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Table B.18
Thermochemical properties of Ti4C4 at 1 bar.
| T |  |
So | −[Go − Ho(298.15 K)]/T | Ho − Ho(298.15 K) | ΔfHo | ΔfGo | logKf | |
|---|---|---|---|---|---|---|---|---|
| (K) | J K−1 mol−1 | kJ mol−1 | ||||||
| 100 | 45.073 | 248.232 | 421.762 | −17.353 | 1175.377 | 1154.239 | −Infinity | |
| 200 | 89.948 | 293.078 | 346.183 | −10.621 | 1173.137 | 1133.969 | −296.156 | |
| 298.15 | 123.665 | 335.836 | 335.836 | 0.000 | 1171.690 | 1115.089 | −195.355 | |
| 300 | 124.152 | 336.603 | 335.840 | 0.229 | 1171.667 | 1114.736 | −194.089 | |
| 400 | 144.319 | 375.370 | 340.988 | 13.753 | 1170.647 | 1095.917 | −143.109 | |
| 500 | 156.171 | 408.981 | 351.305 | 28.838 | 1169.464 | 1077.366 | −112.549 | |
| 600 | 163.478 | 438.170 | 363.405 | 44.859 | 1167.873 | 1059.089 | −92.200 | |
| 700 | 168.225 | 463.769 | 375.953 | 61.471 | 1165.841 | 1041.114 | −77.687 | |
| 800 | 171.455 | 486.471 | 388.376 | 78.476 | 1163.462 | 1023.453 | −66.823 | |
| 900 | 173.742 | 506.818 | 400.425 | 95.754 | 1160.636 | 1006.115 | −58.392 | |
| 1000 | 175.415 | 525.227 | 412.000 | 113.227 | 1157.133 | 989.126 | −51.666 | |
| 1100 | 176.674 | 542.019 | 423.068 | 130.846 | 1152.716 | 972.533 | −46.181 | |
| 1200 | 177.643 | 557.445 | 433.632 | 148.576 | 1131.462 | 956.856 | −41.650 | |
| 1300 | 178.404 | 571.705 | 443.711 | 166.392 | 1128.162 | 942.438 | −37.867 | |
| 1400 | 179.013 | 584.958 | 453.332 | 184.276 | 1124.450 | 928.290 | −34.634 | |
| 1500 | 179.507 | 597.335 | 462.525 | 202.215 | 1120.293 | 914.423 | −31.842 | |
| 1600 | 179.914 | 608.941 | 471.317 | 220.198 | 1115.636 | 900.844 | −29.409 | |
| 1700 | 180.252 | 619.866 | 479.737 | 238.219 | 1110.437 | 887.570 | −27.271 | |
| 1800 | 180.536 | 630.184 | 487.811 | 256.271 | 1104.649 | 874.638 | −25.381 | |
| 1900 | 180.778 | 639.958 | 495.564 | 274.349 | 1098.219 | 862.022 | −23.698 | |
| 2000 | 180.984 | 649.242 | 503.017 | 292.449 | 1032.355 | 851.591 | −22.241 | |
| 2200 | 181.317 | 666.520 | 517.109 | 328.705 | 1010.595 | 834.560 | −19.815 | |
| 2400 | 181.571 | 682.318 | 530.227 | 365.019 | 988.629 | 819.530 | −17.836 | |
| 2600 | 181.769 | 696.870 | 542.493 | 401.379 | 966.457 | 806.333 | −16.199 | |
| 2800 | 181.927 | 710.355 | 554.008 | 437.773 | 944.095 | 794.858 | −14.828 | |
| 3000 | 182.054 | 722.920 | 564.855 | 474.196 | 921.542 | 784.982 | −13.667 | |
| 3200 | 182.158 | 734.680 | 575.104 | 510.642 | 898.808 | 776.619 | −12.677 | |
| 3400 | 182.245 | 745.734 | 584.820 | 547.106 | 875.892 | 769.683 | −11.825 | |
| 3600 | 182.317 | 756.160 | 594.053 | 583.587 | 852.805 | 764.101 | −11.087 | |
| 3800 | 182.379 | 766.025 | 602.846 | 620.081 | −801.917 | 835.970 | −11.491 | |
| 4000 | 182.431 | 775.388 | 611.241 | 656.587 | −816.131 | 922.541 | −12.047 | |
| 4500 | 182.533 | 796.896 | 630.698 | 747.890 | −855.984 | 1142.178 | −13.258 | |
| 5000 | 182.606 | 816.144 | 648.297 | 839.237 | −901.245 | 1366.595 | −14.276 | |
| 6000 | 182.701 | 849.469 | 679.133 | 1022.017 | −1004.029 | 1829.597 | −15.928 | |
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