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Table A.2

Vacuum wavenumbers (cm-1) of clean CH AX transitions in CS22942-019 used for the calculation of the constants.

00
J R11ff R11ee Q11ef Q11fe P11ee P11ff

27.5 ... ... ... ... 22713.66(11) ...
28.5 ... ... ... ... 22706.44(23) ...
29.5 24138.80(12) ... ... 23400.12(22) ... ...
30.5 24159.33(22) 24134.84(41) 23431.16(13) ... 22691.34(19) ...
31.5 ... 24151.75(54) 23437.20(23) ... 22683.31(26) 22708.81(1)
32.5 24192.13(27) 24165.46(39) ... ... ... 22701.03(–1)
33.5 24203.43(–4) 24176.22(55) ... ... 22664.79(32) ...
34.5 24210.99(–39) 24180.89(–169) ... ... 22653.45(–1) ...
35.5 ... ... 23438.52(–91) ... ... 22670.04(–59)
36.5 ... ... ... ... 22625.61(–61) ...

J R22ff R22ee Q22ef Q22fe P22ff P22ee
26.5 ... ... ... ... ... 22712.42(11)
27.5 ... ... ... ... ... 22705.00(8)
28.5 24113.94(28) 24138.39(35) 23398.75(24) ... ... 22697.62(17)
29.5 24133.44(48) 24158.81(37) ... 23430.89(51) ... 22689.95(20)
30.5 24150.17(48) ... ... 23436.54(26) 22708.20(4) 22681.82(22)
31.5 24163.95(42) 24191.43(31) ... ... 22700.46(10) 22672.97(22)
32.5 24174.40(32) 24202.96(25) ... ... ... ...
33.5 24179.32(–166) 24210.29(–31) ... ... ... 22652.01(11)
34.5 ... ... ... 23437.70(–95) ... 22639.13(–12)

11
J R11ff R11ee Q11ef Q11fe P11ee P11ff

19.5 ... ... ... ... ... ...
20.5 23785.15(–8) 23772.25(–7) ... ... 22740.01(–4) 22752.95(–2)
21.5 23807.80(–20) 23793.92(–11) ... ... 22723.58(95) 22736.65(4)
22.5 23829.09(–6) 23813.93(–16) ... ... 22705.20(4) 22720.01(–22)
23.5 23848.18(–23) ... ... ... 22687.43(–9) 22703.50(–17)
24.5 ... 23848.18(–13) ... ... ... 22686.60(–16)
25.5 ... 23861.90(–3) ... ... 22650.93(–6) ...
26.5 23892.07(–9) 23872.79(0) ... ... 22631.70(0) 22650.93(–17)
27.5 23901.15(20) ... ... ... 22611.43(4) 22631.70(–16)
28.5 23906.07(–11) 23884.99(31) ... ... ... 22611.43(14)
29.5 23907.61(26) 23884.99(17) ... ... ... ...
30.5 23903.32(–62) ... ... ... ... ...
31.5 23895.21(–14) 23870.68(–14) ... ... ... ...
32.5 ... ... ... 23165.29(–8) ... ...

J R22ff R22ee Q22ef Q22fe P22ff P22ee
19.5 23771.69(2) 23785.15(–2) ... ... 22752.95(–3) 22739.55(8)
20.5 23793.24(–4) 23807.80(–7) ... ... 22736.65(10) 22722.65(70)
21.5 23813.02(–24) 23829.09(13) ... ... 22720.01(–9) 22704.33(–7)
22.5 23831.24(–12) 23848.18(2) ... ... 22703.50(2) ...
23.5 23847.27(–6) ... ... ... 22686.60(8) ...
24.5 23860.82(–6) ... ... ... ... 22650.93(93)
25.5 ... 23892.07(29) ... ... 22649.90(–87) 22630.47(–18)
26.5 ... 23901.15(62) ... ... 22631.70(21) ...
27.5 23883.74(26) 23906.07(34) ... ... ... ...
28.5 23883.74(16) 23907.61(73) ... ... ... 22565.96(66)
29.5 ... 23903.32(–13) ... ... ... ...
30.5 23869.25(–26) 23895.21(37) ... ... ... ...
31.5 ... ... 23163.46(–60) ... ... ...
32.5 ... ... ... ... ... ...

22
J R11ff R11ee Q11ef Q11fe P11ee P11ff

11.5 23429.68(11) ... ... ... ... ...
12.5 23452.71(15) 23447.70(19) ... ... ... ...
13.5 23475.29(69) 23468.95(19) ... 23118.09(25) 22789.98(32) 22795.65(14)
14.5 23495.76(22) 23489.02(17) ... 23115.90(12) ... ...
15.5 23515.43(22) 23507.69(5) ... 23113.07(5) ... ...
16.5 23533.64(20) ... 23118.09(17) 23109.49(6) 22714.95(14) 22723.58(28)
17.5 23550.11(8) ... 23114.57(27) 23104.74(–12) 22689.33(0) 22699.07(30)
18.5 ... 23554.16(–17) 23109.49(–5) 23098.97(–16) 22663.25(–14) 22673.89(8)
19.5 23577.21(–11) ... 23103.51(5) ... 22636.67(–18) 22648.31(5)
20.5 23587.28(–20) 23574.99(–7) 23095.66(–15) 23083.13(–26) ... 22621.92(–4)
21.5 ... 23581.27(–16) 23086.12(–22) 23072.74(–14) ... 22594.57(–10)
22.5 ... 23584.38(–28) 23074.50(–21) ... 22551.50(–17) ...
23.5 ... 23584.38(6) 23060.18(–41) 23044.82(–23) 22520.41(–20) ...
24.5 ... ... ... ... 22487.54(–16) 22503.99(–29)
25.5 ... 23570.98(11) 23023.01(–10) 23005.42(–7) ... 22469.89(–26)
26.5 23574.99(–21) ... 22998.70(–2) ... 22414.48(–19) 22433.24(–9)
27.5 23555.88(5) ... ... ... ... 22393.04(–22)
28.5 ... 23509.18(35) ... ... 22329.17(55) 22350.69(137)
29.5 ... ... ... ... 22279.51(42) 22300.93(15)
30.5 ... ... ... ... ... 22246.69(–12)
31.5 ... ... ... ... 22162.46(–36) 22185.77(–66)

J R22ff R22ee Q22ef Q22fe P22ff P22ee
10.5 ... 23430.28(–19) ... ... ... ...
11.5 23447.70(–20) 23453.42(11) ... ... ... ...
12.5 23468.95(–3) 23475.29(7) 23118.09(–2) ... 22796.27(5) 22789.98(0)
13.5 23489.02(10) 23495.76(–28) 23115.90(0) ... ... ...
14.5 23507.69(10) 23515.43(–18) 23113.07(6) ... ... ...
15.5 ... 23533.64(–10) 23109.49(20) 23118.09(–16) 22723.58(–10) 22714.95(24)
16.5 ... 23550.11(–14) 23104.74(13) 23114.57(2) 22699.07(1) 22689.33(21)
17.5 23553.94(–1) ... 23098.97(19) 23109.49(–23) 22673.53(–49) 22663.25(17)
18.5 ... 23577.21(–19) ... 23103.51(–6) 22648.31(–9) 22636.52(8)
19.5 23574.43(–8) 23587.28(–23) 23082.71(–16) 23095.66(–20) 22621.92(–11) 22609.03(0)
20.5 23580.82(1) ... 23072.16(–13) 23086.12(–22) 22594.57(–12) ...
21.5 23583.61(–38) ... 23059.28(–28) 23074.50(–17) ... 22550.79(–24)
22.5 23583.61(1) ... ... 23060.18(–32) ... 22519.70(–20)
23.5 ... ... ... ... 22503.99(–18) 22486.62(–31)
24.5 23569.98(–7) ... 23004.68(1) 23023.01(4) 22469.89(–13) ...
25.5 23556.27(58) 23574.99(–5) ... 22998.70(14) 22433.24(6) 22413.72(–10)
26.5 ... 23555.88(21) ... ... 22393.04(–5) ...
27.5 ... ... ... ... 22350.69(155) 22327.83(10)
28.5 ... ... ... ... 22300.93(33) 22278.17(0)
29.5 ... ... ... ... 22246.69(6) ...
30.5 ... ... ... ... 22185.77(–50) 22161.57(–31)
31.5 ... ... ... ... ... ...

33
J R11ff R11ee Q11ef Q11fe P11ee P11ff

11.5 ... ... ... ... ... ...
12.5 ... ... ... ... 22638.01(19) ...
13.5 ... ... ... ... 22606.47(29) ...
14.5 ... ... ... 22900.34(9) 22573.75(17) ...
15.5 ... ... ... 22886.66(2) 22540.01(14) 22547.33(20)
16.5 ... ... 22879.38(21) ... ... ...
17.5 ... ... ... 22853.02(–15) 22468.28(–9) ...
18.5 ... ... 22842.73(2) 22832.61(–11) 22429.92(–22) 22440.19(7)
19.5 ... ... ... ... ... 22400.67(–14)
20.5 ... ... 22794.19(–29) 22782.35(–22) 22346.89(–32) 22358.99(–14)
21.5 ... ... 22764.61(–20) 22751.66(–25) ... 22314.37(–29)
22.5 ... ... 22730.50(–13) 22716.55(–18) 22252.73(–30) 22266.71(–21)
23.5 ... ... ... ... 22200.30(–12) 22215.10(–22)
24.5 23141.75(17) ... ... ... 22143.36(9) 22159.16(1)
25.5 ... 23079.67(19) 22593.60(23) 22576.86(37) ... ...
26.5 ... ... 22532.79(8) ... ... ...
27.5 ... ... 22461.62(–91) 22443.41(–27) ... ...

J R22ff R22ee Q22ef Q22fe P22ff P22ee
11.5 ... ... ... ... ... 22638.26(–4)
12.5 ... ... ... ... 22612.51(1) 22606.47(–3)
13.5 ... ... 22900.34(–2) ... ... 22573.75(0)
14.5 ... ... 22886.66(5) ... 22547.53(–7) 22540.01(11)
15.5 ... ... ... 22879.38(–10) ... ...
16.5 ... ... 22853.02(13) ... ... 22468.28(13)
17.5 ... ... 22832.61(27) 22842.73(–11) 22440.19(–11) 22429.92(12)
18.5 ... ... ... ... 22400.67(–23) ...
19.5 ... ... 22781.88(–10) 22794.19(–27) 22358.99(–16) 22346.54(–13)
20.5 ... ... 22751.24(2) 22764.61(–10) 22314.37(–24) ...
21.5 ... ... 22715.88(–9) 22730.50(3) 22266.71(–9) 22252.19(–12)
22.5 ... ... ... ... 22215.10(–3) 22199.61(–1)
23.5 ... 23141.75(49) ... ... 22159.16(25) 22142.38(0)
24.5 23078.71(27) ... 22576.05(56) 22593.60(57) ... ...
25.5 ... ... ... 22532.79(47) ... ...
26.5 ... ... ... 22461.62(–47) ... ...
27.5 ... ... ... ... ... ...

44
J R11ff R11ee Q11ef Q11fe P11ee P11ff

2.5 22766.84(5) 22766.84(18) ... ... ... ...
3.5 ... ... 22694.84(–16) 22694.84(15) ... ...
4.5 ... ... ... ... ... ...
5.5 ... ... 22684.18(5) ... 22569.68(8) ...
6.5 ... ... ... ... ... ...
7.5 ... ... 22666.75(–13) 22665.00(–21) ... 22509.21(–5)
8.5 ... ... 22655.60(–5) 22653.55(6) ... ...
9.5 ... 22860.44(–16) 22642.52(2) 22639.65(–15) ... ...
10.5 ... ... 22627.20(–7) 22623.97(0) ... 22406.49(3)
11.5 ... ... ... 22605.91(10) ... 22368.84(–2)
12.5 ... ... ... 22585.43(31) 22324.83(15) 22329.32(0)
13.5 ... 22859.29(14) ... 22561.78(15) 22282.44(14) ...
14.5 ... ... ... 22535.23(19) ... ...
15.5 ... ... 22512.25(28) 22504.95(–6) 22190.20(11) 22197.44(39)
16.5 ... 22817.87(–15) 22479.09(19) 22471.01(–9) 22139.68(1) 22147.78(30)
17.5 ... ... ... 22432.69(–11) ... 22094.67(12)
18.5 ... ... 22399.01(–3) 22389.38(–9) 22027.97(–22) 22037.83(6)
19.5 ... ... 22350.69(–17) 22339.95(–42) ... ...
20.5 ... ... 22295.81(–16) 22284.43(–13) ... ...
21.5 ... ... 22233.08(–13) 22220.88(1) ... ...
22.5 ... ... 22161.33(13) ... ... ...
23.5 22489.41(–41) ... 22078.47(29) ... ... ...

J R22ff R22ee Q22ef Q22fe P22ff P22ee
2.5 ... ... ... ... ... ...
3.5 ... ... 22693.20(21) 22693.66(–2) ... ...
4.5 ... ... 22685.83(9) ... ... ...
5.5 ... ... ... 22678.37(–11) ... ...
6.5 ... ... 22666.75(–3) 22668.65(–1) ... 22509.21(–5)
7.5 ... ... 22654.78(4) 22657.04(–10) ... ...
8.5 ... ... ... 22643.80(5) ... ...
9.5 ... ... 22624.58(–14) 22628.27(–5) ... ...
10.5 ... ... 22606.01(–37) ... 22369.74(–6) ...
11.5 ... ... 22585.43(–8) ... 22330.07(–5) 22324.83(–30)
12.5 22859.29(–4) ... 22561.78(–8) ... ... 22282.44(–15)
13.5 ... ... 22535.23(10) ... ... ...
14.5 ... ... 22504.95(–2) 22512.25(–10) 22197.44(–4) 22190.20(9)
15.5 22817.87(5) ... 22471.01(7) 22479.09(–9) 22147.78(–4) 22139.68(12)
16.5 ... ... 22432.69(16) ... 22094.67(–12) ...
17.5 ... ... 22389.38(28) 22399.01(–14) 22037.83(–9) 22027.97(11)
18.5 ... ... 22339.90(0) 22350.69(–20) ... ...
19.5 ... ... 22283.93(–6) 22295.81(–12) ... ...
20.5 ... ... 22220.34(12) 22233.08(–3) ... ...
21.5 ... ... ... 22161.33(30) ... ...
22.5 ... 22489.41(–15) ... 22078.47(51) ... ...
23.5 ... ... ... ... ... ...

55
J R11ff R11ee Q11ef Q11fe P11ee P11ff

2.5 22330.87(–17) 22330.87(–4) ... ... ... ...
3.5 22344.29(–20) 22344.29(10) 22261.95(–38) 22261.95(–8) ... ...
4.5 22354.89(0) 22354.24(–11) 22252.58(–9) 22252.58(45) ... ...
5.5 22362.19(5) ... ... ... ... ...
6.5 22366.44(33) ... 22225.42(67) 22223.30(–26) ... ...
7.5 22366.44(–14) ... 22206.17(–10) 22204.69(3) ... ...
8.5 ... ... 22184.39(–12) 22182.57(13) ... ...
9.5 22355.79(–8) 22353.19(–8) 22159.07(–18) 22156.46(–19) ... ...
10.5 ... ... 22130.08(–10) 22127.38(37) ... ...
11.5 22327.03(–12) ... ... 22093.54(39) ... ...
12.5 22305.11(29) ... 22059.42(30) 22054.75(8) ... ...
13.5 ... ... 22016.43(25) 22011.09(7) ... ...
14.5 ... ... 21967.71(21) 21961.29(–32) ... ...
15.5 22197.89(15) 22191.04(–3) 21912.29(–5) 21906.29(61) ... ...
16.5 22145.62(11) ... ... 21842.11(–20) ... ...

J R22ff R22ee Q22ef Q22fe P22ff P22ee
1.5 22336.55(–2) 22336.55(–20) ... ... ... ...
2.5 ... ... ... ... ... ...
3.5 ... ... ... ... ... ...
4.5 ... ... ... ... ... ...
5.5 ... ... ... ... ... ...
6.5 ... ... 22206.17(4) ... ... ...
7.5 ... ... 22183.46(–15) 22185.82(–8) ... ...
8.5 ... ... 22157.49(–8) 22160.49(8) ... ...
9.5 ... ... 22128.66(93) 22131.15(0) ... ...
10.5 ... ... 22093.54(–14) ... ... ...
11.5 ... 22305.11(–34) 22054.75(–28) 22059.42(–37) ... ...
12.5 ... ... 22011.09(–15) 22016.43(–30) ... ...
13.5 ... ... 21961.29(–40) 21967.71(–23) ... ...
14.5 22191.04(6) 22197.89(–14) 21906.29(66) 21912.29(–38) ... ...
15.5 ... 22145.62(–9) 21842.11(–4) ... ... ...
16.5 ... ... ... ... ... ...

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