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Table C.1
Peak position and FWHM of the methyl formate O−CH3 stretching mode (910.5 cm−1/10.98 μm) in various matrices.
| Mixture | Temperature | λpeak | FWHM | ||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| HCOOCH3 | 15 | 910.47 | 10.983 | 17.51 | 0.2108 |
| HCOOCH3 : CO | 914.33 | 10.937 | 9.909 | 0.1184 | |
| HCOOCH3 : H2CO | 911.20 | 10.975 | 13.10 | 0.1577 | |
| HCOOCH3 : CH3OH | 912.88 | 10.954 | 14.28 | 0.1711 | |
| HCOOCH3 : H2O | 913.61 | 10.946 | 17.72 | 0.2131 | |
| HCOOCH3 | 30 | 910.23 | 10.986 | 17.20 | 0.2071 |
| HCOOCH3 : CO | 914.33 | 10.937 | 11.48 | 0.1371 | |
| HCOOCH3 : H2CO | 911.20 | 10.975 | 12.83 | 0.1544 | |
| HCOOCH3 : CH3OH | 912.88 | 10.954 | 13.67 | 0.1638 | |
| HCOOCH3 : H2O | 912.88 | 10.954 | 17.34 | 0.2085 | |
| HCOOCH3 | 50 | 909.99 | 10.989 | 16.60 | 0.2000 |
| HCOOCH3 : CO | 912.16 | 10.963 | 16.19 | 0.1945 | |
| HCOOCH3 : H2CO | 911.20 | 10.975 | 12.36 | 0.1485 | |
| HCOOCH3 : CH3OH | 913.12 | 10.951 | 12.92 | 0.1548 | |
| HCOOCH3 : H2O | 913.85 | 10.943 | 16.51 | 0.1982 | |
| HCOOCH3 | 80 | 909.27 | 10.998 | 15.72 | 0.1896 |
| HCOOCH3 : CO | 910.47 | 10.983 | 15.63 | 0.1882 | |
| HCOOCH3 : H2CO | 911.20 | 10.975 | 11.90 | 0.1434 | |
| HCOOCH3 : CH3OH | 913.12 | 10.951 | 11.13 | 0.1335 | |
| HCOOCH3 : H2O | 912.88 | 10.954 | 16.06 | 0.1927 | |
| HCOOCH3 | 100 | 899.63 | 11.116 | 3.374 | 0.0417 |
| 904.93 | 11.051 | − | − | ||
| HCOOCH3 : CO | 909.51 | 10.995 | 15.21 | 0.1836 | |
| HCOOCH3 : H2CO | 907.58 | 11.018 | 7.982 | 0.0966 | |
| HCOOCH3 : CH3OH | 912.88 | 10.954 | 11.32 | 0.1357 | |
| HCOOCH3 : H2O | 914.09 | 10.940 | 15.60 | 0.1871 | |
| HCOOCH3 | 120 | 899.87 | 11.113 | 3.422 | 0.0422 |
| 905.17 | 11.048 | − | − | ||
| HCOOCH3 : CO | 899.38 | 11.119 | 2.295 | 0.0284 | |
| 905.17 | 11.048 | − | − | ||
| HCOOCH3 : H2CO | 901.07 | 11.098 | 2.418 | 0.0298 | |
| 905.41 | 11.045 | − | − | ||
| HCOOCH3 : CH3OH | 904.69 | 11.054 | 8.354(*) | 0.1025(*) | |
| 899.63 | 11.116 | − | − | ||
| HCOOCH3 : H2O | 915.05 | 10.928 | 15.87 | 0.1901 | |
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