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Table A.3

Vacuum wavenumbers (cm-1) of clean CH BX transitions in CS 22942-019 used for the calculation of the constants.

00
J R11ff R11ee Q11ef Q11fe P11ee P11ff

0.5 ... ... ... ... ... ...
1.5 ... ... ... ... ... ...
2.5 ... ... ... ... ... ...
3.5 ... ... ... ... ... ...
4.5 ... ... ... ... ... ...
5.5 ... ... ... ... ... ...
6.5 ... ... ... ... ... ...
7.5 ... ... ... ... ... ...
8.5 25818.70(–2) ... ... ... ... ...
9.5 25811.97(5) ... ... ... ... 25346.72(–2)
10.5 25800.62(0) ... ... ... ... 25290.21(–4)
11.5 25784.50(–3) ... ... ... ... 25230.22(6)
12.5 25763.17(–16) ... ... 25448.78(–9) ... 25166.27(–1)
13.5 25736.64(4) ... ... 25401.09(0) ... 25098.40(1)
14.5 25703.89(2) ... ... 25348.17(0) ... 25026.15(–4)
15.5 25664.56(3) ... ... ... ... ...
16.5 25617.93(11) ... ... 25225.06(8) ... 24867.48(2)
17.5 25562.84(9) ... ... 25153.60(19) ... 24779.83(–11)
18.5 ... ... ... 25074.30(32) ... 24686.15(6)
19.5 25422.37(58) ... ... 24985.75(36) ... 24585.13(16)
20.5 25331.48(–27) ... ... 24886.24(33) ... 24475.95(65)
21.5 25226.27(161) ... ... 24773.20(2) ... 24355.86(49)
22.5 ... ... ... ... ... 24222.96(14)

J R22ff R22ee Q22ef Q22fe P22ff P22ee
0.5 ... ... ... ... ... ...
1.5 ... ... ... ... ... ...
2.5 ... ... ... ... ... ...
3.5 ... ... ... ... ... ...
4.5 ... ... ... ... ... ...
5.5 ... ... ... ... ... ...
6.5 ... ... ... ... ... ...
7.5 ... ... ... ... ... ...
8.5 ... 25813.72(13) ... ... 25348.32(–5) ...
9.5 ... 25802.33(17) ... ... 25291.78(3) ...
10.5 ... 25785.95(–2) ... ... 25231.56(1) ...
11.5 ... 25764.50(–17) 25449.75(–4) ... 25167.66(7) ...
12.5 ... 25737.98(11) 25401.83(–8) ... 25099.60(–2) ...
13.5 ... 25704.87(–20) 25348.90(1) ... 25027.34(–2) ...
14.5 ... ... ... ... ... ...
15.5 ... 25618.92(0) 25225.51(–4) ... 24868.53(1) ...
16.5 ... 25563.82(3) 25153.91(1) ... 24780.94(–3) ...
17.5 ... ... 25074.30(–10) ... 24687.07(–1) ...
18.5 ... 25422.37(–38) 24985.75(0) ... 24586.04(12) ...
19.5 ... 25331.48(–119) 24886.24(3) ... 24476.97(75) ...
20.5 ... 25226.27(73) 24773.20(–23) ... 24355.86(–39) ...
21.5 ... ... ... ... 24222.96(–71) ...
22.5 ... ... ... ... ... ...

01
J R11ff R11ee Q11ef Q11fe P11ee P11ff

13.5 ... ... ... ... ... ...
14.5 23081.21(2) ... ... 22725.85(9) ... ...
15.5 23057.47(2) ... ... ... ... ...
16.5 ... ... ... 22634.88(3) ... ...
17.5 ... ... ... ... ... ...
18.5 ... ... ... 22520.41(32) ... 22131.84(5)
19.5 ... ... ... 22451.48(37) ... ...
20.5 ... ... ... 22372.70(50) ... 21961.10(3)

J R22ff R22ee Q22ef Q22fe P22ff P22ee
13.5 ... ... 22726.42(–7) ... ... ...
14.5 ... 23058.59(1) ... ... ... ...
15.5 ... ... 22635.39(–3) ... ... ...
16.5 ... ... ... ... ... ...
17.5 ... ... 22520.41(–12) ... 22132.87(12) ...
18.5 ... ... 22451.48(0) ... ... ...
19.5 ... ... 22372.70(18) ... 21962.02(4) ...
20.5 ... ... ... ... ... ...

10
J R11ff R11ee Q11ef Q11fe P11ee P11ff

4.5 ... ... ... ... ... ...
5.5 27545.34(4) ... ... 27413.23(1) ... 27304.25(–5)
6.5 27528.43(16) ... ... 27375.24(5) ... 27245.60(0)
7.5 27503.58(9) ... ... 27330.17(17) ... 27180.45(10)
8.5 27470.39(2) ... ... 27277.15(–10) ... 27108.33(7)
9.5 27428.13(2) ... ... 27216.47(11) ... 27028.91(–5)
10.5 27375.70(4) ... ... 27146.76(17) ... 26941.79(–11)
11.5 27312.23(64) ... ... 27066.68(–23) ... 26846.26(–9)
12.5 27233.37(–64) ... ... 26976.32(39) ... 26741.50(17)
13.5 ... ... ... 26872.12(35) ... 26626.07(62)
14.5 ... ... ... ... ... 26495.18(–170)

J R22ff R22ee Q22ef Q22fe P22ff P22ee
4.5 ... 27548.20(20) 27415.68(–4) ... 27306.93(–3) ...
5.5 ... 27530.63(6) 27377.27(2) ... 27247.88(3) ...
6.5 ... 27505.62(12) 27331.91(17) ... 27182.45(14) ...
7.5 ... 27472.22(7) 27278.71(–2) ... 27110.20(19) ...
8.5 ... 27429.83(10) 27217.80(15) ... 27030.55(2) ...
9.5 ... 27377.03(–12) 27147.98(27) ... 26943.32(–2) ...
10.5 ... 27312.23(–74) 27067.70(–19) ... 26847.66(–3) ...
11.5 ... 27233.37(–193) 26976.32(–48) ... 26742.74(17) ...
12.5 ... ... 26872.12(–41) ... 26626.07(–55) ...
13.5 ... ... ... ... 26495.18(–282) ...
14.5 ... ... ... ... ... ...

11
J R11ff R11ee Q11ef Q11fe P11ee P11ff

7.5 ... ... ... ... ... ...
8.5 24775.47(2) ... ... ... ... 24413.37(3)
9.5 ... ... ... 24531.08(6) ... 24343.58(8)
10.5 24700.85(14) ... ... 24471.76(–3) ... 24266.94(–1)
11.5 24648.17(–1) ... ... 24403.60(–7) ... 24182.83(–12)
12.5 24585.56(240) ... ... 24325.46(17) ... 24090.70(22)
13.5 ... ... ... 24237.35(261) ... 23989.76(158)

J R22ff R22ee Q22ef Q22fe P22ff P22ee
7.5 ... 24777.19(1) ... ... 24415.04(1) ...
8.5 ... ... 24532.29(1) ... 24345.06(4) ...
9.5 ... 24701.77(–39) 24472.84(–4) ... 24268.36(1) ...
10.5 ... 24648.17(–135) 24404.61(–2) ... 24184.17(–7) ...
11.5 ... 24585.56(114) 24325.46(–68) ... 24091.74(5) ...
12.5 ... ... 24237.35(186) ... 23989.76(44) ...
13.5 ... ... ... ... ... ...

Notes. The numbers in parentheses are the observed minus calculated value. The numbers in italics are predissociation lines where the accuracy of the position is low.

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