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Table A.1

Summary of atomic and molecular collisional data in BASECOL2012.

Id Target Collider Levels Temperature (K) Method Method’s Ref PES Ref Year Recom Fit Matched
101 C H f3 5–1000 CC 2 75 2007 yes y n
116 C H f3 4–1000 CC 1 74 1977 no y n
106 C o-H2 f3 10–1200 CC 3 3 1991 yes y n
105 C p-H2 f3 10–1200 CC 3 3 1991 yes y n
104 C He f3 10–150 CC 4 4 1991 yes y n
102 C+ H f2 20–2000 CC 5 76 2005 yes y n
145 C3 He r6 5–15 CC 6 6 2008 yes n n
214 C4 He r20f30 1–50 CC 122 122 2010 yes n n
201 C2H He h34 5–100 CC+recoup 104 104 2012 yes n n
192 CH+ He r11 20–200 CC 7 7 2008 no n y
146 CH+ He r11 20–2000 CC 77 7 2009 yes n y
191 CH+ He r6 1–200 CC 78 78 2010 yes n y
160 CH+ e r8 100–15 000 R 8 8 1999 yes y y
224 A-CH3OH He r256, vt = 0 10–200 CS 125 126 2010 yes n n
226 A-CH3OH He r256, vt = 1 10–200 CS 125 126 2010 yes n n
229 A-CH3OH He r256, vt = 2 10–200 CS 125 126 2010 yes n n
225 E-CH3OH He r256, vt = 0 10–200 CS 125 126 2010 yes n n
227 E-CH3OH He r256, vt = 1 10–200 CS 125 126 2010 yes n n
228 E-CH3OH He r256, vt = 2 10–200 CS 125 126 2010 yes n n
230 A-CH3OH p-H2 r256, vt = 0 10–200 CS 127 128 2010 yes n n
231 A-CH3OH p-H2 r256, vt = 1 10–200 CS 127 128 2010 yes n n
232 A-CH3OH p-H2 r256, vt = 2 10–200 CS 127 128 2010 yes n n
233 E-CH3OH p-H2 r256, vt = 0 10–200 CS 127 128 2010 yes n n
234 E-CH3OH p-H2 r256, vt = 1 10–200 CS 127 128 2010 yes n n
235 E-CH3OH p-H2 r256, vt = 2 10–200 CS 127 128 2010 yes n n
222 A-CH3OH He rvt150 10–400 CS 129 126 2011 yes n n
223 E-CH3OH He rvt150 10–400 CS 129 126 2011 yes n n
46 o c-C3H2 He r47 30–120 IOS 9, 79 79 2000 yes y y
47 p c-C3H2 He r48 30–120 IOS 9, 79 79 2000 yes y y
210 CN− p-H2 r11 5–100 CS 118 118 2011 yes n y
211 CN− o-H2 r11 5–100 CS 118 118 2011 yes n y
209 CN He r21f41 5–350 CC 119 119 2010 yes n n
212 CN He r13h73 5–30 CC+recoupl 120 119 2011 yes n n
213 CN p-H2 r6h37 5–100 CC+recoupl 121 121 2012 yes n n
48 CO H r8 5–100 CC 10 80 2002 yes y y
60 CO H r17 100–3000 CC 10 80 2002 yes y y
49 CO H v5 100–3000 IOS 10 80 2002 yes y n
218 CO o-H2 r41 1–3000 CC/CS 123 81 2010 yes y y
219 CO p-H2 r41 1–3000 CC/CS 123 81 2010 yes y y
97 CO o-H2 r6 5–70 CC/CS 11 81 2006 no y y
98 CO p-H2 r6 5–70 CC/CS 11 81 2006 no y y
33 CO o-H2 r20 5–400 CC 12 82 2001 no y y
34 CO p-H2 r29 5–400 CC 12 82 2001 no y y
50 CO He r15 5–500 CC 14 83 2002 yes n y
51 CO He v7 500–5000 IOS 14 83 2002 yes n n
161 CO+ e r5 100–10 000 R 15 15 2001 yes y n
61 CS p-H2 r13 10–100 CC/CS 16 16 1978 no y y
10 CS p-H2 r21 20–300 CC/CS 17 16 1992 yes y y
90 CS He r31 10-300 CC 18 18 2006 yes n y
121 CS He v3 (r38 in each v) 300-1500 VCC-IOS 19 19 2007 yes n y
54 o-H2 H r3 100–1000 CC 20 84 1997 yes y n
53 p-H2 H r3 100–1000 CC 20 84 1997 yes y n
26 o-H2 H v1r8,v2r7,v3r5,v4r4 (up to l25) 100–6000 CC 21 84 1998 yes y n
27 p-H2 H v1r9,v2r7,v3r6,v4r5 (up to l28) 100–6000 CC 21 84 1998 yes y n
28 o-H2 o-H2 v1r7,v2r6,v3r4 (up to l22) 100–6000 CC 21 85 1999 yes y n
30 p-H2 o-H2 v1r8,v2r6,v3r5 (up to l19) 100–6000 CC 21 85 1999 yes y n
29 o-H2 p-H2 v1r13,v2r11,v3r5 (up to l24) 100–6000 CC 23 85 1998 yes y n
31 p-H2 p-H2 v1r9,v2r7,v3r6,v4r5 (up to l28) 100–6000 CC 23 85 1998 yes y n
24 o-H2 He v1r8,v2r7,v3r5,v4r4 (up to l25) 100–6000 CC 24 86 1998 yes y n
25 p-H2 He v1r9,v2r7,v3r6,v4r5 (up to l28) 100–6000 CC 24 86 1998 yes y n
165 o-H2+ e r2 100–10 000 R 15 15 2001 yes y n
166 p-H2+ e r2 100–10 000 R 15 15 2001 yes y n
178 H2+ e v3 100–20 000 R 13 13 1993 yes y n
168 o-H3+ e r2 100–10 000 R 25 25 2003 no y n
167 p-H3+ e r4 100–10 000 R 25 25 2003 no y n
240 o-H3+ e r7 5–2000 MQDT 131 131 2010 yes n n
241 p-H3+ e r13 5–2000 MQDT 131 131 2010 yes n n
170 o-H3O+ e r4 100–10 000 R 25 25 2003 yes y n
169 p-H3O+ e r8 100–10 000 R 25 25 2003 yes y n
18 o-H2CO He r41 10–300 CC/CS 25 87 1991 yes y y
17 p-H2CO He r40 10–300 CC/CS 25 87 1991 yes y y
198 o-H2CO p-H2 r10 5–100 CC/CS 102 102 2009 yes y n
199 o-H2CO o-H2 r10 5–100 CC/CS 102 102 2009 yes y n
41 o-H2O o-H2 r5 20–140 CC/CS 27 88 1996 no y y
42 o-H2O p-H2 r5 20–140 CC/CS 27 88 1996 no y y
43 p-H2O o-H2 r5 20–140 CC/CS 27 88 1996 no y y
44 p-H2O p-H2 r5 20–140 CC/CS 27 88 1996 no y y
190 o-H2O o-H2 r45 20–2000 QCT 28 89 2007 no n n
189 o-H2O p-H2 r45 20–2000 QCT 28 89 2007 no n n
188 p-H2O o-H2 r45 20–2000 QCT 28 89 2007 no n n
187 p-H2O p-H2 r45 20–2000 QCT 28 89 2007 no n n
127 o-H2O p-H2 r45 5–1500 CC 29 89 2009 yes y y
193 o-H2O o-H2 r45 5–1500 CC 91 89 2011 yes y y
194 p-H2O p-H2 r45 5–1500 CC 91 89 2011 yes y y
195 p-H2O o-H2 r45 5–1500 CC 90, 91 89 2010, 2011 yes y y
4 o-H2O He r45 20–2000 CC/CS 31 90 1993 yes y y
22 p-H2O He r45 20–2000 CC/CS 31 90 1993 yes y y
134 o-H2O e r14 100–8000 R 32 32 2004 yes y n
128 p-H2O e r14 100–8000 R 32 32 2004 yes y n
182 o-H2O H2 rv411 200–5000 QCT + approx 30 89 2008 yes n n
181 p-H2O H2 rv411 200–5000 QCT + approx 30 89 2008 yes n n
184 o-H2O e rv411 200–5000 R + approx 30 32 2008 yes n n
183 p-H2O e rv411 200–5000 R + approx 30 32 2008 yes n n
140 o-D2O e r18 100–8000 R 32 32 2004 yes y n
135 p-D2O e r18 100–8000 R 32 32 2004 yes y n
207 o-D2O p-H2 r6 5–100 CC 111 89 2012 yes n n
215 p-D2O p-H2 r6 5–100 CC 111 89 2012 yes n n
216 HDO p-H2 r30 5–300 CC/CS 111 89 2012 yes n n
217 HDO o-H2 r30 5–300 CC/CS 111 89 2012 yes n n
36 HC3N He r21 10–80 QCT/IOS 16 16 1978 no n y
175 HC3N He r11 10–20 CC 33 33 2007 yes n y
174 HC3N p-H2 r51 10–100 CC/CS/QCT 33 33 2007 yes ? y y
13 HCl He r8 10–300 CC/CS 34 34 1994 yes n n
14 HCl He h28 10–300 CC/CS/hIOS 34 34 1994 yes n y
62 HCN He r8 5–100 CC 35 35 1974 no y y
202 HCN He r26 5–500 CC 107, 108 109 2010 yes y y
203 HNC He r26 5–500 CC 107, 108 108 2010 yes y y
238 HNC p-H2 r11 5–100 CC 130 130 2011 yes y y
239 HNC o-H2 r11 5–100 CC 130 130 2011 yes y y
92 HCN He r4h13 10–30 CC 36 35 1986 no y y
204 HCN p-H2 r10h31 5–100 CC+recoup 110 110 2012 yes n n
147 HCN e r9 5–2000 R+Born 37 37 2007 yes y y
153 HCN e r3h10 10–100–1000 R+Born +hIOS 37 37 2007 yes n n
150 HNC e r9 5–2000 R+Born 37 37 2007 yes y y
155 HNC e r3h10 10–1000 R+Born+hIOS 37 37 2007 yes y n
157 DCN e r9 5–2000 R+Born 37 37 2007 yes y y
154 DCN e r3h10 10–100–1000 R+Born+hIOS 37 37 2007 yes y n
151 DNC e r9 5–2000 R+Born 37 37 2007 yes y y
154 DNC e r3h10 10–100–1000 R+Born+hIOS 37 37 2007 yes y n
11 HCO+ p-H2 r21 5–390 CC 43 91 1999 yes y y
163 HCO+ e r3 100–10 000 R+Born 15 15 2001 yes y y
144 HCP p-H2 r11 10–70 CC 38 38 2008 yes n y
143 HCP He r16 20–200 CC 39 39 2008 yes n y
19 HCS+ He r11 10–60 CC/CS 40 40 1984 yes n y
70 HD H r9 100–2000 CC 41 84 1999 yes n n
71 HD H v2r9 100–2080 CC 124 84 1999 yes n n
72 HD He r10 80–1000 CC 44 86 1999 yes n n
73 HD o-H2 r9 50–500 CC 42 85 1999 yes y n
74 HD p-H2 r9 50–500 CC 42 85 1999 yes y n
75 HD o-H2 v2r9 100–2080 CC 124 85 1999 yes n n
76 HD p-H2 v2r9 100–2080 CC 124 85 1999 yes n n
21 HDO He r34 50–500 CC/CS 45 92 1989 yes y y
141 HDO e r36 (a-type) 100–8000 R 32 32 2004 yes y n
142 HDO e r36 (b-type) 100–8000 R 32 32 2004 yes y n
63 HF He r10 0.1–300 CC 46 93 2005 yes n y
176 HeH+ e r3 100–20 000 R 48 48 1998 yes y y
177 HeH+ e v3 100–20 000 R 48 48 1998 yes y n
122 HOCO+ He r25 10–30 CS 47 47 2007 yes n y
208 NH He r8f25 5– 350 CC 73 103 2011 yes n n
91 N2H+ He r7 5–40 CC 49 49 1975 no y y
82 N2H+ He r7 5–50 CC 50 94 2005 yes n y
69 N2H+ He r7h55 5–50 CC+S–recoup 50 94 2005 yes n y
125 o-ND2H He r9 5–100 CS 51 51, 95 2007 yes n y
126 p-ND2H He r9 5–100 CS yes 51, 95 2007 yes n n
124 o-NH2D He r9 5–100 CS 52 52, 95 2006 yes n y
123 p-NH2D He r9 5–100 CS 52 52, 95 2006 yes n n
85 o-NH3 p-H2 r9 15–300 CC 53 53 1986 no n y
87 p-NH3 p-H2 r16 15–300 CC 56 53 1987 no y y
88 o-NH3 p-H2 r17 15–300 CC 54 53 1988 yes n y
89 p-NH3 p-H2 r24 15–300 CC 54 53 1988 yes n y
196 o-NH3 p-H2 r6 5–100 CC 101 101 2009 yes n n
197 p-NH3 p-H2 r16 5–100 CC 101 101 2009 yes n n
83 o-NH3 He r22 5–300 CC 55 95 2005 yes n y
84 p-NH3 He r16 5–300 CC 55 95 2005 yes y y
185 NO He f98 10–500 CS 61 100 2008 yes n n
164 NO+ e r5 100–5000 R 15 15 2001 yes y y
117 O H f3 50–1000 CC 1 1 1977 no y n
107 O H f3 50–1000 CC 2 96 2007 yes y n
109 O o-H2 f3 20–1500 CC 57 57 1992 yes y n
108 O p-H2 f3 20–1500 CC 57 57 1992 yes y n
35 OCS p-H2 r13 10–100 CS 16 16 1978 yes y y
12 OCS He r27 10–150 CC 58 97 2001 yes y y
206 OH He f46 5–350 CC 116 117 2007 yes n n
205 O2 He r23f36 5–350 CC 112 113 2010 yes n n
118 PN He r31 5–300 CC/CS 59 59 2007 yes n n
103 Si+ H f2 20–2000 CC 5 5 2005 yes y n
179 SiH+ He r11 5–200 CC 60 60 2009 yes n n
45 o-SiC2 He r40 25–125 IOS 9, 98 98 2000 yes y y
23 SiO p-H2 r21 20–300 CS 17 17 1992 no y y
100 SiO p-H2 r27 10–300 CC 62 62 2006 yes n y
95 SiO He r27 10–300 CC 62 62 2006 yes n y
186 SiO e r41 5-5000 R 63 63 2009 yes y n
172 SiS o-H2 r41 5–300 CS 64 64 2008 yes n y
171 SiS p-H2 r41 5–300 CS 64 64 2008 yes n y
119 SiS He r26 5–200 CC 65 65 2007 yes n y
173 SiS He v5r100 100–1500 VCC+IOS 66 66 2008 yes n n
200 SH He f58 5–350 CC 114 115 2009 yes n n
32 SO p-H2 r24f70 50–350 rCS+fIOS 67 67 1994 no n y
180 SO p-H2 r31 5–50 CC 68 68 2007 yes n n
96 SO He rv236 300–800 VCC–IOS 69 69 2006 yes n n
81 SO He f91 60–300 CC/IOS 70 71 2006 yes y y
77 SO He f31 5–50 CC 71 71 2005 yes n y
20 SO2 He r50 25–125 IOS 72 99 1995 no y y
220 SO2 p-H2 r31 5–30 CC 105 106 2011 yes n n
221 SO2 o-H2 r31 5–30 CC 105 106 2011 yes n n

Notes.The “Method” notations CC, CS, IOS, QCT are explained in the text, “R” stands for R-matrix calculations, “born” stands for Born and Born-Coulomb approximations, VCC-IOS means that vibration is treated with CC and rotation with IOS, hIOS means that the hyperfine transitions are treated with IOS, “approx” means that some additional approximation has been performed, “recoupl” means that a recoupling technique for T or S matrices has been used to obtain the hyperfine cross sections. The different columns provide the following information: (1:) ID by which the collisional system can be found directly in the database, (2:) the available atomic or molecular target, (3:) the perturbing collider, (4:) the rovibrational levels for which rate coefficients are available: the symbols r, f, v, rv and h are used to denote rotational, fine, vibrational, ro-vibrational and hyperfine transitions respectively (for example, “r7” means that rate coefficients are available for the 7 lowest rotational levels), (5:) temperature range for which the rates have been calculated, (6:) method employed to treat the collision dynamics, (7,8:) references to the papers describing the calculations and the potential energy surfaces calculations respectively, (10:) whether the set is recommended, (11:) whether fitting coefficients are available, and the last column indicates whether the collisional set is matched with spectroscopic data (see Sect. 2.2.5).

Reference. (1) Launay & Roueff (1977). (2) Abrahamsson et al. (2007). (3) Schröder et al. (1991). (4) Staemmler & Flower (1991). (5) Barinovs et al. (2005). (6) Ben Abdallah et al. (2008). (7) Hammami et al. (2008a). (8) Lim et al. (1999). (9) Chandra & Kegel (2000). (10) Balakrishnan et al. (2002). (11) Wernli et al. (2006). (12) Flower (2001a). (13) Sarpal & Tennyson (1993). (14) Cecchi-Pestellini et al. (2002). (15) Faure & Tennyson (2001). (16) Green & Chapman (1978). (17) Turner et al. (1992). (18) Lique et al. (2006b). (19) Lique & Spielfiedel (2007). (20) Forrey et al. (1997). (21) Flower & Roueff (1998a). (22) Flower & Roueff (1999b). (23) Flower & Roueff (1998b). (24) Flower et al. (1998). (25) Faure & Tennyson (2003). (26) Green (1991). (27) Phillips et al. (1996). (28) Faure et al. (2007a). (29) Dubernet et al. (2009). (30) Faure & Josselin (2008). (31) Green et al. (1993). (32) Faure et al. (2004a). (33) Wernli et al. (2007a,b). (34) Neufeld & Green (1994). (35) Green & Thaddeus (1974). (36) Monteiro & Stutzki (1986). (37) Faure et al. (2007b). (38) Hammami et al. (2008). (39) Hammami et al. (2008b). (40) Monteiro (1984). (41) Roueff & Flower (1999). (42) Flower (1999a). (43) Flower (1999b). (44) Roueff & Zeippen (1999). (45) Green (1989). (46) Reese et al. (2005). (47) Hammami et al. (2007). (48) Rabadan et al. (1998). (49) Green (1975). (50) Daniel et al. (2005). (51) Machin & Roueff (2007). (52) Machin & Roueff (2006). (53) Danby et al. (1986). (54) Danby et al. (1988). (55) Machin & Roueff (2005). (56) Danby et al. (1987). (57) Jaquet et al. (1992). (58) Flower (2001b). (59) Toboła et al. (2007). (60) Nkem et al. (2009). (61) Kłos et al. (2008). (62) Dayou & Balança (2006). (63) Varambhiaet al. (2009). (64) Kłos & Lique (2008). (65) Vincent et al. (2007). (66) Toboła et al. (2008). (67) Green (1994). (68) Lique et al. (2007). (69) Lique et al. (2006c). (70) Lique et al. (2006a). (71) Lique et al. (2005). (72) Green (1995). (73) Toboła et al. (2011). (74) Yau & Dalgarno (1976). (75) Kalemos et al. (1999). (76) Barinovs & van Hemert (2004). (77) Hammami et al. (2009). (78) Turpin et al. (2010). (79) Green et al. (1987). (80) Keller et al. (1996). (81) Jankowski & Szalewicz (1998). (82) Jankowski & Szalewicz (1998). (83) Heijmen et al. (1997c). (84) Boothroyd et al. (1996). (85) Schwenke (1988). (86) Muchnick & Russek (1994). (87) Garrison & Lester (1975). (88) Phillips et al. (1994). (89) Valiron et al. (2008). (90) Maluendes et al. (1992). (91) Monteiro (1985). (92) Palma et al. (1988). (93) Stoecklin et al. (2003). (94) Daniel et al. (2004). (95) Hodges & Wheatley (2001). (96) Parlant & Yarkony (1999). (97) Higgins & Klemperer (1999). (98) Palma & Green (1987). (99) Palma (1987). (100) Kłos et al. (2000). (101) Maret et al. (2009). (102) Troscompt et al. (2009). (103) Cybulski et al. (2005). (104) Spielfiedel et al. (2012). (105) Cernicharo et al. (2011). (106) Spielfiedel et al. (2009). (107) Dumouchel et al. (2010). (108) Sarrasin et al. (2010). (109) Toczyłowski et al. (2001). (110) Ben Abdallah et al. (2012). (111) Faure et al. (2012). (112) Lique (2010). (113) Groenenboom & Struniewicz (2000). (114) Kłos et al. (2009). (115) Cybulski et al. (2000). (116) Kłos et al. (2007). (117) Lee et al. (2000). (118) Kłos & Lique (2011). (119) Lique et al. (2010b). (120) Lique & Kłos (2011). (121) Kalugina et al. (2012). (122) Lique et al. (2010a). (123) Yang et al. (2010). (124) Flower & Roueff (1999a). (125) Rabli & Flower (2010b). (126) Pottage et al. (2002). (127) Rabli & Flower (2010a). (128) Pottage et al. (2004). (129) Rabli & Flower (2011), (130) Dumouchel et al. (2011), (131) Kokoouline et al. (2010).

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