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Table C.2.

Observed and calculated frequencies of c-C5H4CCH2

Transition νobsa Δνobsb νcalc Δνcald νobs − νcale Ref
(MHz) (MHz) (MHz) (MHz) (MHz)
21, 2- 11, 1 6533.9975 0.0020 6533.9997 0.0004 −0.0022 1
20, 2- 10, 1 6858.3532 0.0020 6858.3531 0.0002 0.0001 1
21, 1- 11, 0 7209.1178 0.0020 7209.1148 0.0004 0.0030 1
31, 3- 21, 2 9792.8921 0.0020 9792.8930 0.0006 −0.0009 1
30, 3- 20, 2 10254.6211 0.0020 10254.6211 0.0004 0.0000 1
32, 2- 22, 1 10307.2815 0.0020 10307.2792 0.0003 0.0023 1
32, 1- 22, 0 10360.0099 0.0020 10360.0094 0.0004 0.0005 1
31, 2- 21, 1 10805.2427 0.0020 10805.2412 0.0006 0.0015 1
41, 4- 31, 3 13042.5047 0.0020 13042.5048 0.0007 −0.0001 1
40, 4- 30, 3 13612.1720 0.0020 13612.1735 0.0005 −0.0015 1
42, 3- 32, 2 13732.7538 0.0020 13732.7509 0.0004 0.0029 1
43, 2- 33, 1 13768.4019 0.0020 13768.4014 0.0005 0.0005 1
43, 1- 33, 0 13770.3390 0.0020 13770.3417 0.0005 −0.0027 1
42, 2- 32, 1 13863.7014 0.0020 13863.7012 0.0006 0.0002 1
41, 3- 31, 2 14390.7930 0.0020 14390.7923 0.0007 0.0007 1
51, 5- 41, 4 16280.4664 0.0020 16280.4654 0.0009 0.0010 1
50, 5- 40, 4 16920.4988 0.0020 16920.5009 0.0007 −0.0021 1
52, 4- 42, 3 17149.4248 0.0020 17149.4194 0.0005 0.0054 1
53, 3- 43, 2 17220.7569 0.0020 17220.7543 0.0006 0.0026 1
53, 2- 43, 1 17227.5324 0.0020 17227.5312 0.0006 0.0012 1
52, 3- 42, 2 17407.7712 0.0020 17407.7712 0.0009 0.0000 1
51, 4- 41, 3 17961.4705 0.0020 17961.4710 0.0008 −0.0005 1
61, 6- 51, 5 19504.9824 0.0020 19504.9813 0.0010 0.0011 1
60, 6- 50, 5 20172.9326 0.0020 20172.9377 0.0011 −0.0051 1
62, 5- 52, 4 20555.1800 0.0500 20555.1215 0.0005 0.0586 2
65, 1- 55, 0 20646.8700 0.0500 20646.8382 0.0020 0.0318 2
65, 2- 55, 1 20646.8700 0.0500 20646.8370 0.0020 0.0330 2
63, 4- 53, 3 20678.2900 0.0500 20678.2760 0.0007 0.0140 2
63, 3- 53, 2 20696.3100 0.0500 20696.2793 0.0008 0.0307 2
62, 4- 52, 3 20996.5800 0.0500 20996.6225 0.0013 −0.0425 2
61, 5- 51, 4 21512.3113 0.0020 21512.3128 0.0009 −0.0015 1
71, 7- 61, 6 22714.9500 0.0500 22714.9139 0.0011 0.0361 2
70, 7- 60, 6 23368.6900 0.0500 23368.6772 0.0015 0.0128 2
72, 6- 62, 5 23947.7600 0.0500 23947.7488 0.0006 0.0112 2
76, 1- 66, 0 24085.9100 0.0500 24085.9553 0.0034 −0.0453 2
76, 2- 66, 1 24085.9100 0.0500 24085.9553 0.0034 −0.0453 2
75, 3- 65, 2 24096.3600 0.0500 24096.3213 0.0022 0.0388 2
75, 2- 65, 1 24096.3600 0.0500 24096.3279 0.0022 0.0321 2
73, 5- 63, 4 24140.5000 0.0500 24140.4484 0.0009 0.0516 2
73, 4- 63, 3 24180.7300 0.0500 24180.7009 0.0010 0.0291 2
72, 5- 62, 4 24628.6800 0.0500 24628.7239 0.0019 −0.0439 2
71, 6- 61, 5 25037.5386 0.0020 25037.5424 0.0010 −0.0038 1
81, 8- 71, 7 25909.8500 0.0500 25909.8088 0.0013 0.0412 2
80, 8- 70, 7 26513.6500 0.0500 26513.6530 0.0018 −0.0030 2
82, 7- 72, 6 27325.3300 0.0500 27325.2866 0.0009 0.0434 2
87, 2- 77, 1 27525.0300 0.0500 27524.9845 0.0054 0.0455 2
87, 1- 77, 0 27525.0300 0.0500 27524.9845 0.0054 0.0455 2
86, 2- 76, 1 27534.3500 0.0500 27534.3463 0.0038 0.0037 2
86, 3- 76, 2 27534.3500 0.0500 27534.3461 0.0038 0.0039 2
85, 3- 75, 2 27549.6600 0.0500 27549.6856 0.0025 −0.0256 2
85, 4- 75, 3 27549.6600 0.0500 27549.6590 0.0025 0.0010 2
83, 6- 73, 5 27606.0400 0.0500 27606.0689 0.0012 −0.0289 2
82, 6- 72, 5 28295.7200 0.0500 28295.6725 0.0026 0.0475 2
81, 7- 71, 6 28530.5400 0.0500 28530.5023 0.0014 0.0377 2
91, 9- 81, 8 29089.9000 0.0500 29089.8668 0.0016 0.0332 2
90, 9- 80, 8 29619.2800 0.0500 29619.2698 0.0022 0.0102 2
92, 8- 82, 7 30685.8700 0.0500 30685.8656 0.0012 0.0044 2
98, 1- 88, 0 30963.7400 0.0500 30963.8251 0.0080 −0.0851 2
98, 2- 88, 1 30963.7400 0.0500 30963.8251 0.0080 −0.0851 2
97, 3- 87, 2 30972.6200 0.0500 30972.6010 0.0060 0.0100 2
97, 2- 87, 1 30972.6200 0.0500 30972.6010 0.0060 0.0100 2
96, 4- 86, 3 30985.7800 0.0500 30985.7573 0.0043 0.0227 2
96, 3- 86, 2 30985.7800 0.0500 30985.7581 0.0043 0.0219 2
93, 7- 83, 6 31073.2100 0.0500 31073.2809 0.0016 −0.0709 2
93, 6- 83, 5 31217.3080 0.0200 31217.3077 0.0022 0.0003 3
93, 6- 83, 5 31217.2000 0.0500 31217.3077 0.0022 −0.1077 2
92, 7- 82, 6 31983.3580 0.0150 31983.3859 0.0033 −0.0279 3
91, 8- 81, 7 31983.7390 0.0100 31983.7384 0.0019 0.0007 3
101, 10- 91, 9 32255.8540 0.0100 32255.8600 0.0020 −0.0060 3
100, 10- 90, 9 32699.2590 0.0150 32699.2546 0.0024 0.0044 3
100, 10- 90, 9 32699.2400 0.0500 32699.2546 0.0024 −0.0146 2
102, 9- 92, 8 34027.8320 0.0150 34027.8258 0.0016 0.0063 3
102, 9- 92, 8 34027.8100 0.0500 34027.8258 0.0016 −0.0158 2
109, 1- 99, 0 34402.4400 0.0500 34402.4085 0.0114 0.0315 2
109, 2- 99, 1 34402.4400 0.0500 34402.4085 0.0114 0.0315 2
108, 3- 98, 2 34410.8900 0.0500 34410.8676 0.0088 0.0224 2
108, 2- 98, 1 34410.8900 0.0500 34410.8676 0.0088 0.0224 2
107, 3- 97, 2 34422.6900 0.0500 34422.7097 0.0066 −0.0197 2
107, 4- 97, 3 34422.6900 0.0500 34422.7097 0.0066 −0.0197 2
106, 4- 96, 3 34440.6000 0.0500 34440.5737 0.0048 0.0263 2
106, 5- 96, 4 34440.6000 0.0500 34440.5709 0.0048 0.0292 2
104, 7- 94, 6 34520.9400 0.0500 34520.9831 0.0026 −0.0431 2
104, 6- 94, 5 34532.0500 0.0500 34532.0806 0.0026 −0.0306 2
103, 8- 93, 7 34539.6790 0.0100 34539.6611 0.0023 0.0179 3
103, 8- 93, 7 34539.6900 0.0500 34539.6611 0.0023 0.0289 2
103, 7- 93, 6 34781.4170 0.0100 34781.4410 0.0033 −0.0240 3
103, 7- 93, 6 34781.4500 0.0500 34781.4410 0.0033 0.0090 2
101, 9- 91, 8 35389.3660 0.0100 35389.3691 0.0026 −0.0031 3
101, 9- 91, 8 35389.4100 0.0500 35389.3691 0.0026 0.0409 2
111, 11-101, 10 35409.0190 0.0100 35409.0038 0.0025 0.0152 3
111, 11-101, 10 35409.0300 0.0500 35409.0038 0.0025 0.0262 2
102, 8- 92, 7 35675.1550 0.0150 35675.1534 0.0042 0.0016 3
102, 8- 92, 7 35675.1200 0.0500 35675.1534 0.0042 −0.0334 2
110, 11-100, 10 35766.1920 0.0150 35766.2148 0.0028 −0.0228 3
110, 11-100, 10 35766.1700 0.0500 35766.2148 0.0028 −0.0448 2
112, 10-102, 9 37349.8080 0.0150 37349.7879 0.0022 0.0201 3
112, 10-102, 9 37349.7700 0.0500 37349.7879 0.0022 −0.0179 2
1110, 1-1010, 0 37840.6200 0.0500 37840.6800 0.0156 −0.0600 2
1110, 2-1010, 1 37840.6200 0.0500 37840.6800 0.0156 −0.0600 2
119, 3-109, 2 37848.9500 0.0500 37848.9767 0.0124 −0.0267 2
119, 2-108, 1 37848.9500 0.0500 37848.9767 0.0124 −0.0267 2
118, 3-108, 2 37860.0100 0.0500 37860.0017 0.0097 0.0083 2
118, 4-108, 3 37860.0100 0.0500 37860.0017 0.0097 0.0083 2
117, 4-107, 3 37875.5500 0.0500 37875.5615 0.0073 −0.0115 2
117, 5-107, 4 37875.5500 0.0500 37875.5614 0.0073 −0.0114 2
116, 5-106, 4 37899.1900 0.0500 37899.1807 0.0054 0.0093 2
116, 6-106, 5 37899.1900 0.0500 37899.1717 0.0054 0.0183 2
113, 9-103, 8 38002.3630 0.0200 38002.3561 0.0031 0.0069 3
114, 7-104, 6 38024.7700 0.0500 38024.8792 0.0035 −0.1092 2
113, 8-103, 7 38383.9030 0.0200 38383.9494 0.0048 −0.0464 3
113, 8-103, 7 38383.9600 0.0500 38383.9494 0.0048 0.0106 2
121, 12-111, 11 38550.7840 0.0150 38550.8045 0.0034 −0.0205 3
111, 10-101, 9 38739.8860 0.0100 38739.8829 0.0035 0.0031 3
111, 10-101, 9 38739.8600 0.0500 38739.8829 0.0035 −0.0229 2
120, 12-110, 11 38829.5150 0.0150 38829.4924 0.0035 0.0226 3
112, 9-102, 8 39354.9490 0.0300 39354.9605 0.0053 −0.0115 3
122, 11-112, 10 40650.7430 0.0200 40650.7284 0.0028 0.0146 3
123, 9-113, 8 42028.8380 0.0200 42028.8560 0.0067 −0.0180 3
121, 11-111, 10 42029.4960 0.0200 42029.4421 0.0044 0.0539 3
122, 10-112, 9 43009.5360 0.0150 43009.5066 0.0065 0.0294 3
141, 14-131, 13 44806.9500 0.0100 44806.9533 0.0059 −0.0033 3
133, 11-123, 10 44904.1230 0.0300 44904.1187 0.0052 0.0043 3
140, 14-130, 13 44964.6120 0.0150 44964.6223 0.0058 −0.0103 3
131, 12-121, 11 45255.5820 0.0150 45255.5507 0.0053 0.0313 3
151, 15-141, 14 47924.5000 0.0200 47924.4911 0.0076 0.0089 3
150, 15-140, 14 48039.8470 0.0200 48039.8698 0.0075 −0.0228 3
141, 13-131, 12 48420.6010 0.0200 48420.5784 0.0063 0.0227 3

Notes.

a

Observed frequencies.

b

Uncertainty of the observed frequeciencies (MHz).

c

Calculated frequencies resulting from the fit (MHz).

d

Predicted uncertainty of the calculated frequencies (MHz).

e

Observed minus calculated frequencies (MHz).

1

Laboratoraty data from McCarthy et al. (2020).

2

Laboratory data from Sakaizumi et al. (1993)

3

This work.

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