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Table D.4

Possible DIB vibronic system of the major DIB λ6613 (ζσ)

Mode DIBvm$\[\mathrm{DIB}_{\text{v}}^m\]$ Å σ cm−1 σtha$\[\sigma_{\mathrm{th}}^a\]$ cm−1 q6613b$\[\mathrm{q}_{6613}^b\]$ EWc FWd Å R21e$\[\mathrm{R}_{21}^e\]$ Tf
000$\[0_0^0\]$ 6613 0 0 x 318 1.1 0.52 ζσ
V01$\[\mathrm{V}_0^1\]$ 6520l 216 x 0.97 48 1.0 0.54 ζσ
V02$\[\mathrm{V}_0^2\]$ 6425 442 432 0.91 21 0.7 0.70
6445?j 395? 432 0.93 40 0.6 0.77 ζσ
V03$\[\mathrm{V}_0^3\]$ 6330 678 658 0.93 16 0.7 0.63 ζσ
V04$\[\mathrm{V}_0^4\]$ 6245 892 845 0.95 7.2 0.5 0.60
W01$\[\mathrm{W}_0^1\]$ 6494g 278 x 0.87g 266 7.4 0.28g
6498 269 x 0.93 9.4 0.7 0.47
W02$\[\mathrm{W}_0^2\]$ 6376 553 556 0.95 50 0.8 0.73 ζσ
6377?j 561 556 0.90 15 0.6 1.1? ζσ
6367?j 585? 556 0.97 18 0.9 0.89 ζσ
W03$\[\mathrm{W}_0^3\]$ 6270h 829 834 0.97 134 1.2 0.41 σh
6271 825 834 0.91 30 0.5 0.33
W04$\[\mathrm{W}_0^4\]$ 6159 1115 1112 0.94 11 1.0 0.41
V01W01$\[\mathrm{V}_0^1 \mathrm{W}_0^1\]$ 6397 512 494 0.91 39 1.3 0.51 ζσ
V02W01$\[\mathrm{V}_0^2 \mathrm{W}_0^1\]$ 6318 707 720 0.90 147 4.8 0.33
V04W01$\[\mathrm{V}_0^4 \mathrm{W}_0^1\]$ 6498 1089 1072 0.93 9.4 0.7 0.47
V01W03$\[\mathrm{V}_0^1 \mathrm{W}_0^3\]$ 6185 1046 1045 0.94 12 0.5 0.58 ζσ
W01W03$\[\mathrm{W}_0^1 \mathrm{W}_0^3\]$ 6159 1114 1107 0.94 11 1.0 0.41
V02W03$\[\mathrm{V}_0^2 \mathrm{W}_0^3\]$ 6113k 1258 1260 0.96 33 0.7 0.79
6108k 1252 1260 0.93 14 0.5 0.57 ζσ
V01W02$\[\mathrm{V}_0^1 \mathrm{W}_0^2\]$ 6384?i 793 790 0.88i 1958 4.5 0.29 σi

m Expected vibronic DIBs, with origin at 6613 Å, and possible vibration modes V at 216 cm−1 and W at 278 cm−1, inferred from λ6520l and λ6494g, respectively.

a Expected wave number of the vibronic DIB.

b Regular Pearson correlation coefficient with λ6613.

c Equivalent width in HD 183143 sight line, measured by APO or inferred.

d APO DIB width (FWHM).

e Ratio of equivalent widths in HD 204827 to HD 183143, measured by APO or inferred.

f DIB family type of DIBv, from Fan et al. (2022). Transition DIBs between the ζ and σ families are denoted ζσ.

g Very broad DIB, possibly implying uncertain values for q6613 and R21.

h Major DIB, λ6269.66, classified as σ by Fan et al. (2022), close to the limit of ζσ DIBs in their Fig. B2.

i An additional DIB at about 6285 Å might be hidden within the very strong and broad DIB λ6284.

j Tentative identification, that may be wrong because of poor wave-number match, low correlation or poor R21 fit.

k λ6108 and λ6113 might also be part of the vibronic system of λ6196 (Table D.3).

l The profiles of the main DIB, λ6613, and the possible vibronic DIB, λ6520, are reported as highly correlated by Ebenbichler et al. (2024).

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