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Table A.3

Laboratory parameters of CH3CN and HNCO and the intensity integrated over the width of each line , which is used for rotation diagrams in Fig. 4.

Mol. Freq. K I(300 K) E L S ul μ 2 o-/p- MM1 MM2 IRS1−mmS Note
(GHz) Log10 (cm-1) (D2) (K km s-1) (K km s-1) (K km s-1)

CH3CN (J = 12 → 11) 220.476 8 3.098 357.938 205.033 p- 24.76 ± 2.50 5.53 ± 0.09 38.15 ± 0.92 1, 2, 3
220.539 7 2.868 283.608 243.499 p- 32.99 ± 2.60 13.07 ± 0.16 46.61 ± 4.02
220.594 6 2.377 219.154 553.690 o- 129.85 ± 10.78 60.20 ± 0.08 166.07 ± 2.04
220.641 5 2.522 164.592 305.047 p- 109.82 ± 4.97 36.07 ± 0.18 165.53 ± 11.26
220.679 4 2.397 119.933 328.188 p- 105.81 ± 3.19 39.42 ± 0.22 225.55 ± 3.57
220.709 3 2.001 85.187 692.234 o- 173.43 ± 7.99 66.98 ± 0.72 287.13 ± 2.31
220.730 2 2.234 60.363 358.988 p- 136.57 ± 1.93 46.87 ± 1.40 280.88 ± 3.92
220.743 1 2.194 45.467 366.614 p- 143.27 ± 31.70 54.19 ± 0.70 301.46 ± 4.56
220.747 0 2.180 40.501 369.277 p- 155.20 ± 31.70 58.70 ± 0.70 326.57 ± 4.56

HNCO 218.981 2.677 62.949 70.596 35.32 ± 1.11 17.38 ± 0.19 88.86 ± 3.25 1, 2, 4, 5
219.656 3.232 293.596 59.063 3.41 ± 0.04 3.86 ± 0.03 8.49 ± 0.49
219.737 2.887 151.337 66.110 25.47 ± 0.12 14.07 ± 0.09 46.96 ± 0.24
219.798 2.602 32.994 72.127 65.23 ± 0.60 36.89 ± 0.18 121.44 ± 6.06

Notes. Uncertainties on the measured intensities are typically 10% as determined from Gaussian fit. 1. Integrated intensities are obtained by Gildas “Gaussian” fits. 2. Laboratory parameters are from CDMS. 3. Q(300 K, CH3CN) = 14683.6324. 4. Q(300 K, HNCO) = 7785.741. 5. “*” denotes the line with blending multiplets due to ourspectral resolution, and the values are giving by simply taking into account their relative weights.

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