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Table B.14

Thermochemical properties of Ti3C4 at 1 bar.

T So −[GoHo(298.15 K)]/T HoHo(298.15 K) ΔfHo ΔfGo logKf


(K) J K−1 mol−1 kJ mol−1
100 49.256 261.892 421.362 −15.947 1218.524 1195.194 −Infinity
200 82.370 306.123 352.983 −9.372 1218.044 1172.021 −306.095
298.15 106.529 343.928 343.928 0.000 1217.700 1149.516 −201.386
300 106.879 344.589 343.929 0.198 1217.693 1149.091 −200.071
400 121.810 377.573 348.325 11.699 1217.263 1126.282 −147.074
500 131.338 405.871 357.075 24.398 1216.435 1103.624 −115.293
600 137.719 430.434 367.301 37.880 1215.130 1081.178 −94.123
700 142.154 452.031 377.894 51.896 1213.390 1058.986 −79.021
800 145.332 471.244 388.384 66.288 1211.323 1037.065 −67.712
900 147.672 488.515 398.566 80.954 1208.876 1015.423 −58.932
1000 149.436 504.180 408.357 95.823 1205.890 994.082 −51.925
1100 150.794 518.499 417.728 110.848 1202.194 973.076 −46.207
1200 151.858 531.676 426.683 125.992 1185.849 952.791 −41.473
1300 152.707 543.874 435.234 141.232 1182.953 933.486 −37.507
1400 153.393 555.224 443.403 156.549 1179.733 914.418 −34.117
1500 153.956 565.834 451.216 171.927 1176.165 895.590 −31.187
1600 154.422 575.792 458.694 187.357 1172.210 877.010 −28.631
1700 154.812 585.172 465.860 202.830 1167.836 858.688 −26.384
1800 155.142 594.036 472.737 218.338 1163.007 840.650 −24.395
1900 155.424 602.438 479.345 233.877 1157.686 822.876 −22.622
2000 155.666 610.422 485.701 249.443 1107.780 806.768 −21.070
2200 156.057 625.287 497.725 280.637 1090.406 777.502 −18.460
2400 156.358 638.889 508.930 311.901 1072.837 749.831 −16.319
2600 156.593 651.422 519.415 343.218 1055.070 723.632 −14.538
2800 156.781 663.042 529.264 374.577 1037.120 698.813 −13.036
3000 156.933 673.871 538.548 405.970 1018.985 675.281 −11.757
3200 157.057 684.010 547.326 437.390 1000.672 652.960 −10.658
3400 157.161 693.541 555.649 468.833 982.183 631.796 −9.706
3600 157.248 702.533 563.562 500.295 963.524 611.721 −8.876
3800 157.322 711.042 571.101 531.774 −278.901 649.815 −8.932
4000 157.385 719.119 578.303 563.266 −290.986 699.006 −9.128
4500 157.508 737.676 595.000 642.043 −324.615 824.703 −9.573
5000 157.597 754.287 610.112 720.873 −362.553 954.417 −9.971
6000 157.712 783.051 636.611 878.638 −448.383 1225.689 −10.670

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