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Table B.4
Line parameters of H2CS.
| Transition | Sym.∗ | Frequency | E u / k | A ul | S ul | g u |  dv |
|
Δv |
|
S / N |
|
|
|||||||||||
| (JKa,Kc)u → (JKa,Kc)l | [MHz] | [K] | [s-1] | [mK km s-1] | [km s-1] | [km s-1] | [mK] | ||||
|
|
|||||||||||
| 31,3 → 21,2 | ortho | 101 477.810F | 8.1 | 1.26 × 10-5 | 2.67 | 7 | 79(8) | 10.8(0.1) | 1.1(0.1) | 68 | 10 |
| 32,2 → 22,1 | para | 103 039.907F | 62.6 | 8.25 × 10-6 | 1.67 | 7 | ⟩ 53(5) | 10.9(0.1) | 1.8(0.2) | 28 | 9 |
| 30,3 → 20,2 | para | 103 040.452F | 9.9 | 1.48 × 10-5 | 3.00 | 7 | |||||
| 32,1 → 22,0 | para | 103 051.847F | 62.6 | 8.25 × 10-6 | 1.67 | 7 | 19(7) | 10.5(0.3) | 1.5(1.3) | 10 | 3 |
| 31,2 → 21,1 | ortho | 104 617.040F | 8.4 | 1.38 × 10-5 | 2.67 | 7 | 85(5) | 10.7(<0.1) | 1.3(0.1) | 59 | 14 |
| 40,4 → 30,3 | para | 137 371.210W | 16.5 | 3.65 × 10-5 | 4.00 | 9 | 182(18) | – | – | – | 2 |
| 41,3 → 31,2 | ortho | 139 483.682W | 15.1 | 3.58 × 10-5 | 3.75 | 9 | 149(22) | – | – | – | 4 |
| 51,5 → 41,4 | ortho | 169 114.079W | 22.7 | 6.68 × 10-5 | 4.80 | 11 | 229(35) | – | – | – | 10 |
| 50,5 → 40,4 | para | 171 688.117W | 24.7 | 7.28 × 10-5 | 5.00 | 11 | 1447(217) | – | – | – | 9 |
| 51,4 → 41,3 | ortho | 174 345.223W | 23.5 | 7.32 × 10-5 | 4.80 | 11 | 300(106) | – | – | – | 3 |
| 61,6 → 51,5 | ortho | 202 924.054F | 32.5 | 1.19 × 10-4 | 5.83 | 13 | 206(10) | 10.9(<0.1) | 0.8(0.1) | 245 | 18 |
| 60,6 → 50,5 | para | 205 987.858F | 34.6 | 1.28 × 10-4 | 6.00 | 13 | 75(7) | 10.9(<0.1) | 0.7(0.1) | 104 | 10 |
| 63,4 → 53,3 | ortho | 206 052.602F | 138.3 | 9.59 × 10-5 | 4.50 | 13 | ⟩ 76(14) | 10.9(0.1) | 1.3(0.4) | 55 | 5 |
| 63,3 → 53,2 | ortho | 206 052.602F | 138.3 | 9.59 × 10-5 | 4.50 | 13 | |||||
| 62,4 → 52,3 | para | 206 158.602F | 87.3 | 1.14 × 10-4 | 5.33 | 13 | 48(7) | 10.9(0.1) | 1.0(0.1) | 47 | 5 |
| 61,5 → 51,4 | ortho | 209 200.620F | 33.5 | 1.30 × 10-4 | 5.83 | 13 | 190(9) | 10.9(<0.1) | 0.8(0.1) | 231 | 17 |
| 71,7 → 61,6 | ortho | 236 727.020F | 43.8 | 1.92 × 10-4 | 6.86 | 15 | 105(14) | 10.9(<0.1) | 0.5(0.1) | 185 | 7 |
| 70,7 → 60,6 | para | 240 266.872F | 46.1 | 2.05 × 10-4 | 7.00 | 15 | 107(13) | 10.8(<0.1) | 0.9(0.1) | 116 | 8 |
| 72,6 → 62,5 | para | 240 382.051F | 98.8 | 1.88 × 10-4 | 6.43 | 15 | 24(6) | 10.8(0.1) | 0.3(0.2) | 76 | 3 |
| 73,5 → 63,4 | ortho | 240 393.037F | 149.8 | 1.68 × 10-4 | 5.71 | 15 | ⟩ 122(14) | 10.5(0.1) | 1.6(0.2) | 72 | 6 |
| 73,4 → 63,3 | ortho | 240 393.762F | 149.8 | 1.68 × 10-4 | 5.71 | 15 | |||||
| 72,5 → 62,4 | para | 240 549.066F | 98.8 | 1.89 × 10-4 | 6.43 | 15 | 62(11) | 10.7(0.1) | 1.5(0.2) | 54 | 5 |
| 71,6 → 61,5 | ortho | 244 048.504F | 45.2 | 2.10 × 10-4 | 6.86 | 15 | 185(11) | 10.9(<0.1) | 0.8(0.1) | 260 | 14 |
| 81,8 → 71,7 | ortho | 270 521.931F | 56.8 | 2.90 × 10-4 | 7.88 | 17 | 128(16) | 10.8(0.1) | 0.9(0.2) | 139 | 6 |
| 80,8 → 70,7 | para | 274 521.931F | 59.3 | 3.08 × 10-4 | 8.00 | 17 | 60(9) | 11.1(0.1) | 0.7(0.1) | 77 | 5 |
| 82,6 → 72,5 | para | 274 953.744F | 112.0 | 2.90 × 10-4 | 7.50 | 17 | 36(9) | 11.0(0.1) | 0.9(0.2) | 39 | 3 |
| 81,7 → 71,6 | ortho | 278 887.661F | 58.6 | 3.18 × 10-4 | 7.87 | 17 | 195(13) | 10.9(<0.1) | 0.7(0.1) | 245 | 14 |
| 91,9 → 81,8 | ortho | 304 307.709F | 71.4 | 4.17 × 10-4 | 8.89 | 19 | 75(8) | 10.7(0.1) | 0.7(0.1) | 101 | 5 |
| 101,10 → 91,9 | ortho | 338 083.195F | 87.6 | 5.77 × 10-4 | 9.90 | 21 | 108(30) | 10.6(0.1) | 0.9(0.3) | 113 | 3 |
Notes. Frequencies, Eu/k, Aul, Sul, and gu from CDMS catalogue.
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