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Table 1

CaH(2Σ+) molecular channels and asymptotic energies (J-average experimental values taken from NIST Kramida et al. 2012) with respect to the ground state.

Asymptotic Asymptotic
j atomic states energies (eV)

1 Ca(4s21S) + H(1s 2S) 0.0
2 Ca(4s4p 3P) + H(1s 2S) 1.892
3 Ca(3d4s 3D) + H(1s 2S) 2.524
4 Ca(3d4s 1D) + H(1s 2S) 2.709
5 Ca(4s4p 1P) + H(1s 2S) 2.933
6 Ca(4s5s 3S) + H(1s 2S) 3.910
7 Ca(4s5s 1S) + H(1s 2S) 4.131
8 Ca(3d4p 3F) + H(1s 2S) 4.442
9 Ca(4s5p 3P) + H(1s 2S) 4.534
10 Ca(4s5p 1P) + H(1s 2S) 4.554
11 Ca(4s4d 1D) + H(1s 2S) 4.624
12 Ca(4s4d 3D) + H(1s 2S) 4.681
13 Ca(3d4p 3P) + H(1s 2S) 4.877
14 Ca(4s6s 3S) + H(1s 2S) 5.018
15 Ca(3d4p 1F) + H(1s 2S) 5.026
16 Ca(4s6s 1S) + H(1s 2S) 5.045
17 Ca(4p21D) + H(1s 2S) 5.049
i Ca+(4s 2S) + H(1s21S) 5.363

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