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Table A.3
Vacuum wavenumbers (cm-1) of clean CH B−X transitions in CS 22942-019 used for the calculation of the constants.
| 0−0 | ||||||
| J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
|
||||||
| 0.5 | ... | ... | ... | ... | ... | ... |
| 1.5 | ... | ... | ... | ... | ... | ... |
| 2.5 | ... | ... | ... | ... | ... | ... |
| 3.5 | ... | ... | ... | ... | ... | ... |
| 4.5 | ... | ... | ... | ... | ... | ... |
| 5.5 | ... | ... | ... | ... | ... | ... |
| 6.5 | ... | ... | ... | ... | ... | ... |
| 7.5 | ... | ... | ... | ... | ... | ... |
| 8.5 | 25818.70(–2) | ... | ... | ... | ... | ... |
| 9.5 | 25811.97(5) | ... | ... | ... | ... | 25346.72(–2) |
| 10.5 | 25800.62(0) | ... | ... | ... | ... | 25290.21(–4) |
| 11.5 | 25784.50(–3) | ... | ... | ... | ... | 25230.22(6) |
| 12.5 | 25763.17(–16) | ... | ... | 25448.78(–9) | ... | 25166.27(–1) |
| 13.5 | 25736.64(4) | ... | ... | 25401.09(0) | ... | 25098.40(1) |
| 14.5 | 25703.89(2) | ... | ... | 25348.17(0) | ... | 25026.15(–4) |
| 15.5 | 25664.56(3) | ... | ... | ... | ... | ... |
| 16.5 | 25617.93(11) | ... | ... | 25225.06(8) | ... | 24867.48(2) |
| 17.5 | 25562.84(9) | ... | ... | 25153.60(19) | ... | 24779.83(–11) |
| 18.5 | ... | ... | ... | 25074.30(32) | ... | 24686.15(6) |
| 19.5 | 25422.37(58) | ... | ... | 24985.75(36) | ... | 24585.13(16) |
| 20.5 | 25331.48(–27) | ... | ... | 24886.24(33) | ... | 24475.95(65) |
| 21.5 | 25226.27(161) | ... | ... | 24773.20(2) | ... | 24355.86(49) |
| 22.5 | ... | ... | ... | ... | ... | 24222.96(14) |
|
|
||||||
| J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
| 0.5 | ... | ... | ... | ... | ... | ... |
| 1.5 | ... | ... | ... | ... | ... | ... |
| 2.5 | ... | ... | ... | ... | ... | ... |
| 3.5 | ... | ... | ... | ... | ... | ... |
| 4.5 | ... | ... | ... | ... | ... | ... |
| 5.5 | ... | ... | ... | ... | ... | ... |
| 6.5 | ... | ... | ... | ... | ... | ... |
| 7.5 | ... | ... | ... | ... | ... | ... |
| 8.5 | ... | 25813.72(13) | ... | ... | 25348.32(–5) | ... |
| 9.5 | ... | 25802.33(17) | ... | ... | 25291.78(3) | ... |
| 10.5 | ... | 25785.95(–2) | ... | ... | 25231.56(1) | ... |
| 11.5 | ... | 25764.50(–17) | 25449.75(–4) | ... | 25167.66(7) | ... |
| 12.5 | ... | 25737.98(11) | 25401.83(–8) | ... | 25099.60(–2) | ... |
| 13.5 | ... | 25704.87(–20) | 25348.90(1) | ... | 25027.34(–2) | ... |
| 14.5 | ... | ... | ... | ... | ... | ... |
| 15.5 | ... | 25618.92(0) | 25225.51(–4) | ... | 24868.53(1) | ... |
| 16.5 | ... | 25563.82(3) | 25153.91(1) | ... | 24780.94(–3) | ... |
| 17.5 | ... | ... | 25074.30(–10) | ... | 24687.07(–1) | ... |
| 18.5 | ... | 25422.37(–38) | 24985.75(0) | ... | 24586.04(12) | ... |
| 19.5 | ... | 25331.48(–119) | 24886.24(3) | ... | 24476.97(75) | ... |
| 20.5 | ... | 25226.27(73) | 24773.20(–23) | ... | 24355.86(–39) | ... |
| 21.5 | ... | ... | ... | ... | 24222.96(–71) | ... |
| 22.5 | ... | ... | ... | ... | ... | ... |
|
|
||||||
| 0−1 | ||||||
| J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
|
||||||
| 13.5 | ... | ... | ... | ... | ... | ... |
| 14.5 | 23081.21(2) | ... | ... | 22725.85(9) | ... | ... |
| 15.5 | 23057.47(2) | ... | ... | ... | ... | ... |
| 16.5 | ... | ... | ... | 22634.88(3) | ... | ... |
| 17.5 | ... | ... | ... | ... | ... | ... |
| 18.5 | ... | ... | ... | 22520.41(32) | ... | 22131.84(5) |
| 19.5 | ... | ... | ... | 22451.48(37) | ... | ... |
| 20.5 | ... | ... | ... | 22372.70(50) | ... | 21961.10(3) |
|
|
||||||
| J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
| 13.5 | ... | ... | 22726.42(–7) | ... | ... | ... |
| 14.5 | ... | 23058.59(1) | ... | ... | ... | ... |
| 15.5 | ... | ... | 22635.39(–3) | ... | ... | ... |
| 16.5 | ... | ... | ... | ... | ... | ... |
| 17.5 | ... | ... | 22520.41(–12) | ... | 22132.87(12) | ... |
| 18.5 | ... | ... | 22451.48(0) | ... | ... | ... |
| 19.5 | ... | ... | 22372.70(18) | ... | 21962.02(4) | ... |
| 20.5 | ... | ... | ... | ... | ... | ... |
|
|
||||||
| 1−0 | ||||||
| J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
|
||||||
| 4.5 | ... | ... | ... | ... | ... | ... |
| 5.5 | 27545.34(4) | ... | ... | 27413.23(1) | ... | 27304.25(–5) |
| 6.5 | 27528.43(16) | ... | ... | 27375.24(5) | ... | 27245.60(0) |
| 7.5 | 27503.58(9) | ... | ... | 27330.17(17) | ... | 27180.45(10) |
| 8.5 | 27470.39(2) | ... | ... | 27277.15(–10) | ... | 27108.33(7) |
| 9.5 | 27428.13(2) | ... | ... | 27216.47(11) | ... | 27028.91(–5) |
| 10.5 | 27375.70(4) | ... | ... | 27146.76(17) | ... | 26941.79(–11) |
| 11.5 | 27312.23(64) | ... | ... | 27066.68(–23) | ... | 26846.26(–9) |
| 12.5 | 27233.37(–64) | ... | ... | 26976.32(39) | ... | 26741.50(17) |
| 13.5 | ... | ... | ... | 26872.12(35) | ... | 26626.07(62) |
| 14.5 | ... | ... | ... | ... | ... | 26495.18(–170) |
|
|
||||||
| J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
| 4.5 | ... | 27548.20(20) | 27415.68(–4) | ... | 27306.93(–3) | ... |
| 5.5 | ... | 27530.63(6) | 27377.27(2) | ... | 27247.88(3) | ... |
| 6.5 | ... | 27505.62(12) | 27331.91(17) | ... | 27182.45(14) | ... |
| 7.5 | ... | 27472.22(7) | 27278.71(–2) | ... | 27110.20(19) | ... |
| 8.5 | ... | 27429.83(10) | 27217.80(15) | ... | 27030.55(2) | ... |
| 9.5 | ... | 27377.03(–12) | 27147.98(27) | ... | 26943.32(–2) | ... |
| 10.5 | ... | 27312.23(–74) | 27067.70(–19) | ... | 26847.66(–3) | ... |
| 11.5 | ... | 27233.37(–193) | 26976.32(–48) | ... | 26742.74(17) | ... |
| 12.5 | ... | ... | 26872.12(–41) | ... | 26626.07(–55) | ... |
| 13.5 | ... | ... | ... | ... | 26495.18(–282) | ... |
| 14.5 | ... | ... | ... | ... | ... | ... |
|
|
||||||
| 1−1 | ||||||
| J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
|
||||||
| 7.5 | ... | ... | ... | ... | ... | ... |
| 8.5 | 24775.47(2) | ... | ... | ... | ... | 24413.37(3) |
| 9.5 | ... | ... | ... | 24531.08(6) | ... | 24343.58(8) |
| 10.5 | 24700.85(14) | ... | ... | 24471.76(–3) | ... | 24266.94(–1) |
| 11.5 | 24648.17(–1) | ... | ... | 24403.60(–7) | ... | 24182.83(–12) |
| 12.5 | 24585.56(240) | ... | ... | 24325.46(17) | ... | 24090.70(22) |
| 13.5 | ... | ... | ... | 24237.35(261) | ... | 23989.76(158) |
|
|
||||||
| J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
| 7.5 | ... | 24777.19(1) | ... | ... | 24415.04(1) | ... |
| 8.5 | ... | ... | 24532.29(1) | ... | 24345.06(4) | ... |
| 9.5 | ... | 24701.77(–39) | 24472.84(–4) | ... | 24268.36(1) | ... |
| 10.5 | ... | 24648.17(–135) | 24404.61(–2) | ... | 24184.17(–7) | ... |
| 11.5 | ... | 24585.56(114) | 24325.46(–68) | ... | 24091.74(5) | ... |
| 12.5 | ... | ... | 24237.35(186) | ... | 23989.76(44) | ... |
| 13.5 | ... | ... | ... | ... | ... | ... |
Notes. The numbers in parentheses are the observed minus calculated value. The numbers in italics are predissociation lines where the accuracy of the position is low.
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