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Table B.16

Thermochemical properties of Ti4C2 at 1 bar.

T So −[GoHo(298.15 K)]/T HoHo(298.15 K) ΔfHo ΔfGo logKf


(K) J K−1 mol−1 kJ mol−1
100 53.151 263.864 426.574 −16.271 1343.127 1320.235 −Infinity
200 84.348 310.990 357.445 −9.291 1341.787 1297.803 −Infinity
298.15 103.078 348.538 348.538 0.000 1340.340 1276.529 −223.638
300 103.337 349.177 348.540 0.191 1340.311 1276.132 −222.190
400 113.847 380.512 352.740 11.109 1338.731 1254.973 −163.880
500 119.854 406.638 360.982 22.828 1336.834 1234.245 −128.938
600 123.503 428.853 370.490 35.018 1334.568 1213.935 −105.680
700 125.853 448.093 380.233 47.502 1331.954 1194.032 −89.098
800 127.443 465.020 389.795 60.180 1329.090 1174.520 −76.687
900 128.565 480.109 399.007 72.992 1325.868 1155.387 −67.056
1000 129.383 493.708 407.808 85.900 1322.046 1136.644 −59.371
1100 129.998 506.078 416.188 98.879 1317.377 1118.323 −53.104
1200 130.470 517.418 424.158 111.912 1295.928 1100.940 −47.922
1300 130.841 527.883 431.739 124.987 1292.485 1084.830 −43.588
1400 131.137 537.597 438.958 138.095 1288.677 1068.999 −39.884
1500 131.377 546.659 445.839 151.230 1284.464 1053.453 −36.684
1600 131.575 555.150 452.408 164.387 1279.791 1038.201 −33.893
1700 131.739 563.137 458.689 177.562 1274.610 1023.253 −31.440
1800 131.877 570.676 464.703 190.752 1268.874 1008.641 −29.269
1900 131.994 577.815 470.471 203.954 1262.526 994.343 −27.336
2000 132.094 584.592 476.008 217.167 1196.773 982.225 −25.653
2200 132.256 597.198 486.461 243.621 1175.323 961.804 −22.836
2400 132.379 608.719 496.176 270.103 1153.771 943.351 −20.531
2600 132.475 619.326 505.247 296.606 1132.112 926.691 −18.617
2800 132.551 629.153 513.750 323.127 1110.361 911.704 −17.008
3000 132.613 638.307 521.753 349.661 1088.511 898.272 −15.640
3200 132.663 646.873 529.309 376.206 1066.572 886.306 −14.467
3400 132.705 654.922 536.463 402.761 1044.541 875.717 −13.453
3600 132.740 662.513 543.256 429.324 1022.426 866.427 −12.571
3800 132.770 669.696 549.724 455.892 −631.238 934.522 −12.846
4000 132.796 676.511 555.894 482.467 −644.309 1017.271 −13.284
4500 132.845 692.166 570.183 548.922 −680.932 1227.086 −14.243
5000 132.880 706.174 583.094 615.398 −722.440 1441.280 −15.057
6000 132.927 730.421 605.689 748.393 −816.165 1882.653 −16.390

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