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Table B.1
Peak position and FWHM of the methyl formate OCO deformation stretching mode (768.3 cm−1 /13.02 μm) in various matrices.
| Mixture | Temperature | λpeak | FWHM | ||
|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | |
| HCOOCH3 | 15 | 768.48 | 13.012 | 8.061 | 0.1361 |
| HCOOCH3 : CO | 768.25 | 13.017 | 3.404 | 0.0576 | |
| HCOOCH3 : H2CO | 770.42 | 12.980 | 5.089 | 0.0857 | |
| HCOOCH3 : CH3OH | 768.49 | 13.013 | 5.329 | 0.0902 | |
| HCOOCH3 : H2O | 777.65 | 12.859 | 13.11(*) | 0.2184(*) | |
| HCOOCH3 : Apolar | 769.94 | 12.988 | 4.941 | 0.0833 | |
| HCOOCH3 | 30 | 768.49 | 13.012 | 7.987 | 0.1349 |
| HCOOCH3 : CO | 768.49 | 13.012 | 4.479 | 0.0757 | |
| HCOOCH3 : H2CO | 770.42 | 12.980 | 4.927 | 0.0829 | |
| HCOOCH3 : CH3OH | 768.25 | 13.017 | 5.050 | 0.0855 | |
| HCOOCH3 : H2O | 777.65 | 12.859 | 13.37(*) | 0.2228(*) | |
| HCOOCH3 : Apolar | 769.94 | 12.988 | 4.743 | 0.0800 | |
| HCOOCH3 | 50 | 768.49 | 13.012 | 7.785 | 0.1314 |
| HCOOCH3 : CO | 768.73 | 13.008 | 7.296 | 0.1231 | |
| HCOOCH3 : H2CO | 770.66 | 12.976 | 4.747 | 0.0799 | |
| HCOOCH3 : CH3OH | 768.25 | 13.017 | 4.709 | 0.0797 | |
| HCOOCH3 : H2O | 777.65 | 12.859 | 13.73(*) | 0.2289(*) | |
| HCOOCH3 : Apolar | 769.94 | 12.988 | 4.523 | 0.0763 | |
| HCOOCH3 | 80 | 768.25 | 13.017 | 7.396 | 0.1249 |
| HCOOCH3 : CO | 768.25 | 13.017 | 7.025 | 0.1186 | |
| HCOOCH3 : H2CO | 770.42 | 12.980 | 4.385 | 0.0739 | |
| HCOOCH3 : CH3OH | 768.25 | 13.017 | 4.336 | 0.0734 | |
| HCOOCH3 : H2O | 769.94 | 12.988 | 14.21(*) | 0.2374(*) | |
| HCOOCH3 : Apolar | 769.94 | 12.988 | 4.290 | 0.0724 | |
| HCOOCH3 | 100 | 768.97 | 13.004 | 2.095 | 0.0354 |
| 775.24 | 12.899 | − | − | ||
| HCOOCH3 : CO | 768.25 | 13.017 | 6.623 | 0.1119 | |
| HCOOCH3 : H2CO | 768.97 | 13.004 | 5.281 | 0.0892 | |
| HCOOCH3 : CH3OH | 768.25 | 13.017 | 4.279 | 0.0725 | |
| HCOOCH3 : H2O | 769.94 | 12.988 | 13.51(*) | 0.2261(*) | |
| HCOOCH3 : Apolar | 769.69 | 12.992 | 4.484 | 0.0757 | |
| HCOOCH3 | 120 | 768.73 | 13.008 | 1.971 | 0.0333 |
| 775.00 | 13.008 | − | − | ||
| HCOOCH3 : CO | 768.45 | 13.017 | 1.710 | 0.0287 | |
| 775.24 | 12.899 | − | − | ||
| HCOOCH3 : H2CO | 768.97 | 13.004 | 1.546 | 0.0262 | |
| 775.24 | 12.899 | − | − | ||
| HCOOCH3 : CH3OH | 768.25 | 13.017 | 3.289 | 0.0558 | |
| 775.24 | 12.899 | − | − | ||
| HCOOCH3 : H2O | 769.21 | 13.000 | 6.784 | 0.1147 | |
| HCOOCH3 : Apolar | 768.49 | 13.013 | 4.505 | 0.0762 | |
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