Table 2
Overview of the dataset and the fit quality.
By measurement uncertainty | By torsional state | ||||
---|---|---|---|---|---|
Unc.(a) | #(b) | RMS(c) | vt(d) | #(b) | WRMS (e) |
0.005 MHz | 147 | 0.0049 MHz | vt = 0 ← 0 | 3329 | 0.90 |
0.010 MHz | 1003 | 0.0100 MHz | vt = 1 ← 1 | 2731 | 0.90 |
0.020 MHz | 890 | 0.0175 MHz | vt = 2 ← 2 | 197 | 1.34 |
0.030 MHz | 841 | 0.0279 MHz | vt = 1 ← 0 | 5160 | 0.79 |
0.050 MHz | 556 | 0.0483 MHz | vt = 2 ← 0 | 507 | 0.89 |
0.100 MHz | 304 | 0.0959 MHz | vt = 2 ← 1 | 717 | 0.75 |
0.200 MHz | 3 | 0.1366 MHz | |||
2 × 10−4 cm−1 | 6473 | 1.6 × 10−4 cm−1 | |||
5 × 10−4 cm−1 | 58 | 1.5 × 10−4 cm−1 |
Notes. (a)Estimated measurement uncertainties for each data group. (b)Number of lines (left part) or transitions (right part) of each category in the least-squares fit. Note that due to blending 10 275 measured line frequencies correspond to 12 641 transitions in the fit. (c)Root-mean-square (RMS) deviation of corresponding data group. (d)Upper and lower state torsional quantum number vt. (e)Weighted root-mean-square (WRMS) deviation of corresponding data group.
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