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Table 2

HFS and isotopic splitting data for the lines retained in this analysis.

Lower level Upper level
λ Iso. J A B HFS J A B HFS
(nm) (MHz) (MHz) ref. (MHz) (MHz) ref.
Sc i : 100% 45Sc ()
474.3821 45Sc 9 / 2 285.967 −15.460 1 7 / 2
508.1561 45Sc 9 / 2 285.967 −15.460 1 9 / 2
535.6097 45Sc 7 / 2 −25.000 2 5 / 2
567.1828 45Sc 9 / 2 285.967 −15.460 1 11 / 2 55.000 25.000 3
623.9800 45Sc 3 / 2 269.556 −26.346 4 3 / 2 348.320 5
Sc ii
442.0661 45Sc 4 38.357 −16.456 6 3 205.400 −70.000 7
443.1362 45Sc 3 113.674 −12.615 6 2 366.800 −40.000 7
535.7202 45Sc 2 −27.732 22.127 8 1
564.1000 45Sc 1 −107.501 −12.300 8 2 106.117 −20.200 8
565.8362 45Sc 0 0.000 0.000 N 1 255.155 11.753 8
566.7164 45Sc 1 −107.501 −12.300 8 1 255.155 11.753 8
566.9055 45Sc 1 −107.501 −12.300 8 0 0.000 0.000 N
568.4214 45Sc 2 −27.732 22.127 8 1 255.155 11.753 8
624.5641 45Sc 2 −27.732 22.127 8 3 99.730 21.495 8
630.0746 45Sc 2 −27.732 22.127 8 2 125.423 8.769 8
632.0843 45Sc 1 −107.501 −12.300 8 1 304.788 3.824 8
660.4578 45Sc 2 149.361 7.818 6 2 215.700 18.000 9
Ti i : 8.25% 46Ti (I = 0), 7.44% 47Ti (), 73.72% 48Ti (I = 0), 5.41% 49Ti (), 5.18% 50Ti (I = 0)
Isotopic separations from Gangrsky et al. (1995)
586.6429 50Ti 2 0.000 0.000 N 3 0.000 0.000 N
586.6439 49Ti 2 −25.216 −39.202 10 3
586.6448 48Ti 2 0.000 0.000 N 3 0.000 0.000 N
586.6458 47Ti 2 −25.216 −47.826 10 3
586.6468 46Ti 2 0.000 0.000 N 3 0.000 0.000 N
592.2088 50Ti 0 0.000 0.000 N 1 0.000 0.000 N
592.2097 49Ti 0 0.000 0.000 N 1 −140.600 0.000 11
592.2107 48Ti 0 0.000 0.000 N 1 0.000 0.000 N
592.2117 47Ti 0 0.000 0.000 N 1 −140.700 0.000 11
592.2128 46Ti 0 0.000 0.000 N 1 0.000 0.000 N
Ti ii : Isotopic separations from Nouri et al. (2010)
4444.524 50Ti 7 / 2 0.000 0.000 N 7 / 2 0.000 0.000 N
4444.530 49Ti 7 / 2 −54.374 26.422 12 7 / 2 −31.500 −14.000 12
4444.536 48Ti 7 / 2 0.000 0.000 N 7 / 2 0.000 0.000 N
4444.542 47Ti 7 / 2 −54.374 32.235 12 7 / 2 −31.500 −17.080 12
4444.547 46Ti 7 / 2 0.000 0.000 N 7 / 2 0.000 0.000 N
4493.520 46Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N
4493.521 47Ti 3 / 2 97.013 −19.453 12 5 / 2
4493.523 48Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N
4493.524 49Ti 3 / 2 97.013 −23.733 12 5 / 2
4493.525 50Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N
4583.396 50Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N
4583.403 49Ti 3 / 2 −6.630 −24.100 13 5 / 2 −84.210 −44.000 12
4583.409 48Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N
4583.415 47Ti 3 / 2 −6.630 −29.402 13 5 / 2 −84.210 −53.680 12
4583.421 46Ti 3 / 2 0.000 0.000 N 5 / 2 0.000 0.000 N

Reference. 1) Ertmer & Hofer (1976, ABMR); 2) Başar et al. (2004, theoretical calculations); 3) Singh et al. (1991); 4) Childs (1971); 5) Aboussaïd et al. (1996); 6) Mansour et al. (1989); 7) Young et al. (1988); 8) statistically-weighted average of Mansour et al. (1989) and Villemoes et al. (1992); 9) Arnesen et al. (1982); 10) Aydin et al. (1990); 11) Gangrsky et al. (1995); 12) Berrah-Mansour et al. (1992); 13) Nouri et al. (2010).

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