anthracene S1 ← S0 3610.74c 0.34 19 0.016 5.3 × 1011
phenanthrene S1 ← S0 3409.21d 0.20 0.16 0.00016 6.2 × 1013
pyrene S2 ← S0 3208.22e 5.5 89 0.097 1.1 × 1011
3166.26e 4.7 30 0.033 3.4 × 1011
2,3-benzofluorene S1 ← S0 3344.16f 0.18 8.4 0.0085 1.2 × 1012
3266.63f 0.22 2.4 0.0025 4.2 × 1012
benzo[ghi]perylene S2 ← S0 3512.15g 8.2 9.9 0.009 1 × 1012
3501.76g 5.3 5.7 0.005 1.8 × 1012
hexabenzocoronene β-band 3344 ± 8h 900i

Notes. 

(a)

Band positions are given for air under standard conditions (see text);

(b)

an upper limit of the column density has been calculated assuming a detection limit with an equivalent width of 1 mÅ;

(d)

Rouillé et al. (2010);

(h)

extrapolated from Ne and Ar matrix measurements (Rouillé et al. 2009b);

(i)

calculated for Ne matrix spectra.

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