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Fig. A.1

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Upper panel: Absorption profile of the C–H symmetric stretch mode of methyl cyanide, around 2940.9 cm−1 (3.400 µm), in pure and mixed ices. The ice spectra at different temperatures are indicated by different colors and labels. Bottom left: Peak position and FWHM of the C–H symmetric stretching mode of CH3CN in different ice mixtures at selected temperatures. Bottom right: relative band strengths of the C–H symmetric stretch band in different ice mixtures at 15 K.

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