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Table 6

Truncated octahedral particle compositions.

i NC NH n NC (n) NH (n) NCH H/C XH [CH]/[CH2]
2 35 36 1 29 36 12 12 5 1.24 0.55 1.00
                       
3 84 64 1 78 64 40 12 26 0.82 0.45 3.33
2 66 64 16 24 26 0.97 0.49 0.67
                       
4 165 100 1 159 100 76 12 71 0.63 0.39 6.33
2 147 100 52 24 71 0.68 0.40 2.17
3 123 100 28 36 59 0.81 0.45 0.78
                       
5 286 144 1 280 144 120 12 148 0.51 0.34 10.00
2 268 144 96 24 148 0.54 0.35 4.00
3 244 144 72 36 136 0.59 0.37 2.00
4 208 144 36 54 118 0.69 0.41 0.67
                       
6 455 196 1 449 196 172 12 265 0.44 0.30 14.33
2 437 196 148 24 265 0.45 0.31 6.17
3 413 196 124 36 253 0.47 0.32 3.44
4 377 196 88 54 235 0.52 0.34 1.63
5 323 196 52 72 199 0.61 0.38 0.72
6 251 196 4 96 151 0.78 0.44 0.04
                       
7 680 256 1 674 256 232 12 430 0.38 0.28 19.33
2 662 256 208 24 430 0.39 0.28 8.67
3 638 256 184 36 418 0.40 0.29 5.11
4 602 256 148 54 400 0.43 0.30 2.74
5 548 256 112 72 364 0.47 0.32 1.56
6 476 256 64 96 316 0.54 0.35 0.67
7 380 256 16 120 244 0.67 0.40 0.13
                       
8 969 324 1 963 324 300 12 651 0.34 0.25 25.00
2 951 324 276 24 651 0.34 0.25 11.50
3 927 324 252 36 639 0.35 0.26 7.00
4 891 324 216 54 621 0.36 0.27 4.00
5 837 324 180 72 585 0.39 0.28 2.50
6 765 324 132 96 537 0.42 0.30 1.38
7 669 324 84 120 465 0.48 0.33 0.70
8 549 324 24 150 375 0.59 0.37 0.16

Notes. As a function of the number of atomic layers, i, and the number of atomic layer truncations, n. NC and NH are the total number of carbon and hydrogen atoms in the parent octahedron and NC (n) and NH (n) those in the truncated octahedron. NCH and the number of CHn groups on the surfaces, the number of carbon atoms in the bulk and XH the atomic hydrogen fraction.

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