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Table B.15
Peak position and FWHM of the ethanol CH3 s-deformation mode at 7.240 μm.
| Mixture | Temperature | λpeak,−baseline | λpeak,−matrix | FWHM | |||
|---|---|---|---|---|---|---|---|
| (K) | (cm−1) | (μm) | (cm−1) | (μm) | (cm−1) | (μm) | |
| CH3CH2OH | 15 | 1381.3 | 7.2397 | – | – | 20.7 | 0.1088* |
| CH3CH2OH:H2O | 1379.8 | 7.2473 | 1379.3 | 7.2499 | – | – | |
| 1385.6 | 7.2171 | 1385.6 | 7.2171 | 15.6 | 0.0817 | ||
| CH3CH2OH:CO | 1372.1 | 7.2881 | – | – | 5.7 | 0.0304 | |
| 1396.2 | 7.1622 | – | – | 3.4 | 0.0175 | ||
| CH3CH2OH:CH3OH | 1383.7 | 7.2271 | 1381.3 | 7.2397 | 14.9 | 0.0782** | |
| CH3CH2OH:CO:CH3OH | 1384.2 | 7.2246 | 1381.7 | 7.2372 | 15.0 | 0.0788** | |
| CH3CH2OH | 30 | 1381.3 | 7.2397 | – | – | 19.8 | 0.1042* |
| CH3CH2OH:H2O | 1379.8 | 7.2473 | 1379.3 | 7.2499 | – | – | |
| 1385.6 | 7.2171 | 1385.1 | 7.2196 | 16.3 | 0.0852* | ||
| CH3CH2OH:CO | 1372.6 | 7.2855 | – | – | 7.5 | 0.0397 | |
| 1383.7 | 7.2271 | – | – | – | – | ||
| 1396.2 | 7.1622 | – | – | 3.3 | 0.0171 | ||
| CH3CH2OH:CH3OH | 1384.2 | 7.2246 | 1381.3 | 7.2397 | 14.9 | 0.0784** | |
| CH3CH2OH:CO:CH3OH | 1383.7 | 7.2271 | 1381.7 | 7.2372 | 15.9 | 0.0838** | |
| CH3CH2OH | 70 | 1380.8 | 7.2423 | – | – | 19.1 | 0.1005* |
| CH3CH2OH:H2O | 1379.3 | 7.2499 | 1379.3 | 7.2499 | – | – | |
| 1385.1 | 7.2196 | 1385.1 | 7.2196 | 16.7 | 0.0878 | ||
| CH3CH2OH:CO | – | – | – | – | – | – | |
| CH3CH2OH:CH3OH | 1383.2 | 7.2297 | 1380.8 | 7.2423 | – | – | |
| CH3CH2OH:CO:CH3OH | 1381.7 | 7.2372 | 1381.7 | 7.2372 | 16.2 | 0.0853** | |
| CH3CH2OH | 100 | 1380.3 | 7.2448 | – | – | 15.8 | 0.0833* |
| CH3CH2OH:H2O | 1379.3 | 7.2499 | 1378.9 | 7.2524 | – | – | |
| 1385.1 | 7.2196 | 1384.6 | 7.2221 | 17.5 | 0.0919* | ||
| CH3CH2OH:CO | – | – | – | – | – | – | |
| CH3CH2OH:CH3OH | 1382.2 | 7.2347 | 1380.8 | 7.2423 | 15.0 | 0.0790** | |
| CH3CH2OH:CO:CH3OH | 1381.7 | 7.2372 | 1381.3 | 7.2397 | 12.1 | 0.0635** | |
| CH3CH2OH | 120 | 1372.6 | 7.2855 | – | – | 15.8 | 0.0833 |
| 1382.7 | 7.2322 | – | – | – | – | ||
| CH3CH2OH:H2O | 1378.9 | 7.2524 | 1378.4 | 7.2549 | – | – | |
| 1384.6 | 7.2221 | 1384.6 | 7.2221 | 18.4 | 0.0967* | ||
| CH3CH2OH:CO | – | – | – | – | – | – | |
| CH3CH2OH:CH3OH | 1381.7 | 7.2372 | 1381.3 | 7.2397 | 14.1 | 0.0740** | |
| CH3CH2OH:CO:CH3OH | 1381.7 | 7.2372 | 1381.7 | 7.2372 | 12.6 | 0.0664** | |
| CH3 CH2OH | 130 | 1373.1 | 7.2830 | – | – | 4.4 | 0.0235 |
| 1385.1 | 7.2196 | – | – | – | – | ||
| CH3 CH2OH:H2O | 1378.4 | 7.2549 | 1378.4 | 7.2549 | – | – | |
| 1384.6 | 7.2221 | 1384.2 | 7.2246 | 18.6 | 0.0977* | ||
| CH3 CH2OH:CO | – | – | – | – | – | – | |
| CH3 CH2OH:CH3OH | 1381.3 | 7.2397 | 1381.3 | 7.2397 | 14.6 | 0.0767** | |
| CH3 CH2OH:CO:CH3OH | 1381.7 | 7.2372 | 1381.7 | 7.2372 | 13.7 | 0.0721** | |
| CH3 CH2OH | 140 | 1373.1 | 7.2830 | – | – | 4.5 | 0.0239 |
| 1385.1 | 7.2196 | – | – | – | – | ||
| CH3 CH2OH:H2O | 1380.3 | 7.2448 | 1378.4 | 7.2549 | 19.0 | 0.1000* | |
| 1384.2 | 7.2246 | 1383.7 | 7.2271 | – | – | ||
| CH3 CH2OH:CO | – | – | – | – | – | – | |
| CH3 CH2OH:CH3OH | 1381.3 | 7.2397 | 1381.3 | 7.2397 | 14.6 | 0.0769** | |
| CH3 CH2OH:CO:CH3OH | 1381.3 | 7.2397 | 1381.7 | 7.2372 | 13.9 | 0.0733** | |
| CH3 CH2OH | 150 | 1373.1 | 7.2830 | – | – | 5.2 | 0.0277 |
| 1384.6 | 7.2221 | – | – | – | – | ||
| CH3 CH2OH:H2O | 1380.3 | 7.2448 | 1378.4 | 7.2549 | 18.6 | 0.0975* | |
| 1383.7 | 7.2271 | 1383.7 | 7.2271 | – | – | ||
| CH3 CH2OH:CO | – | – | – | – | – | – | |
| CH3 CH2OH:CH3OH | 1381.7 | 7.2372 | 1381.3 | 7.2397 | 14.3 | 0.0752** | |
| CH3 CH2OH:CO:CH3OH | 1381.7 | 7.2372 | 1381.7 | 7.2372 | 14.0 | 0.0734** | |
| CH3 CH2OH | 160 | – | – | – | – | – | – |
| CH3 CH2OH:H2O | 1380.3 | 7.2448 | 1380.3 | 7.2448 | 18.9 | 0.0994 | |
| CH3 CH2OH:CO | – | – | – | – | – | – | |
| CH3 CH2OH:CH3OH | – | – | – | – | – | – | |
| CH3 CH2OH:CO:CH3OH | – | – | – | – | – | – | |
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