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Table 4

Most important reactions to H2S in the model.

Visual extinction TMC 1

Minissale bare Minissale ice
H2S production

Av ~ 5 mag s-H + s-HS → H2S (91.0%) s-H + s-HS → H2S (90.3%)
H3CS+ + e→ H2S + CH (8.2%) H3CS+ + e→ H2S + CH (9.2%)

Av ~ 20 mag s-H + s-HS → H2S (55.1%) s-H + s-HS → H2S (43.6%)
H3S+ + e→ H + H2S (31.9%) H3S+ + e→ H + H2S (43.3%)

H2S destruction

Av ~ 5 mag H2S + S+ → H2 + S (40.1%) H2S + S+ → H2 + S (39.1%)
C + H2S → HCS + H (16.7%) C + H2S → HCS + H (18.0%)

Av ~ 20 mag H2S + H H2 + H3S+(†) (51.7%) H2S + H H2 + H3S+ (72.9%)
H2S + S+ → H2 + S (11.2%) H2S + H+ → H + H2S+ (6.4%)

Visual extinction Barnard 1b

Minissale bare Minissale ice

H2S production

Av ~ 5 mag s-H + s-HS → H2S (99.2%) s-H + s-HS → H2S (85.4%)
S + H2S+ → H2S + S+ (0.3%) s-H2S → H2S (0.3%)

Av ~ 70 mag H3S+ + e→ H + H2S (48.4%) H3S+ + e→ H + H2S (47.0%)
s-H + s-HS → H2S (42.8%) s-H + s-HS → H2S (46.8%)

H2S destruction

Av ~ 5 mag H2S + S+ → H2 + S (39.2%) H2S + S+ → H2 + S (38.0%)
C + H2S → HCS + H (32.1%) C + H2S → HCS + H (32.4%)

Av ~ 70 mag H2S + H H2 + H3S+ (73.8%) H2S + H H2 + H3S+ (69.8%)
H2S + H+ → H + H2S+ (10.9%) H2S + H+ → H + H2S+ (20.6%)

Notes. (†) This reaction recycles H2S since the products are reactants in the production reactions.

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