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Table D.1
Peak position and FWHM of the methyl formate CH3 rocking mode (1165.3 cm−1/8.582 μm) in various matrices.
| Mixture | Temperature | λpeak | FWHM | ||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| HCOOCH3 | 15 | 1165.3 | 8.5817 | 27.17 | 0.2009 |
| HCOOCH3 : CO | 1162.1 | 8.6048 | 10.53 | 0.0777 | |
| HCOOCH3 : H2CO | 1167.9 | 8.5622 | 22.75 | 0.1654 (*) | |
| HCOOCH3 : CH3OH | 1167.0 | 8.5693 | 23.01 | 0.1701 | |
| HCOOCH3 : H2O | 1173.0 | 8.5253 | 13.11 | 0.0953 | |
| HCOOCH3 : Apolar | 1170.1 | 8.5463 | 17.72 | 0.1293 | |
| HCOOCH3 | 30 | 1165.3 | 8.5817 | 26.94 | 0.1992 |
| HCOOCH3 : CO | 1161.6 | 8.6084 | 12.01 | 0.0887 | |
| HCOOCH3 : H2CO | 1167.7 | 8.5634 | 22.73 | 0.1653 (*) | |
| HCOOCH3 : CH3OH | 1165.8 | 8.5782 | 21.59 | 0.1596 | |
| HCOOCH3 : H2O | 1173.0 | 8.5253 | 12.75 | 0.0927 | |
| HCOOCH3 : Apolar | 1169.1 | 8.5534 | 18.23 | 0.1331 | |
| HCOOCH3 | 50 | 1165.3 | 8.5817 | 26.31 | 0.1945 |
| HCOOCH3 : CO | 1167.4 | 8.5658 | 23.14 | 0.1704 | |
| HCOOCH3 : H2CO | 1167.4 | 8.5658 | 22.50 | 0.1637 (*) | |
| HCOOCH3 : CH3OH | 1166.0 | 8.5763 | 19.69 | 0.1455 | |
| HCOOCH3 : H2O | 1172.5 | 8.5288 | 12.38 | 0.0901 | |
| HCOOCH3 : Apolar | 1167.9 | 8.5622 | 18.70 | 0.1366 | |
| HCOOCH3 | 80 | 1164.8 | 8.5853 | 25.35 | 0.1875 |
| HCOOCH3 : CO | 1167.4 | 8.5658 | 23.16 | 0.1706 | |
| HCOOCH3 : H2CO | 1167.0 | 8.5693 | 21.70 (*) | 0.1580 (*) | |
| HCOOCH3 : CH3OH | 1166.0 | 8.5764 | 17.49 | 0.1293 | |
| HCOOCH3 : H2O | 1172.3 | 8.5305 | 13.23 | 0.0964 | |
| HCOOCH3 : Apolar | 1166.5 | 8.5728 | 18.94 | 0.1385 | |
| HCOOCH3 | 100 | 1165.8 | 8.5782 | 2.854 | 0.0210 |
| 1177.1 | 8.4956 | − | − | ||
| HCOOCH3 : CO | 1163.8 | 8.5924 | 24.00 | 0.1776 | |
| HCOOCH3 : H2CO | 1176.8 | 8.4973 | 2.113 | 0.0153 | |
| HCOOCH3 : CH3OH | 1165.5 | 8.5799 | 16.70 | 0.1235 | |
| HCOOCH3 : H2O | 1171.8 | 8.5340 | 14.51 | 0.1060 | |
| HCOOCH3 : Apolar | 1165.5 | 8.5799 | 16.09 | 0.1186 | |
| HCOOCH3 | 120 | 1165.8 | 8.5782 | 2.742 | 0.0202 |
| 1176.8 | 8.4973 | − | − | ||
| HCOOCH3 : CO | 1171.1 | 8.5393 | 4.508 | 0.0328 | |
| 1165.8 | 8.5782 | − | − | ||
| HCOOCH3 : H2CO | 1174.2 | 8.5165 | 3.921 | 0.0285 | |
| 1166.0 | 8.5764 | − | − | ||
| HCOOCH3 : CH3OH | 1165.5 | 8.5799 | −(**) | −(**) | |
| HCOOCH3 : H2O | 1166.2 | 8.5746 | 14.03 | 0.1027 | |
| HCOOCH3 : Apolar | 1176.8 | 8.4973 | 1.258 | 0.0091 | |
| 1164.5 | 8.5870 | − | − | ||
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