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Table 3
Simplified set of C-H-O reactions derived from Dobrijevic et al. (2014, see text).
| Reaction | Rate coefficient | Reference | |
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|
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| R60 | O(1D) + N2→ O(3P) + N2 | 2.15 × 10-11e110 /T | Sander et al. (2011) |
| R61 | O(1D) + H2→ OH + H | 1.1 × 10-10 | Sander et al. (2011) |
| R62a | O(1D) + CH4→ OH + CH3 | 1.05 × 10-10 | Atkinson et al. (2006) |
| R62b | O(1D) + CH4→ CH3O + H | 3.5 × 10-11 | Atkinson et al. (2006) |
| R62c | O(1D) + CH4→ H2CO + H2 | 7.5 × 10-12 | Atkinson et al. (2006) |
| R63a | O(3P) + CH3→ H2CO + H | 1.1 × 10-10 | Baulch et al. (2005); Dobrijevic et al. (2014) |
| R63b | O(3P) + CH3→ CO + H + H2 | 2.9 × 10-11 | Baulch et al. (2005); Dobrijevic et al. (2014) |
| R64a | O(3P) + 1CH2→ HCO + H | 1.0 × 10-11 | Böhland et al. (1984); Vinckier (1979); |
| R64b | O(3P) + 1CH2→ CO + H + H | 5.0 × 10-11 | Shepler et al. (2007); Wang et al. (1973); |
| R64c | O(3P) + 1CH2→ CO + H2 | 6.0 × 10-11 | Baulch et al. (2005); Zhang et al. (2004) |
| R65a | O(3P) + 3CH2→ HCO + H | 1.0 × 10-11 | Böhland et al. (1984); Vinckier (1979); |
| R65b | O(3P) + 3CH2→ CO + H + H | 5.0 × 10-11 | Shepler et al. (2007); Wang et al. (1973); |
| R65c | O(3P) + 3CH2→ CO + H2 | 6.0 × 10-11 | Baulch et al. (2005); Zhang et al. (2004) |
| R66a | O(3P) + C2H2→3CH2 + CO | 6.6 × 10-12e− 1600 /T | Baulch et al. (2005); Sander et al. (2011) |
| R66b | O(3P) + C2H2→ HC2O + H | 2.6 × 10-11e− 1600 /T | Baulch et al. (2005); Sander et al. (2011) |
| R67a | O(3P) + C2H4→ CH3CO + H | 4.8 × 10-13(T/ 300)1.88e− 92 /T | Baulch et al. (2005); Fu et al. (2012a,b); Balucani et al. (2012) |
| R67b | O(3P) + C2H4→ CH3 + HCO | 5.0 × 10-13(T/ 300)1.88e− 92 /T | Baulch et al. (2005); Fu et al. (2012a,b); Balucani et al. (2012) |
| R67c | O(3P) + C2H4→3CH2 + H2CO | 1.0 × 10-13(T/ 300)1.88e− 92 /T | Baulch et al. (2005); Fu et al. (2012a,b); Balucani et al. (2012) |
| R67d | O(3P) + C2H4→ CH2CO + H2 | 3.0 × 10-14(T/ 300)1.88e− 92 /T | Baulch et al. (2005); Fu et al. (2012a,b); Balucani et al. (2012) |
| R68a | O(3P) + C2H3→ CH3 + CO | 6.0 × 10-11 | Heinemann et al. (1988); Harding et al. (2005); Dobrijevic et al. (2014) |
| R68b | O(3P) + C2H3→ OH + C2H2 | 1.0 × 10-11 | Heinemann et al. (1988); Harding et al. (2005); Dobrijevic et al. (2014) |
| R69a | O(3P) + C2H5→ H2CO + CH3 | 5.0 × 10-11 | Harding et al. (2005); Hoyermann et al. (1999) |
| R69b | O(3P) + C2H5→ CH3CHO + H | 6.0 × 10-11 | Harding et al. (2005); Hoyermann et al. (1999) |
| R69c | O(3P) + C2H5→ OH + C2H4 | 3.0 × 10-11 | Harding et al. (2005); Hoyermann et al. (1999) |
| R70 | O(3P) + C4H2→ CO + C3H2 | 1.31 × 10-11e− 678 /T | Adamson et al. (1994) |
| R71 | OH + H2→ H2O + H | 2.8 × 10-12e− 1800 /T | Sander et al. (2011) |
| R72a | OH + CH3→ H2O + 1CH2 | 3.2 × 10-11 | De Avillez Pereira et al. (1997); Jasper et al. (2007); Sangwan et al. (2012) |
| R72b | OH + CH3→ H2CO + H2 | 8.0 × 10-12 | De Avillez Pereira et al. (1997); Jasper et al. (2007); Sangwan et al. (2012) |
| R72c | OH + CH3→ CH3OH | k0 = 2.0 × 10-26(T/ 300)-6e− 1000 /T | |
| k∞ = 1.2 × 10-10(T/ 300)-0.49 | De Avillez Pereira et al. (1997); Jasper et al. (2007); Sangwan et al. (2012) | ||
| R73 | OH + CH4→ H2O + CH3 | 1.9 × 10-12e− 1690 /T | Atkinson et al. (2006) |
| R74 | OH + C2H2→ CH3CO | k0 = 5.5 × 10-30 | Sander et al. (2011) |
| k∞ = 8.3 × 10-13(T/ 300)2 | Sander et al. (2011) | ||
| R75 | OH + C2H4→ HOCH2CH2 | k0 = 1.0 × 10-28(T/ 300)-4.5 | Sander et al. (2011) |
| k∞ = 7.5 × 10-12(T/ 300)-0.85 | Sander et al. (2011) | ||
| R76 | OH + CO → CO2 + H |
|
Atkinson et al. (2006) |
| R77 | HCO + H → CO + H2 | 1.5 × 10-10 | Baulch et al. (2005) |
| R78 | HCO + CH3→ CO + CH4 | 9.3 × 10-11 | Krasnoperov et al. (2005); Hébrard et al. (2013) |
| R79a | H + CH3O → CH3 + OH | 3.0 × 10-12 | Hoyermann et al. (1981); Dóbó et al. (1991) |
| R79b | H + CH3O → H2CO + H2 | 3.0 × 10-11 | Hoyermann et al. (1981); Dóbó et al. (1991) |
| R80 | CH3O + CH3→ H2CO + CH4 | 4.0 × 10-11 | Tsang & Hampson (1986) |
| R81 | C2H + H2O → OH + C2H2 | 7.9 × 10-24(T/ 300)3.05e− 376 /T | Carl et al. (2005) |
| R82 | H + CO → HCO | k0 = 7.5 × 10-35(T/ 300)0.2 | Baulch et al. (2005) |
| k∞ = 1.2 × 10-10e− 1000 /T | Wagner & Bowman (1987); Wang et al. (1973) | ||
| R83 | H + H2CO → H2 + HCO | 3.3 × 10-11e− 1850 /T | Klemm (1979) |
| R84a | H + CH3CO → CH3 + HCO | 4.0 × 10-11 | Bartels et al. (1991); Ohmori et al. (1990) |
| R84b | H + CH3CO → H2C2O + H2 | 2.0 × 10-11 | Bartels et al. (1991); Ohmori et al. (1990) |
| R85 | CH + H2O → H2CO + H | 2.8 × 10-11(T/ 300)-1.22e− 12 /T | Blitz et al. (1999); Bergeat et al. (2009); Hickson et al. (2013); Zabarnick et al. (1988) |
| R86 | CH + H2CO → H2C2O + H | 1.0 × 10-10e− 260 /T | Zabarnick et al. (1988) |
| R87 | CH + CO2→ H + CO + CO | 5.71 × 10-12e− 345 /T | Berman et al. (1982) |
| R88 | CH3 + CH3O → CH4 + H2CO | 4.0 × 10-11 | Tsang & Hampson (1986) |
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