Table 1
Spectroscopic constants of propiolamide in the ground state and three excited vibrational states (A-reduction, Ir -representation).
| Ground state | vin = 1 | vout = 1 | vinv = 1 | |
|---|---|---|---|---|
| A / MHz | 11 417.92091 (11)(a) | 11 306.86167 (25) | 11 537.98892 (27) | 11 397.27733 (18) |
| B / MHz | 4135.477101 (40) | 4153.949250 (78) | 4146.28849 (10) | 4131.104876 (83) |
| C / MHz | 3032.592907(35) | 3036.029785 (61) | 3041.801213 (72) | 3032.360188 (56) |
| ΔJ / kHz | 0.579701 (18) | 0.612639 (36) | 0.594171 (59) | 0.578258 (51) |
| ΔJK / kHz | 20.86142 (18) | 19.27979 (36) | 21.82228 (41) | 20.73217 (36) |
| ΔK / kHz | −10.05819 (20) | −16.51167 (89) | −2.7538 (10) | −9.93128 (41) |
| δJ / kHz | 0.1753084 (80) | 0.190158 (18) | 0.177915 (29) | 0.174458 (25) |
| δK / kHz | 12.16107 (24) | 11.28587 (43) | 13.08620 (65) | 12.08963 (55) |
| ΦJ / Hz | 0.0003369 (31) | 0.0005094 (77) | 0.000273 (17) | 0.000370 (15) |
| ΦJK / Hz | 0.19762 (12) | 0.16406 (25) | 0.22129 (38) | 0.19630 (28) |
| ΦKJ / Hz | −0.47001 (41) | −0.55885 (90) | −0.3560 (13) | −0.46592 (78) |
| ΦK / Hz | 0.30222 (35) | −0.5968 (10) | 1.1713 (13) | 0.30279 (69) |
| ϕJ / Hz | 0.0001448 (15) | 0.0002278 (41) | 0.0001229 (89) | 0.0001680 (78) |
| ϕJK / Hz | 0.095653 (64) | 0.08057 (11) | 0.10591 (22) | 0.09532 (19) |
| ϕK / Hz | 0.6385(11) | 0.3538 (18) | 0.9125 (29) | 0.6349 (22) |
| LJJK / mHz | −0.0011188 (88) | −0.001301 (27) | −0.000844 (35) | −0.001004 (28) |
| LKKJ / mHz | ... | 0.05208 (54) | −0.05083 (72) | ... |
| χaa / MHz | 1.8157 (22) | 1.8157(b) | 1.8157(b) | 1.8157(b) |
| χbb − χcc / MHz | 6.0012 (44) | 6.336 (40) | 6.212 (48) | 5.796 (44) |
| Jmin∕Jmax | 0 / 75 | 3 / 71 | 3 / 71 | 3 / 71 |
| Ka,min∕Ka,max | 0 / 32 | 0 / 25 | 0 / 25 | 0 / 25 |
| σfit (c) MHz | 0.023 | 0.032 | 0.032 | 0.026 |
| N (d) | 1924 | 1482 | 1219 | 978 |
Notes. (a) The numbers in parentheses are 1σ uncertainties (67% confidence level) in units of the last decimal digit. The SPFIT/SPCAT program package (Pickett 1991) was used for the analysis. (b)Fixed to the ground state value owing to the limited hyperfine data set in excited vibrational states. (c) Root mean square deviation of the fit. (d)Number of distinct frequency lines in the fit.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.