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Table 4:

Assignment of infrared absorption features produced by the radiolysis of the H2O:NH3:CO ice (1:0.6:0.4) by 46 MeV Ni ions at 13 K and after warming to 300 K.
Frequency Wavelength Temp. Molecule Notes
(cm-1) ($\mu$m) (K)    
2233 4.48 13 N2O [1,2]
2218-2200 4.51-4.54 300 nitriles$^\dag $ [8]
2168 4.61 13, 300 OCN- [1,3,4,7]
2147 4.66 300 aliph. isocyanide$^\dag $ [8]
$\sim$2112 4.73 300 NCO$_2^\dag $ [2]
1725 5.80 300 ester$^\dag $ [5]
1683 5.94 300 amides$^\dag $ [5]
1652 6.05 300 asym-N2O$_3^\dag $ [2]
1637 6.11 13 ?  
1593 6.28 300 NH3+CH2COO$^{-\dag }$ [6]
1558 6.42 300 ?  
1533 6.52 300 ?  
1506 6.64 300 NH3+CH2COO$^{-\dag }$ [6]
$\sim$1490 6.71 13 NH4+ [1,3,7]
1474 6.78 13 NO$_3^\dag $ [2]
1440 6.94 13 NH3+CH2COO$^{-\dag }$ [6]
1415 7.07 300 NH3+CH2COO$^{-\dag }$ [6]
$\sim$1370 7.30 13, 300 HMT$^\dag $ [5]
      HCOO- [5,9]
$\sim$1338 7.47 13, 300 NH3+CH2COO$^{-\dag }$ [6]
      NH2CH2COO$^{-\dag }$ [6]
      HCOO- [9]
1305 7.66 13 N2O$_3^\dag $; N2O$_4^\dag $ [2]
1283 7.80 300 N2O$^\dag $ [2]

$^\dag $Tentative assignment. [1] Proton bombardment of several ices (Hudson et al. 2001); [2] Electron bombardment of N2:CO2 (Jamieson et al. 2005); [3] Hudson & Moore (2000; [4] van Broekhuizen et al. 2005; [5] UV photolysis of H2O:NH3:CH3OH:CO:CO2 ice (Munoz Caro & Shutte 2003); [6] electron bombardment of CH3NH2:CO2 ice (Holtom et al. 2005); [7] UV photolysis of ammonia-containing ices (Demyk et al. 1998); [8] UV photolysis of N2:CH4 ices at various pressures (Imanaka et al. 2004); [9] proton bombardment of H2O:NH3:CO ice (Hudson & Moore 2001).


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