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Table F.1
Peak position and FWHM of the methyl formate C=O stretching mode (1723.1 cm−1 /5.804 μm) in various matrices.
| Mixture | Temperature | λpeak | FWHM | ||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| HCOOCH3 | 15 | 1722.8 | 5.8044 | 30.94 | 0.1043 |
| HCOOCH3 : CO | 1733.4 | 5.7689 | 12.80 (*) | 0.0425 (*) | |
| HCOOCH3 : CH3OH | 1722.1 | 5.8068 | 17.57 | 0.0593 | |
| HCOOCH3 : H2O | 1712.5 | 5.8395 | 51.14 (*) | 0.1762 (*) | |
| HCOOCH3 | 30 | 1722.8 | 5.8044 | 30.75 | 0.1038 |
| HCOOCH3 : CO | 1733.0 | 5.7705 | 14.26 (*) | 0.0474 (*) | |
| 1739.5 | 5.7489 | − | − | ||
| HCOOCH3 : CH3OH | 1722.1 | 5.8068 | 16.28 | 0.0549 | |
| HCOOCH3 : H2O | 1712.7 | 5.8387 | 49.67 (*) | 0.1711 (*) | |
| HCOOCH3 | 50 | 1722.4 | 5.8060 | 30.61 | 0.1033 |
| HCOOCH3 : CO | 1726.7 | 5.7914 | 28.20 | 0.0950 | |
| HCOOCH3 : CH3OH | 1722.4 | 5.8060 | 14.72 | 0.0496 | |
| HCOOCH3 : H2O | 1714.2 | 5.8338 | 46.45 (*) | 0.1597 (*) | |
| HCOOCH3 | 80 | 1720.7 | 5.8117 | 30.38 | 0.1027 |
| HCOOCH3 : CO | 1725.5 | 5.7955 | 29.02 | 0.0978 | |
| HCOOCH3 : CH3OH | 1722.8 | 5.8044 | 13.27 | 0.0447 | |
| HCOOCH3 : H2O | 1715.6 | 5.8289 | 38.74 (*) | 0.1325 (*) | |
| HCOOCH3 | 100 | 1698.0 | 5.8893 | 5.659 | 0.0196 |
| 1709.8 | 5.8486 | − | − | ||
| HCOOCH3 : CO | 1718.0 | 5.8207 | 29.54 | 0.1000 | |
| HCOOCH3 : CH3OH | 1723.3 | 5.8028 | 13.11 | 0.0442 | |
| HCOOCH3 : H2O | 1715.1 | 5.8305 | 38.54 (*) | 0.1312 (*) | |
| HCOOCH3 | 120 | 1698.7 | 5.8868 | 5.239 | 0.0181 |
| 1710.5 | 5.8461 | − | − | ||
| HCOOCH3 : CO | 1699.2 | 5.8851 | 5.769 | 0.0200 | |
| HCOOCH3 : CH3OH | 1723.8 | 5.8011 | 13.85 | 0.0466 | |
| 1699.2 | 5.8851 | − | − | ||
| HCOOCH3 : H2O | 1716.1 | 5.8272 | 41.30 (*) | 0.1398 (*) | |
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