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Table B.17
Thermochemical properties of Ti4C3 at 1 bar.
| T |  |
So | −[Go − Ho(298.15 K)]/T | Ho − Ho(298.15 K) | ΔfHo | ΔfGo | logKf | |
|---|---|---|---|---|---|---|---|---|
| (K) | J K−1 mol−1 | kJ mol−1 | ||||||
| 100 | 53.997 | 272.972 | 448.402 | −17.543 | 1307.526 | 1283.819 | −Infinity | |
| 200 | 90.784 | 322.103 | 373.308 | −10.241 | 1306.182 | 1260.592 | −Infinity | |
| 298.15 | 115.657 | 363.434 | 363.434 | 0.000 | 1305.020 | 1238.479 | −216.972 | |
| 300 | 116.011 | 364.151 | 363.438 | 0.214 | 1304.998 | 1238.064 | −215.562 | |
| 400 | 130.568 | 399.737 | 368.190 | 12.619 | 1303.882 | 1215.920 | −158.780 | |
| 500 | 139.042 | 429.883 | 377.593 | 26.145 | 1302.466 | 1194.085 | −124.743 | |
| 600 | 144.239 | 455.747 | 388.517 | 40.338 | 1300.625 | 1172.575 | −102.080 | |
| 700 | 147.605 | 478.267 | 399.764 | 54.952 | 1298.368 | 1151.409 | −85.917 | |
| 800 | 149.892 | 498.148 | 410.843 | 69.844 | 1295.797 | 1130.586 | −73.818 | |
| 900 | 151.508 | 515.913 | 421.549 | 84.928 | 1292.812 | 1110.107 | −64.428 | |
| 1000 | 152.689 | 531.951 | 431.800 | 100.151 | 1289.182 | 1089.994 | −56.934 | |
| 1100 | 153.577 | 546.557 | 441.579 | 115.476 | 1284.665 | 1070.287 | −50.823 | |
| 1200 | 154.261 | 559.960 | 450.893 | 130.880 | 1263.336 | 1051.505 | −45.770 | |
| 1300 | 154.797 | 572.338 | 459.766 | 146.344 | 1259.983 | 1033.986 | −41.545 | |
| 1400 | 155.226 | 583.833 | 468.221 | 161.857 | 1256.240 | 1016.743 | −37.934 | |
| 1500 | 155.574 | 594.562 | 476.290 | 177.408 | 1252.069 | 999.781 | −34.815 | |
| 1600 | 155.861 | 604.619 | 484.000 | 192.990 | 1247.416 | 983.107 | −32.095 | |
| 1700 | 156.099 | 614.082 | 491.377 | 208.599 | 1242.237 | 966.738 | −29.704 | |
| 1800 | 156.299 | 623.016 | 498.444 | 224.230 | 1236.485 | 950.708 | −27.588 | |
| 1900 | 156.469 | 631.477 | 505.225 | 239.879 | 1230.105 | 934.993 | −25.704 | |
| 2000 | 156.614 | 639.512 | 511.740 | 255.543 | 1164.304 | 921.458 | −24.066 | |
| 2200 | 156.848 | 654.460 | 524.045 | 286.912 | 1142.713 | 898.214 | −21.326 | |
| 2400 | 157.027 | 668.125 | 535.491 | 318.321 | 1120.965 | 876.950 | −19.086 | |
| 2600 | 157.167 | 680.708 | 546.184 | 349.762 | 1099.059 | 857.501 | −17.227 | |
| 2800 | 157.277 | 692.367 | 556.214 | 381.228 | 1077.011 | 839.747 | −15.665 | |
| 3000 | 157.367 | 703.228 | 565.657 | 412.713 | 1054.816 | 823.573 | −14.339 | |
| 3200 | 157.440 | 713.394 | 574.577 | 444.215 | 1032.486 | 808.883 | −13.203 | |
| 3400 | 157.501 | 722.947 | 583.026 | 475.731 | 1010.019 | 795.598 | −12.223 | |
| 3600 | 157.552 | 731.957 | 591.052 | 507.257 | 987.422 | 783.637 | −11.370 | |
| 3800 | 157.595 | 740.482 | 598.694 | 538.793 | −666.766 | 849.096 | −11.671 | |
| 4000 | 157.632 | 748.572 | 605.988 | 570.337 | −680.405 | 929.231 | −12.134 | |
| 4500 | 157.704 | 767.155 | 622.883 | 649.225 | −718.634 | 1132.648 | −13.147 | |
| 5000 | 157.755 | 783.785 | 638.156 | 728.143 | −762.012 | 1340.638 | −14.005 | |
| 6000 | 157.822 | 812.573 | 664.900 | 886.040 | −860.257 | 1770.197 | −15.411 | |
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