Fig. 2

H2Cl+ OPR as a function of the gas temperature: (i) at thermal equilibirum (solid pink line); (ii) obtained with a full model considering a hydrogen abstraction and a proton hop mechanism for respectively the H2 + HCl+ and formation reactions (dashed red curve); (iii) obtained with a model considering full scrambling for all the reactions involving nuclear-spin forms (dashed blue curves); (iv) taken from a simple analytical formula and designated OPR0, this model represents scrambling via reaction (4) at steady state with the OPR for H2 treated as thermal (Neufeld et al. 2015) (solid cyan). The time evolution of the complete scrambling model is depicted on the second panel where the H2Cl+ OPR is represented in green for a time of 1.5 × 103 yr as an indicative reference.
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