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Table 3
Comparison of the fitting parameters of spinel.
| j | T(K) | ΩTOj | γTOj | ΩLOj | γLOj | ϵ∞ |
| (cm-1) | (cm-1) | (cm-1) | (cm-1) | |||
|
|
||||||
| 1 | 300 | 231.05 | 8.97 | 231.58 | 8.29 | 2.77 |
| 551 | 226.96 | 9.99 | 227.54 | 9.41 | 2.8 | |
| 738 | 230.02 | 9.79 | 230.34 | 9.18 | 2.82 | |
| 928 | 227.33 | 13.81 | 227.78 | 13.45 | 2.77 | |
| 2 | 300 | 307.12 | 12.65 | 310.73 | 13.68 | − |
| 551 | 304.4 | 16.38 | 308.36 | 17.02 | ||
| 738 | 302.2 | 20.15 | 306.49 | 20.68 | ||
| 928 | 300.07 | 20.15 | 304.01 | 20.58 | ||
| 3 | 300 | 427.11 | 134.26 | 442.85 | 112.26 | − |
| 551 | 426.34 | 139.54 | 438.44 | 108.65 | ||
| 738 | 438.12 | 140.41 | 444.8 | 96.33 | ||
| 928 | 440.49 | 140.09 | 442.56 | 97.23 | ||
| 4 | 300 | 481.53 | 30.58 | 608.03 | 37.88 | − |
| 551 | 475.24 | 35.89 | 598.4 | 42.79 | ||
| 738 | 469.66 | 38.7 | 590.55 | 48.62 | ||
| 928 | 466.52 | 45.67 | 582.36 | 55.59 | ||
| 5 | 300 | 531.37 | 55.1 | 558.16 | 70.14 | − |
| 551 | 527.69 | 63.05 | 553.85 | 74.68 | ||
| 738 | 521.27 | 65.86 | 549.66 | 79.03 | ||
| 928 | 520.32 | 76.53 | 546.93 | 82.07 | ||
| 6 | 300 | 581.8 | 74.64 | 546.32 | 120.96 | − |
| 551 | 576.95 | 74.12 | 547.55 | 122.79 | ||
| 738 | 569.98 | 75.11 | 542.25 | 126.64 | ||
| 928 | 563.9 | 73.29 | 544.39 | 126 | ||
| 7 | 300 | 672.28 | 36.67 | 866.53 | 39.52 | − |
| 551 | 662.28 | 47.55 | 862.97 | 47.55 | ||
| 738 | 655.42 | 55.98 | 860.15 | 55.98 | ||
| 928 | 649.32 | 64.24 | 855.98 | 64.24 | ||
| 8 | 300 | 811.63 | 77.37 | 800.67 | 73.77 | − |
| 551 | 797.84 | 86.36 | 785.72 | 76.12 | ||
| 738 | 789.47 | 92.02 | 776.78 | 79.87 | ||
| 928 | 786.4 | 93.61 | 772.56 | 85.91 | ||
Notes.Oscillators 2, 4, 5, and 7 represent the predicted T1u-type modes of the theory.
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