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Table A.8

Calculated frequencies and relative intensities of nuclear quadrupole splitting components for the Ka = 0,1,2 ground state (νb = 0, m = 0) rotational transitions of CH3NCO.

K = 0 K = 1L K = 1U K = 2L K = 2U
F′–F′′ νa/MHz Irelb F′–F′′ ν/MHz Irel F′–F′′ ν/MHz Irel F′–F′′ ν/MHz Irel F′–F′′ ν/MHz Irel
J = 1−0
0−1 8669.943 0.1111
2−1 8671.222 0.5555
1−1 8672.076 0.3334
J = 2 − 1
1−1 17 341.104 0.0833 1−0 17 189.333 0.1111 1−0 17 503.509 0.1111
1−2 17 341.957 0.0056 1−2 17 189.916 0.0056 1−2 17 504.205 0.0056
3−2 17 342.465 0.4667 3−2 17 190.192 0.4667 3−2 17 504.436 0.4667
2−1 17 342.526 0.2500 1−1 17 190.305 0.0833 1−1 17 504.669 0.0833
1−0 17 343.237 0.1111 2−2 17 190.690 0.0833 2−2 17 504.853 0.0833
2−2 17 343.379 0.0833 2−1 17 191.079 0.2500 2−1 17 505.317 0.2500
J = 3 − 2
2−2 26 012.000 0.0370 2−2 25 784.511 0.0370 2−2 26 255.928 0.0370 2−1 26 037.145 0.2000 2−1 26 037.736 0.2000
2−3 26 012.914 0.0011 2−3 25 785.008 0.0011 2−3 26 256.344 0.0011 3−3 26 037.653 0.0370 3−3 26 038.244 0.0370
4−3 26 013.246 0.4286 4−3 25 785.272 0.4286 2−1 26 256.576 0.2000 4−3 26 037.653 0.4286 4−3 26 038.244 0.4286
3−2 26 013.280 0.2963 2−1 25 785.285 0.2000 4−3 26 256.578 0.4286 2−3 26 037.653 0.0011 2−3 26 038.244 0.0011
2−1 26 013.422 0.2000 3−2 25 785.527 0.2963 3−2 26 256.831 0.2963 2−2 26 038.567 0.0370 3−2 26 039.158 0.2963
3−3 26 014.194 0.0370 3−3 25 786.025 0.0370 3−3 26 257.247 0.0370 3−2 26 038.567 0.2963 2−2 26 039.158 0.0370
J = 4 − 3
3−3 34 682.204 0.0208 3−3
3−4 34 683.153 0.0003 3−4 34 379.823 0.0003 3−4 35 008.150 0.0003 3−3 34 716.569 0.0208 3−3 34 718.047 0.0003
5−4 34 683.402 0.4074 5−4 34 380.045 0.4074 5−4 35 008.351 0.4074 3−4 34 716.569 0.0003 3−4 34 718.047 0.0208
4−3 34 683.424 0.3125 3−2 34 380.086 0.2381 3−2 35 008.384 0.2381 5−4 34 716.669 0.4074 5−4 34 718.146 0.4074
3−2 34 683.484 0.2381 4−3 34 380.160 0.3125 4−3 35 008.463 0.3125 4−3 34 717.057 0.3125 4−3 34 718.534 0.0208
4−4 34 684.372 0.0208 4−4 34 380.912 0.0208 4−4 35 009.132 0.0208 4−4 34 717.057 0.0208 4−4 34 718.534 0.3125
J = 5 − 4
4−4 43 351.569 0.0133 4−4 42 973.421 0.0133 4−4 43 758.741 0.0133 4−4 43 394.804 0.0133 4−4 43 397.758 0.0133
4−5 43 352.539 0.0001 4−5 42 974.288 0.0001 4−5 43 759.523 0.0001 4−5 43 395.192 0.0001 4−5 43 398.145 0.0001
6−5 43 352.740 0.3939 6−5 42 974.477 0.3939 6−5 43 759.694 0.3939 4−3 43 395.292 0.2593 4−3 43 398.245 0.2593
5−4 43 352.755 0.3200 4−3 42 974.511 0.2593 4−3 43 759.723 0.2593 6−5 43 395.312 0.3939 6−5 43 398.265 0.3939
4−3 43 352.788 0.2593 5−4 42 974.540 0.3200 5−4 43 759.755 0.3200 5−4 43 395.515 0.3200 5−4 43 398.468 0.3200
5−5 43 353.725 0.0133 5−5 42 975.407 0.0133 5−5 43 760.537 0.0133 5−5 43 395.903 0.0133 5−5 43 398.856 0.0133
J = 6 − 5
5−5 52 019.907 0.0093 5−5 51 567.406 0.0093 5−5 52 509.526 0.0093 5−5 52 072.829 0.0093 5−5 52 077.994 0.0093
5−6 52 020.892 0.0001 5−6 51 568.335 0.0001 5−6 52 510.369 0.0001 5−6 52 073.419 0.0001 5−6 52 078.584 0.0001
7−6 52 021.060 0.3846 7−6 51 568.499 0.3846 7−6 52 510.517 0.3846 7−6 52 073.539 0.3846 7−6 52 078.704 0.3846
6−5 52 021.071 0.3241 5−4 51 568.525 0.2727 5−4 52 510.540 0.2727 5−4 52 073.540 0.2727 5−4 52 078.705 0.2727
5−4 52 021.092 0.2727 6−5 51 568.538 0.3241 6−5 52 510.555 0.3241 6−5 52 073.660 0.3241 6−5 52 078.824 0.3241
6−6 52 022.056 0.0093 6−6 51 569.467 0.0093 6−6 52 511.398 0.0093 6−6 52 074.250 0.0093 6−6 52 079.415 0.0093
J = 7 − 6
6−6 60 687.022 0.0068 6−6 60 160.922 0.0068 6−6 61 259.710 0.0068 6−6 60 750.459 0.0068 6−6 60 758.718 0.0068
6−7 60 688.018 0.0000 6−7 60 161.890 0.0000 6−7 61 260.590 0.0000 6−7 60 751.170 0.0000 6−7 60 759.428 0.0000
8−7 60 688.163 0.3778 8−7 60 162.034 0.3778 8−7 61 260.721 0.3778 8−7 60 751.284 0.3778 8−7 60 759.542 0.3778
7−6 60 688.171 0.3265 6−5 60 162.054 0.2820 6−5 61 260.739 0.2821 6−5 60 751.290 0.2821 6−5 60 759.548 0.2821
6−5 60 688.186 0.2821 7−6 60 162.060 0.3265 7−6 61 260.746 0.3265 7−6 60 751.361 0.3265 7−6 60 759.619 0.3265
7−7 60 689.167 0.0068 7−7 60 163.028 0.0068 7−7 61 261.627 0.0068 7−7 60 752.072 0.0068 7−7 60 760.330 0.0068
J = 8 − 7
7−7 69 352.717 0.0052 7−7 68 753.883 0.0052 7−7 70 009.183 0.0052 7−7 69 427.576 0.0052 7−7 69 439.955 0.0052
7−8 69 353.721 0.0000 7−8 68 754.877 0.0000 7−8 70 010.088 0.0000 7−8 69 428.365 0.0000 7−8 69 440.743 0.0000
9−8 69 353.849 0.3725 9−8 68 755.005 0.3725 9−8 70 010.205 0.3726 9−8 69 428.471 0.3726 9−8 69 440.848 0.3725
8−7 69 353.855 0.3281 7−6 68 755.021 0.2889 7−6 70 010.219 0.2889 7−6 69 428.479 0.2889 7−6 69 440.856 0.2889
7−6 69 353.866 0.2889 8−7 68 755.024 0.3281 8−7 70 010.223 0.3281 8−7 69 428.524 0.3281 8−7 69 440.902 0.3281
8−8 69 354.860 0.0052 8−8 68 756.018 0.0052 8−8 70 011.128 0.0052 8−8 69 429.313 0.0052 8−8 69 441.690 0.0052
J = 9 − 8
8−8 78 016.793 0.0041 8−8 77 346.206 0.0041 8−8 78 757.837 0.0041 8−8 78 104.085 0.0041 8−8 78 121.752 0.0041
8−9 78 017.805 0.0000 8−9 77 347.220 0.0000 8−9 78 758.761 0.0000 8−9 78 104.927 0.0000 8−9 78 122.593 0.0000
10−9 78 017.918 0.3684 10−9 77 347.334 0.3684 10−9 78 758.866 0.3684 10−9 78 105.026 0.3684 10−9 78 122.692 0.3685
8−7 78 017.924 0.3292 8−7 77 347.347 0.2941 8−7 78 758.877 0.2941 8−7 78 105.033 0.2941 8−7 78 122.699 0.2941
9−8 78 017.932 0.2941 9−8 77 347.348 0.3292 9−8 78 758.879 0.3292 9−8 78 105.064 0.3292 9−8 78 122.730 0.3292
9−9 78 018.935 0.0041 9−9 77 348.361 0.0041 9−9 78 759.803 0.0041 9−9 78 105.906 0.0041 9−9 78 123.571 0.0041

Notes.

(a)

Calculated frequency with uncertainty estimated at 5 kHz.

(b)

Relative intensity of a given hyperfine component such that the sum over all components for this rotational transition is unity.

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