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Fig. 3

image

Evolution of the IR spectrum of the ice sample during UV photoprocessing in experiment 2 (see Table 3) conveniently split in four regions. Results were similar in experiment 1. a) A new feature appears at 3005 cm-1 (dashed line) between the O-H and C-H stretching bands of C2H5OH, which is attributed to the formation of CH4. This species also displays a more intense band near 1302 cm-1, shown in panel c). b) Formation of CO2 and CO leads to the appearance of two C-O stretching bands at 2340 cm-1 and 2136 cm-1 (dashed lines), respectively. c) Dashed lines at 1715 cm-1, 1349 cm-1, and 1302 cm-1 indicate new features due to the formation of photoproducts (probably H2CO, CH3CHO, C2H6, and CH4; see text). A broad band on the red side of the 1715 cm-1 peak may indicate the presence of H2O. d) Intensity of the C-O stretching band of C2H5OH at 1048 cm-1 (dashed line) decreases as the ice is processed.

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