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Table B.15
Thermochemical properties of Ti4C at 1 bar.
| T |  |
So | −[Go − Ho(298.15 K)]/T | Ho − Ho(298.15 K) | ΔfHo | ΔfGo | logKf | |
|---|---|---|---|---|---|---|---|---|
| (K) | J K−1 mol−1 | kJ mol−1 | ||||||
| 100 | 56.425 | 272.031 | 426.841 | −15.481 | 1433.256 | 1409.453 | −Infinity | |
| 200 | 80.219 | 319.392 | 361.942 | −8.510 | 1432.233 | 1385.953 | −Infinity | |
| 298.15 | 91.748 | 353.859 | 353.859 | 0.000 | 1430.670 | 1363.562 | −238.886 | |
| 300 | 91.898 | 354.427 | 353.860 | 0.170 | 1430.636 | 1363.144 | −237.340 | |
| 400 | 97.833 | 381.785 | 357.550 | 9.694 | 1428.685 | 1340.933 | −175.104 | |
| 500 | 101.110 | 404.016 | 364.690 | 19.663 | 1426.364 | 1319.255 | −137.819 | |
| 600 | 103.068 | 422.651 | 372.841 | 29.886 | 1423.709 | 1298.077 | −113.005 | |
| 700 | 104.318 | 438.650 | 381.126 | 40.267 | 1420.765 | 1277.369 | −95.317 | |
| 800 | 105.159 | 452.648 | 389.211 | 50.750 | 1417.627 | 1257.094 | −82.078 | |
| 900 | 105.750 | 465.078 | 396.961 | 61.305 | 1414.183 | 1237.231 | −71.806 | |
| 1000 | 106.181 | 476.251 | 404.342 | 71.909 | 1410.180 | 1217.778 | −63.609 | |
| 1100 | 106.503 | 486.393 | 411.347 | 82.551 | 1405.368 | 1198.765 | −56.923 | |
| 1200 | 106.751 | 495.678 | 417.993 | 93.222 | 1383.808 | 1180.701 | −51.394 | |
| 1300 | 106.945 | 504.236 | 424.302 | 103.914 | 1380.281 | 1163.917 | −46.766 | |
| 1400 | 107.100 | 512.172 | 430.298 | 114.623 | 1376.414 | 1147.419 | −42.810 | |
| 1500 | 107.225 | 519.571 | 436.006 | 125.347 | 1372.164 | 1131.209 | −39.391 | |
| 1600 | 107.328 | 526.499 | 441.448 | 136.082 | 1367.474 | 1115.293 | −36.410 | |
| 1700 | 107.414 | 533.013 | 446.644 | 146.827 | 1362.295 | 1099.684 | −33.789 | |
| 1800 | 107.486 | 539.159 | 451.615 | 157.579 | 1356.578 | 1084.407 | −31.468 | |
| 1900 | 107.547 | 544.976 | 456.377 | 168.338 | 1350.266 | 1069.448 | −29.401 | |
| 2000 | 107.600 | 550.497 | 460.946 | 179.102 | 1284.563 | 1056.663 | −27.597 | |
| 2200 | 107.684 | 560.764 | 469.561 | 200.646 | 1263.259 | 1034.899 | −24.571 | |
| 2400 | 107.748 | 570.142 | 477.557 | 222.203 | 1241.905 | 1015.091 | −22.092 | |
| 2600 | 107.798 | 578.775 | 485.016 | 243.773 | 1220.498 | 997.054 | −20.031 | |
| 2800 | 107.838 | 586.770 | 492.002 | 265.351 | 1199.046 | 980.668 | −18.294 | |
| 3000 | 107.870 | 594.216 | 498.571 | 286.936 | 1177.543 | 965.818 | −16.816 | |
| 3200 | 107.896 | 601.184 | 504.769 | 308.527 | 1155.998 | 952.408 | −15.546 | |
| 3400 | 107.918 | 607.730 | 510.635 | 330.123 | 1134.405 | 940.347 | −14.446 | |
| 3600 | 107.937 | 613.903 | 516.202 | 351.723 | 1112.772 | 929.557 | −13.487 | |
| 3800 | 107.952 | 619.743 | 521.499 | 373.326 | −540.365 | 996.127 | −13.692 | |
| 4000 | 107.965 | 625.284 | 526.551 | 394.933 | −552.867 | 1077.321 | −14.068 | |
| 4500 | 107.991 | 638.011 | 538.243 | 448.958 | −587.881 | 1283.120 | −14.894 | |
| 5000 | 108.009 | 649.398 | 548.799 | 502.995 | −627.516 | 1493.099 | −15.598 | |
| 6000 | 108.033 | 669.105 | 567.257 | 611.089 | −716.720 | 1925.446 | −16.762 | |
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