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Table A.2
Vacuum wavenumbers (cm-1) of clean CH A−X transitions in CS22942-019 used for the calculation of the constants.
0−0 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
27.5 | ... | ... | ... | ... | 22713.66(11) | ... |
28.5 | ... | ... | ... | ... | 22706.44(23) | ... |
29.5 | 24138.80(12) | ... | ... | 23400.12(22) | ... | ... |
30.5 | 24159.33(22) | 24134.84(41) | 23431.16(13) | ... | 22691.34(19) | ... |
31.5 | ... | 24151.75(54) | 23437.20(23) | ... | 22683.31(26) | 22708.81(1) |
32.5 | 24192.13(27) | 24165.46(39) | ... | ... | ... | 22701.03(–1) |
33.5 | 24203.43(–4) | 24176.22(55) | ... | ... | 22664.79(32) | ... |
34.5 | 24210.99(–39) | 24180.89(–169) | ... | ... | 22653.45(–1) | ... |
35.5 | ... | ... | 23438.52(–91) | ... | ... | 22670.04(–59) |
36.5 | ... | ... | ... | ... | 22625.61(–61) | ... |
|
||||||
J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
26.5 | ... | ... | ... | ... | ... | 22712.42(11) |
27.5 | ... | ... | ... | ... | ... | 22705.00(8) |
28.5 | 24113.94(28) | 24138.39(35) | 23398.75(24) | ... | ... | 22697.62(17) |
29.5 | 24133.44(48) | 24158.81(37) | ... | 23430.89(51) | ... | 22689.95(20) |
30.5 | 24150.17(48) | ... | ... | 23436.54(26) | 22708.20(4) | 22681.82(22) |
31.5 | 24163.95(42) | 24191.43(31) | ... | ... | 22700.46(10) | 22672.97(22) |
32.5 | 24174.40(32) | 24202.96(25) | ... | ... | ... | ... |
33.5 | 24179.32(–166) | 24210.29(–31) | ... | ... | ... | 22652.01(11) |
34.5 | ... | ... | ... | 23437.70(–95) | ... | 22639.13(–12) |
|
||||||
1−1 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
19.5 | ... | ... | ... | ... | ... | ... |
20.5 | 23785.15(–8) | 23772.25(–7) | ... | ... | 22740.01(–4) | 22752.95(–2) |
21.5 | 23807.80(–20) | 23793.92(–11) | ... | ... | 22723.58(95) | 22736.65(4) |
22.5 | 23829.09(–6) | 23813.93(–16) | ... | ... | 22705.20(4) | 22720.01(–22) |
23.5 | 23848.18(–23) | ... | ... | ... | 22687.43(–9) | 22703.50(–17) |
24.5 | ... | 23848.18(–13) | ... | ... | ... | 22686.60(–16) |
25.5 | ... | 23861.90(–3) | ... | ... | 22650.93(–6) | ... |
26.5 | 23892.07(–9) | 23872.79(0) | ... | ... | 22631.70(0) | 22650.93(–17) |
27.5 | 23901.15(20) | ... | ... | ... | 22611.43(4) | 22631.70(–16) |
28.5 | 23906.07(–11) | 23884.99(31) | ... | ... | ... | 22611.43(14) |
29.5 | 23907.61(26) | 23884.99(17) | ... | ... | ... | ... |
30.5 | 23903.32(–62) | ... | ... | ... | ... | ... |
31.5 | 23895.21(–14) | 23870.68(–14) | ... | ... | ... | ... |
32.5 | ... | ... | ... | 23165.29(–8) | ... | ... |
|
||||||
J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
19.5 | 23771.69(2) | 23785.15(–2) | ... | ... | 22752.95(–3) | 22739.55(8) |
20.5 | 23793.24(–4) | 23807.80(–7) | ... | ... | 22736.65(10) | 22722.65(70) |
21.5 | 23813.02(–24) | 23829.09(13) | ... | ... | 22720.01(–9) | 22704.33(–7) |
22.5 | 23831.24(–12) | 23848.18(2) | ... | ... | 22703.50(2) | ... |
23.5 | 23847.27(–6) | ... | ... | ... | 22686.60(8) | ... |
24.5 | 23860.82(–6) | ... | ... | ... | ... | 22650.93(93) |
25.5 | ... | 23892.07(29) | ... | ... | 22649.90(–87) | 22630.47(–18) |
26.5 | ... | 23901.15(62) | ... | ... | 22631.70(21) | ... |
27.5 | 23883.74(26) | 23906.07(34) | ... | ... | ... | ... |
28.5 | 23883.74(16) | 23907.61(73) | ... | ... | ... | 22565.96(66) |
29.5 | ... | 23903.32(–13) | ... | ... | ... | ... |
30.5 | 23869.25(–26) | 23895.21(37) | ... | ... | ... | ... |
31.5 | ... | ... | 23163.46(–60) | ... | ... | ... |
32.5 | ... | ... | ... | ... | ... | ... |
|
||||||
2−2 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
11.5 | 23429.68(11) | ... | ... | ... | ... | ... |
12.5 | 23452.71(15) | 23447.70(19) | ... | ... | ... | ... |
13.5 | 23475.29(69) | 23468.95(19) | ... | 23118.09(25) | 22789.98(32) | 22795.65(14) |
14.5 | 23495.76(22) | 23489.02(17) | ... | 23115.90(12) | ... | ... |
15.5 | 23515.43(22) | 23507.69(5) | ... | 23113.07(5) | ... | ... |
16.5 | 23533.64(20) | ... | 23118.09(17) | 23109.49(6) | 22714.95(14) | 22723.58(28) |
17.5 | 23550.11(8) | ... | 23114.57(27) | 23104.74(–12) | 22689.33(0) | 22699.07(30) |
18.5 | ... | 23554.16(–17) | 23109.49(–5) | 23098.97(–16) | 22663.25(–14) | 22673.89(8) |
19.5 | 23577.21(–11) | ... | 23103.51(5) | ... | 22636.67(–18) | 22648.31(5) |
20.5 | 23587.28(–20) | 23574.99(–7) | 23095.66(–15) | 23083.13(–26) | ... | 22621.92(–4) |
21.5 | ... | 23581.27(–16) | 23086.12(–22) | 23072.74(–14) | ... | 22594.57(–10) |
22.5 | ... | 23584.38(–28) | 23074.50(–21) | ... | 22551.50(–17) | ... |
23.5 | ... | 23584.38(6) | 23060.18(–41) | 23044.82(–23) | 22520.41(–20) | ... |
24.5 | ... | ... | ... | ... | 22487.54(–16) | 22503.99(–29) |
25.5 | ... | 23570.98(11) | 23023.01(–10) | 23005.42(–7) | ... | 22469.89(–26) |
26.5 | 23574.99(–21) | ... | 22998.70(–2) | ... | 22414.48(–19) | 22433.24(–9) |
27.5 | 23555.88(5) | ... | ... | ... | ... | 22393.04(–22) |
28.5 | ... | 23509.18(35) | ... | ... | 22329.17(55) | 22350.69(137) |
29.5 | ... | ... | ... | ... | 22279.51(42) | 22300.93(15) |
30.5 | ... | ... | ... | ... | ... | 22246.69(–12) |
31.5 | ... | ... | ... | ... | 22162.46(–36) | 22185.77(–66) |
|
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J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
10.5 | ... | 23430.28(–19) | ... | ... | ... | ... |
11.5 | 23447.70(–20) | 23453.42(11) | ... | ... | ... | ... |
12.5 | 23468.95(–3) | 23475.29(7) | 23118.09(–2) | ... | 22796.27(5) | 22789.98(0) |
13.5 | 23489.02(10) | 23495.76(–28) | 23115.90(0) | ... | ... | ... |
14.5 | 23507.69(10) | 23515.43(–18) | 23113.07(6) | ... | ... | ... |
15.5 | ... | 23533.64(–10) | 23109.49(20) | 23118.09(–16) | 22723.58(–10) | 22714.95(24) |
16.5 | ... | 23550.11(–14) | 23104.74(13) | 23114.57(2) | 22699.07(1) | 22689.33(21) |
17.5 | 23553.94(–1) | ... | 23098.97(19) | 23109.49(–23) | 22673.53(–49) | 22663.25(17) |
18.5 | ... | 23577.21(–19) | ... | 23103.51(–6) | 22648.31(–9) | 22636.52(8) |
19.5 | 23574.43(–8) | 23587.28(–23) | 23082.71(–16) | 23095.66(–20) | 22621.92(–11) | 22609.03(0) |
20.5 | 23580.82(1) | ... | 23072.16(–13) | 23086.12(–22) | 22594.57(–12) | ... |
21.5 | 23583.61(–38) | ... | 23059.28(–28) | 23074.50(–17) | ... | 22550.79(–24) |
22.5 | 23583.61(1) | ... | ... | 23060.18(–32) | ... | 22519.70(–20) |
23.5 | ... | ... | ... | ... | 22503.99(–18) | 22486.62(–31) |
24.5 | 23569.98(–7) | ... | 23004.68(1) | 23023.01(4) | 22469.89(–13) | ... |
25.5 | 23556.27(58) | 23574.99(–5) | ... | 22998.70(14) | 22433.24(6) | 22413.72(–10) |
26.5 | ... | 23555.88(21) | ... | ... | 22393.04(–5) | ... |
27.5 | ... | ... | ... | ... | 22350.69(155) | 22327.83(10) |
28.5 | ... | ... | ... | ... | 22300.93(33) | 22278.17(0) |
29.5 | ... | ... | ... | ... | 22246.69(6) | ... |
30.5 | ... | ... | ... | ... | 22185.77(–50) | 22161.57(–31) |
31.5 | ... | ... | ... | ... | ... | ... |
|
||||||
3−3 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
11.5 | ... | ... | ... | ... | ... | ... |
12.5 | ... | ... | ... | ... | 22638.01(19) | ... |
13.5 | ... | ... | ... | ... | 22606.47(29) | ... |
14.5 | ... | ... | ... | 22900.34(9) | 22573.75(17) | ... |
15.5 | ... | ... | ... | 22886.66(2) | 22540.01(14) | 22547.33(20) |
16.5 | ... | ... | 22879.38(21) | ... | ... | ... |
17.5 | ... | ... | ... | 22853.02(–15) | 22468.28(–9) | ... |
18.5 | ... | ... | 22842.73(2) | 22832.61(–11) | 22429.92(–22) | 22440.19(7) |
19.5 | ... | ... | ... | ... | ... | 22400.67(–14) |
20.5 | ... | ... | 22794.19(–29) | 22782.35(–22) | 22346.89(–32) | 22358.99(–14) |
21.5 | ... | ... | 22764.61(–20) | 22751.66(–25) | ... | 22314.37(–29) |
22.5 | ... | ... | 22730.50(–13) | 22716.55(–18) | 22252.73(–30) | 22266.71(–21) |
23.5 | ... | ... | ... | ... | 22200.30(–12) | 22215.10(–22) |
24.5 | 23141.75(17) | ... | ... | ... | 22143.36(9) | 22159.16(1) |
25.5 | ... | 23079.67(19) | 22593.60(23) | 22576.86(37) | ... | ... |
26.5 | ... | ... | 22532.79(8) | ... | ... | ... |
27.5 | ... | ... | 22461.62(–91) | 22443.41(–27) | ... | ... |
|
||||||
J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
11.5 | ... | ... | ... | ... | ... | 22638.26(–4) |
12.5 | ... | ... | ... | ... | 22612.51(1) | 22606.47(–3) |
13.5 | ... | ... | 22900.34(–2) | ... | ... | 22573.75(0) |
14.5 | ... | ... | 22886.66(5) | ... | 22547.53(–7) | 22540.01(11) |
15.5 | ... | ... | ... | 22879.38(–10) | ... | ... |
16.5 | ... | ... | 22853.02(13) | ... | ... | 22468.28(13) |
17.5 | ... | ... | 22832.61(27) | 22842.73(–11) | 22440.19(–11) | 22429.92(12) |
18.5 | ... | ... | ... | ... | 22400.67(–23) | ... |
19.5 | ... | ... | 22781.88(–10) | 22794.19(–27) | 22358.99(–16) | 22346.54(–13) |
20.5 | ... | ... | 22751.24(2) | 22764.61(–10) | 22314.37(–24) | ... |
21.5 | ... | ... | 22715.88(–9) | 22730.50(3) | 22266.71(–9) | 22252.19(–12) |
22.5 | ... | ... | ... | ... | 22215.10(–3) | 22199.61(–1) |
23.5 | ... | 23141.75(49) | ... | ... | 22159.16(25) | 22142.38(0) |
24.5 | 23078.71(27) | ... | 22576.05(56) | 22593.60(57) | ... | ... |
25.5 | ... | ... | ... | 22532.79(47) | ... | ... |
26.5 | ... | ... | ... | 22461.62(–47) | ... | ... |
27.5 | ... | ... | ... | ... | ... | ... |
|
||||||
4−4 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
2.5 | 22766.84(5) | 22766.84(18) | ... | ... | ... | ... |
3.5 | ... | ... | 22694.84(–16) | 22694.84(15) | ... | ... |
4.5 | ... | ... | ... | ... | ... | ... |
5.5 | ... | ... | 22684.18(5) | ... | 22569.68(8) | ... |
6.5 | ... | ... | ... | ... | ... | ... |
7.5 | ... | ... | 22666.75(–13) | 22665.00(–21) | ... | 22509.21(–5) |
8.5 | ... | ... | 22655.60(–5) | 22653.55(6) | ... | ... |
9.5 | ... | 22860.44(–16) | 22642.52(2) | 22639.65(–15) | ... | ... |
10.5 | ... | ... | 22627.20(–7) | 22623.97(0) | ... | 22406.49(3) |
11.5 | ... | ... | ... | 22605.91(10) | ... | 22368.84(–2) |
12.5 | ... | ... | ... | 22585.43(31) | 22324.83(15) | 22329.32(0) |
13.5 | ... | 22859.29(14) | ... | 22561.78(15) | 22282.44(14) | ... |
14.5 | ... | ... | ... | 22535.23(19) | ... | ... |
15.5 | ... | ... | 22512.25(28) | 22504.95(–6) | 22190.20(11) | 22197.44(39) |
16.5 | ... | 22817.87(–15) | 22479.09(19) | 22471.01(–9) | 22139.68(1) | 22147.78(30) |
17.5 | ... | ... | ... | 22432.69(–11) | ... | 22094.67(12) |
18.5 | ... | ... | 22399.01(–3) | 22389.38(–9) | 22027.97(–22) | 22037.83(6) |
19.5 | ... | ... | 22350.69(–17) | 22339.95(–42) | ... | ... |
20.5 | ... | ... | 22295.81(–16) | 22284.43(–13) | ... | ... |
21.5 | ... | ... | 22233.08(–13) | 22220.88(1) | ... | ... |
22.5 | ... | ... | 22161.33(13) | ... | ... | ... |
23.5 | 22489.41(–41) | ... | 22078.47(29) | ... | ... | ... |
|
||||||
J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
2.5 | ... | ... | ... | ... | ... | ... |
3.5 | ... | ... | 22693.20(21) | 22693.66(–2) | ... | ... |
4.5 | ... | ... | 22685.83(9) | ... | ... | ... |
5.5 | ... | ... | ... | 22678.37(–11) | ... | ... |
6.5 | ... | ... | 22666.75(–3) | 22668.65(–1) | ... | 22509.21(–5) |
7.5 | ... | ... | 22654.78(4) | 22657.04(–10) | ... | ... |
8.5 | ... | ... | ... | 22643.80(5) | ... | ... |
9.5 | ... | ... | 22624.58(–14) | 22628.27(–5) | ... | ... |
10.5 | ... | ... | 22606.01(–37) | ... | 22369.74(–6) | ... |
11.5 | ... | ... | 22585.43(–8) | ... | 22330.07(–5) | 22324.83(–30) |
12.5 | 22859.29(–4) | ... | 22561.78(–8) | ... | ... | 22282.44(–15) |
13.5 | ... | ... | 22535.23(10) | ... | ... | ... |
14.5 | ... | ... | 22504.95(–2) | 22512.25(–10) | 22197.44(–4) | 22190.20(9) |
15.5 | 22817.87(5) | ... | 22471.01(7) | 22479.09(–9) | 22147.78(–4) | 22139.68(12) |
16.5 | ... | ... | 22432.69(16) | ... | 22094.67(–12) | ... |
17.5 | ... | ... | 22389.38(28) | 22399.01(–14) | 22037.83(–9) | 22027.97(11) |
18.5 | ... | ... | 22339.90(0) | 22350.69(–20) | ... | ... |
19.5 | ... | ... | 22283.93(–6) | 22295.81(–12) | ... | ... |
20.5 | ... | ... | 22220.34(12) | 22233.08(–3) | ... | ... |
21.5 | ... | ... | ... | 22161.33(30) | ... | ... |
22.5 | ... | 22489.41(–15) | ... | 22078.47(51) | ... | ... |
23.5 | ... | ... | ... | ... | ... | ... |
|
||||||
5−5 | ||||||
J | R11ff | R11ee | Q11ef | Q11fe | P11ee | P11ff |
|
||||||
2.5 | 22330.87(–17) | 22330.87(–4) | ... | ... | ... | ... |
3.5 | 22344.29(–20) | 22344.29(10) | 22261.95(–38) | 22261.95(–8) | ... | ... |
4.5 | 22354.89(0) | 22354.24(–11) | 22252.58(–9) | 22252.58(45) | ... | ... |
5.5 | 22362.19(5) | ... | ... | ... | ... | ... |
6.5 | 22366.44(33) | ... | 22225.42(67) | 22223.30(–26) | ... | ... |
7.5 | 22366.44(–14) | ... | 22206.17(–10) | 22204.69(3) | ... | ... |
8.5 | ... | ... | 22184.39(–12) | 22182.57(13) | ... | ... |
9.5 | 22355.79(–8) | 22353.19(–8) | 22159.07(–18) | 22156.46(–19) | ... | ... |
10.5 | ... | ... | 22130.08(–10) | 22127.38(37) | ... | ... |
11.5 | 22327.03(–12) | ... | ... | 22093.54(39) | ... | ... |
12.5 | 22305.11(29) | ... | 22059.42(30) | 22054.75(8) | ... | ... |
13.5 | ... | ... | 22016.43(25) | 22011.09(7) | ... | ... |
14.5 | ... | ... | 21967.71(21) | 21961.29(–32) | ... | ... |
15.5 | 22197.89(15) | 22191.04(–3) | 21912.29(–5) | 21906.29(61) | ... | ... |
16.5 | 22145.62(11) | ... | ... | 21842.11(–20) | ... | ... |
|
||||||
J | R22ff | R22ee | Q22ef | Q22fe | P22ff | P22ee |
1.5 | 22336.55(–2) | 22336.55(–20) | ... | ... | ... | ... |
2.5 | ... | ... | ... | ... | ... | ... |
3.5 | ... | ... | ... | ... | ... | ... |
4.5 | ... | ... | ... | ... | ... | ... |
5.5 | ... | ... | ... | ... | ... | ... |
6.5 | ... | ... | 22206.17(4) | ... | ... | ... |
7.5 | ... | ... | 22183.46(–15) | 22185.82(–8) | ... | ... |
8.5 | ... | ... | 22157.49(–8) | 22160.49(8) | ... | ... |
9.5 | ... | ... | 22128.66(93) | 22131.15(0) | ... | ... |
10.5 | ... | ... | 22093.54(–14) | ... | ... | ... |
11.5 | ... | 22305.11(–34) | 22054.75(–28) | 22059.42(–37) | ... | ... |
12.5 | ... | ... | 22011.09(–15) | 22016.43(–30) | ... | ... |
13.5 | ... | ... | 21961.29(–40) | 21967.71(–23) | ... | ... |
14.5 | 22191.04(6) | 22197.89(–14) | 21906.29(66) | 21912.29(–38) | ... | ... |
15.5 | ... | 22145.62(–9) | 21842.11(–4) | ... | ... | ... |
16.5 | ... | ... | ... | ... | ... | ... |
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