Table 1
MnH(j7Σ+) molecular states, the corresponding asymptotic atomic states (scattering channels), the manganese terms, the asymptotic energies (
-average experimental values taken from NIST; Kramida et al. 2012) with respect to the ground-state level, the electronic bound energies Ej, and the statistical probabilities for population of the molecular states.
| j | Asymptotic atomic states | Mn terms | Asymptotic energies (eV) | Bound energies Ej (eV) |
|
|
|
|||||
| 1 | Mn(3d54s2) + H(1s 2S) | a 6S | 0.0 | –7.43404 | 0.5833 |
| 2 | Mn(3d6(5D)4s) + H(1s 2S) | a 6D | 2.14508 | –5.28896 | 0.1167 |
| 3 | Mn(3d5(6S)4s4p 3P°) + H(1s 2S) | z 8P° | 2.30260 | –5.13144 | 0.1458 |
| 4 | Mn(3d5(6S)4s4p 3P°) + H(1s 2S) | z 6P° | 3.07387 | –4.36017 | 0.1944 |
| 5 | Mn(3d5(6S)4s4p 1P°) + H(1s 2S) | y 6P° | 4.43088 | –3.00315 | 0.1944 |
| 6 | Mn(3d54s(7S)5s) + H(1s 2S) | e 8S | 4.88886 | –2.54518 | 0.4375 |
| 7 | Mn(3d54s(7S)5s) + H(1s 2S) | e 6S | 5.13343 | –2.30061 | 0.5833 |
| 8 | Mn(3d6(5D)4p) + H(1s 2S) | z 6D° | 5.20176 | –2.23228 | 0.1167 |
| 9 | Mn(3d6(5D)4p) + H(1s 2S) | z 6F° | 5.38961 | –2.04443 | 0.0833 |
| 10 | Mn(3d6(5D)4p) + H(1s 2S) | x 6P° | 5.59255 | –1.84149 | 0.1944 |
| 11 | Mn(3d54s(7S)5p) + H(1s 2S) | y 8P° | 5.70411 | –1.72993 | 0.1458 |
| 12 | Mn(3d54s(7S)4d) + H(1s 2S) | e 8D | 5.79126 | –1.64278 | 0.0875 |
| 13 | Mn(3d54s(7S)4d) + H(1s 2S) | e 6D | 5.85360 | –1.58043 | 0.1167 |
| 14 | Mn(3d54s(7S)5p) + H(1s 2S) | w 6P° | 5.89743 | –1.53661 | 0.1944 |
| 15 | Mn(3d5(4P)4s4p 3P°) + H(1s 2S) | y 6D° | 5.92037 | –1.51367 | 0.1167 |
| 16 | Mn(3d5(4G)4s4p 3P°) + H(1s 2S) | y 6F° | 5.97253 | –1.46151 | 0.0833 |
| 17 | Mn(3d54s(5S)5s) + H(1s 2S) | f 6S | 6.12672 | –1.30732 | 0.5833 |
| 18 | Mn(3d5(4P)4s4p 3P°) + H(1s 2S) | v 6P° | 6.19628 | –1.23775 | 0.1944 |
| 19 | Mn(3d54s(7S)6s) + H(1s 2S) | f 8S | 6.21875 | –1.21529 | 0.4375 |
| 20 | Mn(3d54s(7S)6s) + H(1s 2S) | g 6S | 6.31138 | –1.12266 | 0.0833 |
| 21 | Mn(3d5(4D)4s4p 3P°) + H(1s 2S) | x 6F° | 6.32861 | –1.10543 | 0.5833 |
| 22 | Mn+(3d54s 7S) + H−(1s S) |
– | 6.68004 | –0.754 | 1.0 |
Notes. The electronic bound energies are the same as the asymptotic energies, but measured from the ionization limit Mn+(3d5 4s 7S) + H(1s 2S); the differences between the asymptotic energy values and the bound energy values are equal to the ionization potential IMn = 7.43404 eV.
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