Table 2
Level energies for Ni xi.
| i | Conf. | Mixing | Lev. | Eexp | Et | |
|
|
||||||
| 1 | 3s23p6 | (96%) | 1S0 | 0.0 | 0.0 | |
| 2 | 3s23p53d | (96%) | 3P0 | 469 310.0 | 475 347.0 (–6037) | |
| 3 | 3s23p53d | (95%) | 3P1 | 472 970.0 | 479 422.0 (–6452) | |
| 4 | 3s23p53d | (93%) | 3P2 | 480 950.0 | 487 788.0 (–6838) | |
| 5 | 3s23p53d | (97%) | 3F4 | 493 250.0 | 502 075.0 (–8825) | |
| 6 | 3s23p53d | (88%) | 3F3 | 497 364.0 | 506 189.0 (–8825) | R |
| 7 | 3s23p53d | (84%) | 3F2 | 503 971.0 | 512 795.0 (–8824) | R |
| 8 | 3s23p53d | (63%) +12(33%) | 3D3 | 527 309.0 | 537 259.0 (–9950) | R |
| 9 | 3s23p53d | (56%) +7(11%) +11(28%) | 1D2 | 530 687 | 540 935.0 (–10248) | R |
| 10 | 3s23p53d | (95%) | 3D1 | 534 830.0 | 544 664.0 (–9834) | |
| 11 | 3s23p53d | (60%) +9(32%) | 3D2 | 539 180.0 | 549 219.0 (–10039) | |
| 12 | 3s23p53d | (58%) +8(30%) | 1F3 | 543 220.0 | 553 118.0 (–9898) | |
| 13 | 3s23p53d | (95%) | 1P1 | 673 960.0 | 691 250.0 (–17290) | |
| 14 | 3s3p63d | (77%) +121(c4 13%) | 3D1 | – | 859 654.0 | |
| 15 | 3s3p63d | (77%) +123(c4 13%) | 3D2 | – | 861 160.0 | |
| 16 | 3s3p63d | (78%) +118(c4 13%) | 3D3 | 839 979.0 | 863 728.0 (–23749) | TN |
| 17 | 3s3p63d | (72%) +44(c4 14%) | 1D2 | – | 889 505.0 | |
| 133 | 3s23p54s | (61%) +139(36%) | 3P1 | 1 269 940.0 | 1 322 202.0 (–52262) | |
| 139 | 3s23p54s | (60%) +133(35%) | 1P1 | 1 292 110.0 | 1 343 945.0 (–51835) | |
| 335 | 3s23p54d | (80%) | 3P1 | 1 571 310.0 | 1 615 059.0 (–43749) | |
| 357 | 3s23p54d | (68%) +385(27%) | 1P1 | 1 594 130.0 | 1 628 741.0 (–34611) | ? |
| 440 | 3s3p64s | (70%) +972(c12 24%) | 1S0 | 1 629 344.0 | 1 688 705.0 (–59361) | TN |
| 525 | 3s23p54f | (97%) | 3D1 | 1 701 800.0 | 1 762 546.0 (–60746) | |
| 534 | 3s23p54f | (91%) | 3D2 | 1 704 400.0 | 1 765 388.0 (–60988) | |
| 540 | 3s23p54f | (98%) | 3G5 | 1 706 600.0 | 1 768 505.0 (–61905) | |
| 543 | 3s23p54f | (78%) +588(10%) | 3D3 | 1 708 500.0 | 1 769 846.0 (–61346) | |
| 545 | 3s23p54f | (72%) +589(22%) | 3G4 | 1 709 045.0 | 1 771 320.0 (–62275) | R |
| 553 | 3s23p54f | (57%) +588(17%) +583(23%) | 3G3 | 1 714 400.0 | 1 776 707.0 (–62307) | |
| 565 | 3s23p54f | (48%) +589(44%) | 3F4 | 1 716 600.0 | 1 780 199.0 (–63599) | |
| 583 | 3s23p54f | (38%) +553(40%) +588(18%) | 1F3 | 1 733 700.0 | 1 796 277.0 (–62577) | |
| 588 | 3s23p54f | (50%) +583(27%) +543(18%) | 3F3 | 1 736 100.0 | 1 798 185.0 (–62085) | |
| 589 | 3s23p54f | (30%) +545(20%) +565(46%) | 1G4 | 1 736 600.0 | 1 798 761.0 (–62161) | |
| 599 | 3s23p54f | (64%) +577(26%) | 1D2 | 1 739 500.0 | 1 808 761.0 (–69261) | |
Notes. The first column indicates the (unique) level index, while the second the configuration. The third column indicates the mixing of the levels. For example, level No. 8 is a due by 63% to the 3D3 and by 33% to the level No. 12, the 1F3. Only the main contributing terms (above 10%) are listed. The fourth column indicates the dominant LSJ contribution to the level. The experimental level energies Eexp (cm-1) are shown in Col. 5 while Col. 6 lists those obtained from our scattering target Et. Values in parentheses indicate differences between Eexp and Et. Only a selection of levels is shown. R are revised values, TN tentative new ones.
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