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Table A.1

Identified lines from PdBI dataset.

Freq.a Molb Trans.c E u / k Cmt.d Freq.a Mol.d (candidates) Trans.c E u / k Cmt.d
(GHz) (K) (GHz) (K)

217.19 ± 0.01 UL 2.2 217.191 CH3OCH3 (224,19−223,20)A(E)A(E) 253
217.194 g−(CH2OH)2(ν = 1) (174,14 → 163,13) 83
217.194 HCOOCH3(ν = 0) (304,26 → 303,27)E 291
217.216 HCOOCH3(ν = 0) (329,24 → 328,25)A 368 1.3
217.236 HCOOCH3(ν = 0) (329,24 → 328,25)E 368 1.3
217.239 DCN (3 → 2) 21
217.3 ± 0.01 UL 2.2 217.300 (235,19 → 225,18) 178
217.301 (235,18 → 225,17) 178
217.290-217.307 13CN (N = 2−1) 16
217.299 CH3OH(vt = 1) (61,5 → 72,6−−) 374
217.313 HCOOCH3(ν = 1) (174,13 → 164,12)A 290 1.2
217.64 ± 0.01 UL 2.2 217.639 13CH3CH2CN (251,24 → 241,23) 139
217.642 CH2CH13CN (234,19 → 224,18) 160
217.646 (2314,9 → 2214,8) 533
217.646 (2314,10 → 2214,9) 533
217.633-217.640 13CN (N = 2−1) 15
217.643 CH3OH(vt = 1) (156,10 → 165,11−−) 746
217.643 CH3OH(vt = 1) (156,9 → 165,12 + +) 746
217.833 33SO (65 → 54) 35
217.89 ± 0.005 UL 2.2 217.886 CH3OH(vt = 0) (201,19 → 200,20) 508
217.889 CH2CH13CN (2314,9 → 2214,8) 544
217.889 CH2CH13CN (2314,10 → 2214,9) 544
217.895 13CH2CHCN (231,23 → 220,22) 121
218.108 HCOOCH3(ν = 1) (174,13 → 164,12)E 290 1.2
218.198 O13CS (18 → 17) 99 3
218.222 H2CO (30,3 → 20,2) 21
218.260 HCOOCH3(ν = 0) (319,23 → 318,24)A 349 1.3
218.281 HCOOCH3(ν = 0) (173,14 → 163,13)E 100 2.2
218.298 HCOOCH3(ν = 0) (173,14 → 163,13)A 100 2.2
218.325 HC3N(ν = 0) (24 → 23) 131
218.390 CH3CH2CN(ν = 0) (243,21 → 233,20) 140 3
218.440 CH3OH(ν = 0) (42,2 → 31,2) 46
218.460 NH2CHO (101,9 → 91,8) 61
218.476 H2CO (32,2 → 22,1) 68
218.585 HCOOCH3(ν = 0) (369,28 → 368,29)A 450 2.2
218.593 HCOOCH3(ν = 0) (277,21 → 275,22)A 258 2.2
218.607 HCOOCH3(ν = 0) (369,28 → 368,29)E 450 2.2
218.633 HCOOCH3(ν = 0) (277,21 → 275,22)E 258 2.2
218.655 HCOOCH3(ν = 1) (1816,2 → 1716,1)E 460 1.3
218.738 HCOOCH3(ν = 1) (1814,4 → 1714,3)E 419 2.3
218.760 H2CO (32,1 → 22,0) 68
218.831 HCOOCH3(ν = 1) (1813,5 → 1713,4)E 401 1.3
218.861 HC3N(v7 = 1) (24 → 23,l = 1e) 452
218.903 OCS(ν = 0) (18 → 17) 100
218.966 HCOOCH3(ν = 1) (1812,6 → 1712,5)E 384 1.3
218.981 HNCO(ν = 0) (101,10 → 91,9) 101
219.068 HCOOCH3(ν = 1) (1817,2 → 1717,1)E 481 2.2
219.079 HCOOCH3(ν = 1) (283,25 → 282,26)E 434 2.2
219.090 HCOOCH3(ν = 0) (347,28 → 345,29)E 388 2.2
219.109 HCOOCH3(ν = 0) (347,28 → 345,29)A 388 2.3
219.153 HCOOCH3(ν = 1) (104,6 → 93,6)E 230 2.3 219.155 HCOOCH3(ν = 1) (1811,7 → 1711,6)E 369 2.3
219.174 HC3N(ν7 = 1) (24 → 23) 452
219.195 HCOOCH3(ν = 1) (1816,3 → 1716,2)E 459 2.3
219.264 HCOOCH3(ν = 0) (366,30 → 366,31)A 429 2.2
219.276 SO2(ν = 0) (227,15 → 236,18) 352
219.331 HCOOCH3(ν = 1) (1815,4 → 1715,3)E 438 2.3
219.355 34SO2(ν = 0) (111,11 → 100,10) 60 3
219.412 HCOOCH3(ν = 1) (1810,8 → 1710,7)E 355
219.417 HCOOCH3(ν = 0) (305,26 → 304,27)E 292 2.3
219.479 HCOOCH3(ν = 1) (1814,5 → 1714,4)E 419 2.3
219.484 HCOOCH3(ν = 0) (305,26 → 304,27)A 292 2.3
219.506 CH3CH2CN(ν = 0) (242,22 → 232,21) 136 2.3
219.560 C18O (2 → 1) 16
219.566 HCOOCH3(ν = 1) (1814,4 → 1714,3)A 419 219.566 HCOOCH3(ν = 1) (1814,5 → 1714,5)A 419
219.566 HCOOCH3(ν = 1) (1815,4 → 1715,3)A 438
219.566 HCOOCH3(ν = 1) (1815,3 → 1715,3)A 438
219.571 HCOOCH3(ν = 1) (1816,2 → 1716,1)A 459
219.571 HCOOCH3(ν = 1) (1816,3 → 1716,2)A 459
219.579 HCOOCH3(ν = 0) (289,19 → 288,20)A 295 2.3
219.584 HCOOCH3(ν = 1) (1813,5 → 1713,4)A 401 2.3 219.584 HCOOCH3(ν = 1) (1813,6 → 1713,5)A 401 2.3
219.592 HCOOCH3(ν = 0) (289,19 → 288,20)E 295 1.3
219.600 HCOOCH3(ν = 0) (309,22 → 308,23)E 330 1.1
219.607 HCOOCH3(ν = 0) (305,26 → 303,27)E 292
219.623 HCOOCH3(ν = 1) (1812,6 → 1712,5)A 384 1.1 219.623 HCOOCH3(ν = 1) (1812,7 → 1712,6)A 384 1.1
219.642 HCOOCH3(ν = 1) (1813,6 → 1713,5)E 400 1.1
219.657 HNCO (103,8 → 93,7) 447 219.657 HNCO (103,7 → 93,6) 447
219.696 HCOOCH3(ν = 1) (1811,8 → 1711,7)A 369 1.3 219.696 HCOOCH3(ν = 1) (1811,7 → 1711,6)A 369 1.3
219.705 HCOOCH3(ν = 1) (184,15 → 174,14)A 299 2.2
219.734 HNCO(ν = 0) (102,9 → 92,8) 231 219.737 HNCO(ν = 0) (102,8 → 92,7) 231
219.764 HCOOCH3(ν = 1) (189,9 → 179,8)E 342 1.2
219.798 HNCO(ν = 0) (100,10 → 90,9) 58
219.822 HCOOCH3(ν = 1) (1810,9 → 1710,8)A 355 1.2 219.822 HCOOCH3(ν = 1) (1810,8 → 1710,7)A 355 1.2
219.827 HCOOCH3(ν = 1) (1812,7 → 1712,6)E 384 2.3
219.908 (31,2 → 21,1) 33
219.949 SO(ν = 0) (65 → 54) 35
220.030 HCOOCH3(ν = 1) (189,10 → 179,9)A 342 220.030 HCOOCH3(ν = 1) (189,9 → 179,8)A 342
220.043 HCOOCH3(ν = 1) (1811,8 → 1711,7)E 368 2.3
220.078 CH3OH(νt = 0) (80,8 → 71,6) 97
220.167 HCOOCH3(ν = 0) (174,13 → 164,12)E 103
220.178 CH2CO (111,11 → 101,10) 76
220.190 HCOOCH3(ν = 0) (174,13 → 164,12)A 103
220.258 HCOOCH3(ν = 1) (242,23 → 241,24)E 355 1.3
220.296 (129 → 119) 646 1.3
220.307 HCOOCH3(ν = 1) (1810,9 → 1710,8)E 354 1.2
220.368 HCOOCH3(ν = 1) (188,11 → 178,10)A 331 2.2 220.370 HCOOCH3(ν = 1) (188,10 → 178,9)A 331 2.2
220.366 HCOOCH3(ν = 0) (335,28 → 335,29)E 357 2.2
220.399 13CO (2 → 1) 16
220.409 HCOOCH3(ν = 1) (184,15 → 174,14)E 299 1.3
220.476 CH3CN(ν = 0) (128 → 118) 526
220.539 CH3CN(ν = 0) (127 → 117) 419
220.570 (124 → 114) 183
220.594 CH3CN(ν = 0) (126 → 116) 326
220.621 (122 → 112) 97
220.641 CH3CN(ν = 0) (125 → 115) 248
220.647 HCOOCH3(ν = 1) (189,10 → 179,9)E 342 2.2
220.661 CH3CH2CN(ν = 0) (252,24 → 242,23) 143 2.3
220.679 CH3CN(ν = 0) (124 → 114) 183
220.709 CH3CN(ν = 0) (123 → 113) 133
220.730 CH3CN(ν = 0) (122 → 112) 98
220.743 CH3CN(ν = 0) (121 → 111) 76
220.747 CH3CN(ν = 0) (120 → 110) 69

Notes. In case of blending, lines with stronger CDMS/JPL intensity are listed in the left column, and the possible weaker blended transitions in the right column. Without any digital annotation indicates that the lines are detected in both IRS1 and MM1, especially showing absorption or an (inverse) P-Cygni profile towards IRS1-peak. “1.1” denote the lines being detected in IRS1 only, especially showing absorption or an (inverse) P-cygni profile towards IRS1-peak. “1.2” denote the lines being detected in IRS1 only, especially showing pure emission towards IRS1-peak. “1.3” denote the lines being detected in IRS1-mmS only, but without clear detection in IRS1-peak. “2.2” denote the lines being detected in both IRS1 and MM1, especially showing pure emission towards IRS1-peak. “2.3” denote the lines being detected in both IRS1 and MM1, but without clear detection in IRS1-peak. “3” denote the lines being detected only in MM1.

(a)

Tentative detections (intensity ~3σ rms) are marked with “*”.

(b)

Unidentified lines are denoted as “UL”, and possible transitions are given.

(c)

“A(E)A(E)” indicates 4 types of transitions are possible for a certain line: AA, EE, AE, EA.

(d)

Lines with are imaged in Fig. 3.

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