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Table 5

f-values and predissociation rates for for the 4p(2) and 5p(0) complexes in 13C16O.

Band Band f-value (×10-3) Predissociation ratesa
origin

Upper level R0 (nm) f(0)b f(0) + f(x)c f int f E91 parity k(0) k(J) E91

4pπ1Π(2) 93.104 6.19(0.44) 6.2(0.6) e 0.771(0.044) +0.0290(0.0097)x 1.0
f 0.763(0.052) +0.0160(0.0013)x

4pσ(2)? 93.320 1.0(0.2) 1.0(0.2) ~1.5–2.8

5pπ1Π(0) 93.204 Pd:9.34(0.90) 9.34(0.90) + 0.21(0.01)x + [0.17(0.07)] × 10 13.55(1.03) e 0.603(0.015) +0.0049(0.0002)x (for J = 1–7) 1.0
Rd:9.34(0.47) 9.34(0.47) + 0.0078(0.00026)x 16.8(1.7)e e 0.262(0.160) +0.0083(0.0011)x (for J′> 7)
Qd:9.34(0.22) 9.34(0.22) + 0.036(0.0009)x f 0.550(0.028) +0.0056(0.0004)x

II 1Π(0)? ~93.24 2.14(0.23)

5pσ(0) 93.302 Pd:20.2(0.9) 20.2(0.9) – 0.15(0.04)x 13.68(0.96) 16.8(1.7) 0.147(0.017) +0.0402(0.0026)x (for J = 1–5) 0.1
Rd:20.2(0.7) 20.2(0.7) + 0.25(0.04)x 2.05(0.09) +0.023(0.012)x (for J′> 5)

I 1Π ~93.359 11.0(0.9) very diffuse

Sum 47.56

Notes. Uncertainties are given in parentheses (1 standard error). Comparison with the previous work E91 (Eidelsberg et al. 1991).

(a)

Predissociation rates in units of (1011 s-1).

(b)

f-value for J′ = 0.

(c)

f-value for J′ ≥ 0, x = J(J′ + 1).

(d)

Each branch are reported with a common averaged J = 0 intercept but being fitted separately, the uncertainties are different.

(e)

This result includes the unknown band, which may be II 1Π(0).

(f)

f gives the f-value integrated from the fit of the entire band including, when required, corrected Hönl-London factors and linewidths.

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