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Table 5
f-values and predissociation rates for for the 4p(2) and 5p(0) complexes in 13C16O.
Band | Band | f-value (×10-3) | Predissociation ratesa | ||||||
origin | |||||||||
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Upper level | R0 (nm) | f(0)b | f(0) + f(x)c | f int f | E91 | parity | k(0) | k(J) | E91 |
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4pπ1Π(2) | 93.104 | 6.19(0.44) | 6.2(0.6) | e | 0.771(0.044) | +0.0290(0.0097)x | 1.0 | ||
f | 0.763(0.052) | +0.0160(0.0013)x | |||||||
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4pσ![]() |
93.320 | 1.0(0.2) | 1.0(0.2) | ~1.5–2.8 | |||||
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5pπ1Π(0) | 93.204 | Pd:9.34(0.90) | 9.34(0.90) + 0.21(0.01)x + [0.17(0.07)] × 10![]() |
13.55(1.03) | e | 0.603(0.015) | +0.0049(0.0002)x (for J′ = 1–7) | 1.0 | |
Rd:9.34(0.47) | 9.34(0.47) + 0.0078(0.00026)x | 16.8(1.7)e | e | 0.262(0.160) | +0.0083(0.0011)x (for J′> 7) | ||||
Qd:9.34(0.22) | 9.34(0.22) + 0.036(0.0009)x | f | 0.550(0.028) | +0.0056(0.0004)x | |||||
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II 1Π(0)? | ~93.24 | 2.14(0.23) | |||||||
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5pσ![]() |
93.302 | Pd:20.2(0.9) | 20.2(0.9) – 0.15(0.04)x | 13.68(0.96) | 16.8(1.7) | 0.147(0.017) | +0.0402(0.0026)x (for J′ = 1–5) | 0.1 | |
Rd:20.2(0.7) | 20.2(0.7) + 0.25(0.04)x | 2.05(0.09) | +0.023(0.012)x (for J′> 5) | ||||||
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I 1Π | ~93.359 | 11.0(0.9) | very diffuse | ||||||
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Sum | 47.56 |
Notes. Uncertainties are given in parentheses (1 standard error). Comparison with the previous work E91 (Eidelsberg et al. 1991).
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