A stringent upper limit of the PH3 abundance at the cloud top of Venus

Vol. 643
1. Letters to the Editor

A stringent upper limit of the PH3 abundance at the cloud top of Venus

A recent candidate detection of the phosphine molecule (PH3) with JCMT and ALMA in the upper atmosphere of Venus has incited a great deal of public interest. Phosphine is not expected to survive long in the highly oxidizing atmosphere of Venus, and its tentative detection has therefore been speculated to reflect biological processes in the Venusian atmosphere. Encrenaz et al. use observations of a 10 micrometer transition of phosphine to set an upper limit on its abundance at and slightly above the top of the Venus clouds. That limit is, at the 3 sigma confidence level, a factor of four lower than the PH3 abundance derived from the tentative millimeter-wave detection. The millimeter-wave transition of PH3 probes higher levels of the Venus atmosphere than the 10 micrometer transition, leaving the two results formally compatible; however, the tight upper limit obtained by Encrenaz et al. sets very strong constraints on phosphine production in Venus.