Characterisation of the HNCO monolayer deposition. The TPD spectra (m/z 43) for HNCO depositions of a) 1.5 ML; b) 1 ML; c) 0.75 ML; and d) 0.5 ML. The original data are plotted in grey, with a smoothed version overplotted in black. The Polanyi-Wigner fit to the leading edge of the 1.5 ML deposition (see Sect. 3.2.1) is plotted as a dotted line.
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